EBK GENERAL, ORGANIC, AND BIOLOGICAL CH
7th Edition
ISBN: 8220100853180
Author: STOKER
Publisher: CENGAGE L
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Chapter 13.12, Problem 4QQ
Interpretation Introduction
Interpretation:
The isomerism that is not possible for
Concept Introduction:
Alkyne contain a triple bond. The spatial arrangement of carbon atom that is bonded by the triple bond is linear. Due to this linearity, cis‑trans isomerism is not possible at all. The same cis‑trans isomerism is found in
Skeletal isomers and positional isomers are possible for alkynes.
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H
OH
CH2OH
D
H
ОН
H
الحزن
ОН
CH2OH
ОН
H
ОН I
Which of the following statements correctly describes this structure?
(A) The monomer units are bonded by beta 1-2 glycosidic linkage.
B
The monomer units are bonded by alpha 1-2 glycosidic linkage.
The monomer units are bonded by alpha 1-4 glycosidic linkage.
The monomer units are bonded by beta 1-4 glycosidic linkage.
H
CH2OH
H
ОН
H
ОН
H
ОН
Classify the following lipid (choose all that apply for the overall structure, not the individual residues).
a. wax ester
b. fatty acid
c. polyunsaturated
d. trans alkene(s)
e. steroid
f. monounsaturated
g. triglyceride
h. cis alkene(s)
i. saturated
Consider the structure of the tripeptide (in its fully protonated form) below.
H
H
H
+ I ||
H₂N-C-C-N-C-C-N-C-C-OH
1
I |
H CH₂ H CH₂
CH₂
T
C=O
OH
AA1
0=0
||
HC-CH3
CH3
AA2
AA3
0=C
1. Give the sequence of the tripeptide using the ONE-LETTER DESIGNATION (UPPERCASE LETTER) with NO spaces and symbols between each letter.
2. How many ionizable groups are there in the tripeptide? Give the numerical value (e.g., 10 not ten).
• pH 10: {Choices: -2, -1, 0, +1, +2}
3. Which amino acid residue has one ionizable group left upon forming the tripeptide? {Choices: AA1, AA2, AA3, none, all}
4. Give the net charge of the dominant structure of the tripeptide at the given pH values. The pK, values of the amino acids are given in Table 1.
• pH 4: {Choices: -2, -1, 0, +1, +2}
Chapter 13 Solutions
EBK GENERAL, ORGANIC, AND BIOLOGICAL CH
Ch. 13.1 - Prob. 1QQCh. 13.1 - Prob. 2QQCh. 13.1 - Prob. 3QQCh. 13.2 - Prob. 1QQCh. 13.2 - Prob. 2QQCh. 13.2 - Prob. 3QQCh. 13.2 - Prob. 4QQCh. 13.3 - Prob. 1QQCh. 13.3 - Prob. 2QQCh. 13.3 - Prob. 3QQ
Ch. 13.3 - Prob. 4QQCh. 13.4 - Prob. 1QQCh. 13.4 - Prob. 2QQCh. 13.5 - Prob. 1QQCh. 13.5 - Prob. 2QQCh. 13.5 - Prob. 3QQCh. 13.6 - Prob. 1QQCh. 13.6 - Prob. 2QQCh. 13.6 - Prob. 3QQCh. 13.7 - Prob. 1QQCh. 13.7 - Prob. 2QQCh. 13.7 - Prob. 3QQCh. 13.8 - Prob. 1QQCh. 13.8 - Prob. 2QQCh. 13.9 - Prob. 1QQCh. 13.9 - Prob. 2QQCh. 13.10 - Prob. 1QQCh. 13.10 - Prob. 2QQCh. 13.10 - Prob. 3QQCh. 13.10 - Prob. 4QQCh. 13.10 - Prob. 5QQCh. 13.11 - Prob. 1QQCh. 13.11 - Prob. 2QQCh. 13.11 - Prob. 3QQCh. 13.11 - Prob. 4QQCh. 13.11 - Prob. 5QQCh. 13.12 - Prob. 1QQCh. 13.12 - Prob. 2QQCh. 13.12 - Prob. 3QQCh. 13.12 - Prob. 4QQCh. 13.12 - Prob. 5QQCh. 13.13 - Prob. 1QQCh. 13.13 - Prob. 2QQCh. 13.13 - Prob. 3QQCh. 13.14 - Prob. 1QQCh. 13.14 - Prob. 2QQCh. 13.14 - Prob. 3QQCh. 13.14 - Prob. 4QQCh. 13.15 - Prob. 1QQCh. 13.15 - Prob. 2QQCh. 13.15 - Prob. 3QQCh. 13.15 - Prob. 4QQCh. 13.16 - Prob. 1QQCh. 13.16 - Prob. 2QQCh. 13 - Classify each of the following hydrocarbons as...Ch. 13 - Classify each of the following hydrocarbons as...Ch. 13 - Prob. 13.3EPCh. 13 - Prob. 13.4EPCh. 13 - Prob. 13.5EPCh. 13 - Prob. 13.6EPCh. 13 - Prob. 13.7EPCh. 13 - Prob. 13.8EPCh. 13 - Prob. 13.9EPCh. 13 - What is the molecular formula for each of the...Ch. 13 - Prob. 13.11EPCh. 13 - Prob. 13.12EPCh. 