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Concept explainers
Interpretation:
Among the given reactions, the one which gives two different halogenated hydrocarbons has to be chosen from the given options.
Concept Introduction:
In this reaction no atoms or group of atoms are removed. Instead the unsaturated bond is reduced to saturated bond. A general scheme for addition reaction of
Addition reactions can be classified broadly into two types. They are asymmetrical addition reaction and symmetrical addition reaction.
Symmetrical addition reactions is the one in which the same atom or same group of atoms are added across the carbon‑carbon multiple bonds.
Unsymmetrical addition reactions is the one in which the different atom or different group of atoms are added across the carbon‑carbon multiple bonds.
Hydrohalogenation is an unsymmetrical addition reaction. In this reaction a hydrogen atom and a halogen atom are added across the multiple bond. If the alkene considered is a symmetrical one, then only one product is formed. If the alkene considered is an unsymmetrical one, then two products are formed which depends on which side of the double bond the atoms gets attached.
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Chapter 13 Solutions
EBK GENERAL, ORGANIC, AND BIOLOGICAL CH
- Identify any combination reactions. (Select all that apply.) C4H10 + O2 → CO2 + H2O S8 + O2 → SO3 NaNO3 → NaNO2 + O2 HgO → Hg + O2 Ga + H2SO4 → Ga2(SO4)3 + H2 AgCl2 + H2 → Ag + HCl none of the above Identify any decomposition reactions. (Select all that apply.) C4H10 + O2 → CO2 + H2O S8 + O2 → SO3 NaNO3 → NaNO2 + O2 HgO → Hg + O2 Ga + H2SO4 → Ga2(SO4)3 + H2 AgCl2 + H2 → Ag + HCl none of the abovearrow_forwardGive the reagent or chemical test that would differentiate the following pairs of compounds. Write chemical equations for the reactions. List of Chemical Tests (choose here)I. Halogenation: Bromination with and without lightII. Oxidation: Reaction with Baeyer’s reagent III. Reaction with Ammoniacal Silver Nitrate (AgNO3) or simply Tollen’s reagent a. benzene and ethylbenzeneb. 1-butyne and 2-butynec. 2-methylpentane and 2-methyl-2-pentened. toluene and 1-methylcyclohexenearrow_forward1. Rank the following amines from lowest to highest boiling point. Explain your reasoning. CH3 CH2CH3 H3C CH3 ༣.མིའི་ན་བྱིན་ CH NH₂ -CH3 H₂ NH2 2. Which compound in each pair would have the higher boiling point? Why? a. H3C CH3 H3C OH b. NH2 CH3 H₂ H3C CH CH CH3 H3C -CH3 NH2 3. Circle each of the following molecules that would be significantly soluble in water. Explain. ΝΗΣ H₂ H₂ H₂ H₂ CH C- NH₂ H3C -CH3 H3C H2 H₂ CH3 CH CH3 H3C -CH3 H3C H₂arrow_forward
- Briefly discuss why increased chlorination of organic compounds increases the recalcitrance or stability of the molecule in the environment.arrow_forwardSome diazotrophs produce a vanadium-containing VFe protein in addition to the MoFe protein. The vanadium-containing nitrogenase converts N2 to NH3 and also converts CO to compounds such as ethane and propane. What aspect of the standard nitrogenase reaction is responsible for the production of alkanes?arrow_forwardWhy Nitrogen (or Argon) Gas Is Used as a Wine Preservative?arrow_forward
- Compound A has two functional groups and it will formed an oily yellow liquid when it reacts with nitrous acid. They discovered that compound B is produced during the halogenation process of compound A. When compound B is reacted with nitric acid, compound C is formed. While Friedel Crafts alkylation of compoundAproduces compoundD. CompoundE was produced by Friedel Crafts acylation of compound A. This compound E reacts positively with alkaline iodine and 2,4-dinitrophenylhydrazine. However, it returns negative results for Tollens' and Benedict's tests. (a) Illutsrate the potential carbon-13 NMR spectrum for compound A. (b) Identify the possible structural formula of compound A (according to the carbon type) based on your proposed 13C NMR spectrum. (c) Predict the possible structural formula compounds B to E. The carbon atoms for compound A should more than SIX (6). (d) Distinguish between compound A with benzenedizonium chloride. (e) Predict the possible chemical reaction for…arrow_forward4) Alpha carotene has an Rf value of .97. Explain the significance of this value in terms of the relationship between the pigment and solvent front migration rates. What is the maximum value for Rf?arrow_forwardSelect the product for the following cyclization CHO OH OH OH H OH OH Но HO HO OH но Но - OH HO HO Но. OH H- OH OH H H H ČH2OH 1 3 О 1&2 1 2arrow_forward
- What is meant by recalcitrance,give an example and briefly discuss why increased chlorination of organic compounds increases the recalcitrance or stability of the molecule in the environment.arrow_forwardWhat is the product of intramolecular dehydration of pentanol-2 CH3CH(OH)CH2CH2CH3? Select one:a. Pentene-2b. Pentene-3c. Pentene-1d. Pentanearrow_forwardChoose the correct product for the following Diels-Alder reaction. OEt OEt product OEt OEt OEt OEt OEt OH OH of of off of A B C OEt D E O Targets placed: 0/3 You can place up to 3 targets Undo Delete selected Remove Allarrow_forward