13 - What is wrong, if anything, with the following...Ch. 13 - Prob. 13.14EPCh. 13 - Prob. 13.15EPCh. 13 - Prob. 13.16EPCh. 13 - Prob. 13.17EPCh. 13 - Prob. 13.18EPCh. 13 - Draw a condensed structural formula for each of...Ch. 13 - Draw a condensed structural formula for each of...Ch. 13 - The following names are incorrect by IUPAC rules....Ch. 13 - The following names are incorrect by IUPAC rules....Ch. 13 - Prob. 13.23EPCh. 13 - Prob. 13.24EPCh. 13 - Prob. 13.25EPCh. 13 - Classify each of the following compounds as...Ch. 13 - Prob. 13.27EPCh. 13 - How many hydrogen atoms are present in a molecule...Ch. 13 - Prob. 13.29EPCh. 13 - Draw a line-angle structural formula for each of...Ch. 13 - Prob. 13.31EPCh. 13 - Prob. 13.32EPCh. 13 - Prob. 13.33EPCh. 13 - Prob. 13.34EPCh. 13 - Prob. 13.35EPCh. 13 - Prob. 13.36EPCh. 13 - Prob. 13.37EPCh. 13 - Prob. 13.38EPCh. 13 - For each of the following pairs of alkenes,...Ch. 13 - Prob. 13.40EPCh. 13 - Prob. 13.41EPCh. 13 - Prob. 13.42EPCh. 13 - Prob. 13.43EPCh. 13 - Prob. 13.44EPCh. 13 - Prob. 13.45EPCh. 13 - Prob. 13.46EPCh. 13 - For each molecule, indicate whether cistrans...Ch. 13 - For each molecule, indicate whether cistrans...Ch. 13 - Prob. 13.49EPCh. 13 - Prob. 13.50EPCh. 13 - Prob. 13.51EPCh. 13 - Draw a structural formula for each of the...Ch. 13 - Prob. 13.53EPCh. 13 - Prob. 13.54EPCh. 13 - Prob. 13.55EPCh. 13 - Prob. 13.56EPCh. 13 - Prob. 13.57EPCh. 13 - Prob. 13.58EPCh. 13 - Why is the number of carbon atoms in a terpene...Ch. 13 - How many isoprene units are present in a....Ch. 13 - Prob. 13.61EPCh. 13 - Indicate whether each of the following statements...Ch. 13 - Prob. 13.63EPCh. 13 - With the help of Figure 13-7, indicate whether...Ch. 13 - Prob. 13.65EPCh. 13 - Prob. 13.66EPCh. 13 - Prob. 13.67EPCh. 13 - Prob. 13.68EPCh. 13 - Prob. 13.69EPCh. 13 - Prob. 13.70EPCh. 13 - Prob. 13.71EPCh. 13 - Prob. 13.72EPCh. 13 - Prob. 13.73EPCh. 13 - Prob. 13.74EPCh. 13 - Prob. 13.75EPCh. 13 - Write a chemical equation showing reactants,...Ch. 13 - Supply the structural formula of the product in...Ch. 13 - Prob. 13.78EPCh. 13 - What reactant would you use to prepare each of the...Ch. 13 - Prob. 13.80EPCh. 13 - Prob. 13.81EPCh. 13 - Prob. 13.82EPCh. 13 - Prob. 13.83EPCh. 13 - Prob. 13.84EPCh. 13 - Prob. 13.85EPCh. 13 - Prob. 13.86EPCh. 13 - Prob. 13.87EPCh. 13 - Prob. 13.88EPCh. 13 - Prob. 13.89EPCh. 13 - Prob. 13.90EPCh. 13 - Prob. 13.91EPCh. 13 - Prob. 13.92EPCh. 13 - Prob. 13.93EPCh. 13 - What are the bond angles about the triple bond in...Ch. 13 - Prob. 13.95EPCh. 13 - Prob. 13.96EPCh. 13 - Prob. 13.97EPCh. 13 - Prob. 13.98EPCh. 13 - Prob. 13.99EPCh. 13 - Prob. 13.100EPCh. 13 - Prob. 13.101EPCh. 13 - Prob. 13.102EPCh. 13 - Prob. 13.103EPCh. 13 - Prob. 13.104EPCh. 13 - Prob. 13.105EPCh. 13 - Prob. 13.106EPCh. 13 - Prob. 13.107EPCh. 13 - Prob. 13.108EPCh. 13 - Assign each of the compounds in Problem 13-107 an...Ch. 13 - Assign each of the compounds in Problem 13-108 an...Ch. 13 - Prob. 13.111EPCh. 13 - Prob. 13.112EPCh. 13 - Prob. 13.113EPCh. 13 - Prob. 13.114EPCh. 13 - Prob. 13.115EPCh. 13 - Write a structural formula for each of the...Ch. 13 - Eight isomeric substituted benzenes have the...Ch. 13 - Prob. 13.118EPCh. 13 - Prob. 13.119EPCh. 13 - Prob. 13.120EPCh. 13 - Prob. 13.121EPCh. 13 - Prob. 13.122EPCh. 13 - Prob. 13.123EPCh. 13 - Prob. 13.124EPCh. 13 - Prob. 13.125EPCh. 13 - For each of the following classes of compounds,...Ch. 13 - Prob. 13.127EPCh. 13 - Prob. 13.128EPCh. 13 - Prob. 13.129EPCh. 13 - Prob. 13.130EP
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