The products of reductive amination of the given compounds are to be predicted. Concept introduction: When an aldehyde or a ketone is converted to an amine , the process is known as reductive amination. The conversion takes place through the formation of an intermediate known as imine. Reductive amination is also known as reductive alkylation.

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Answer 1

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Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 19, Problem 19.63SP

(a)

Interpretation Introduction

Interpretation:

The products of reductive amination of the given compounds are to be predicted.

Concept introduction:

When an aldehyde or a ketone is converted to an amine, the process is known as reductive amination. The conversion takes place through the formation of an intermediate known as imine. Reductive amination is also known as reductive alkylation.

(b)

Interpretation Introduction

Interpretation:

The products of reductive amination of the given compounds are to be predicted.

Concept introduction:

When an aldehyde or a ketone is converted to an amine, the process is known as reductive amination. The conversion takes place through the formation of an intermediate known as imine. Reductive amination is also known as reductive alkylation.

(c)

Interpretation Introduction

Interpretation:

The products of reductive amination of the given compounds are to be predicted.

Concept introduction:

When an aldehyde or a ketone is converted to an amine, the process is known as reductive amination. The conversion takes place through the formation of an intermediate known as imine. Reductive amination is also known as reductive alkylation.

(d)

Interpretation Introduction

Interpretation:

The products of reductive amination of the given compounds are to be predicted.

Concept introduction:

When an aldehyde or a ketone is converted to an amine, the process is known as reductive amination. The conversion takes place through the formation of an intermediate known as imine. Reductive amination is also known as reductive alkylation.

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Which of the following alcohols will give a carboxylic acid product when reacted with K2Cr2O7? 2-Butanol Methanol Tert-butyl-alcohol All of these will be oxidized to carboxylic acids. 2. Aromatic amines are _________ acidic, but stronger than the aliphatic amines are unique as they do not behave like any of the other amines neutral because of the polarity basic, but weaker than aliphatic amines 3. Which of the following is true of the Fischer esterification reactions? It is an equilibrium reaction that can never be driven far to the right. It proceeds until the limiting reagent is completely used up. It is an equilibrium reaction that can be driven to the right by the addition of water. It is an equilibrium reaction that can be driven to the right by the removal of water.

Hinsberg's Method to determine, 1°, 2°, 3° amines. Draw the structure of the products of the following reactions. Aniline (1°) + BSC, excess NaOH (DRAW STRUCTURE), then + HCl (DRAW STRUCTURE) Diethylamine (2°)+ BSC, excess NaOH (DRAW STRUCTURE), then + HCl (DRAW STRUCTURE) Triethylamine (3°)+ BSC, excess NaOH(DRAW STRUCTURE), then + HCl (DRAW STRUCTURE)

Considering Hinsberg's Method to determine, 1°, 2°, 3° amines. Draw the structure of the products of the following reactions. Aniline (1°) + BSC, excess NaOH(DRAW STRUCTURE), then, + HCl (DRAW STRUCTURE) Diethylamine (2°)+ BSC, excess NaOH (DRAW STRUCTURE), then, + HCl (DRAW STRUCTURE) Triethylamine (3°)+ BSC, excess NaOH(DRAW STRUCTURE), then, + HCl (DRAW STRUCTURE)

Answer 2

Question

Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 19, Problem 19.63SP

(a)

Interpretation Introduction

Interpretation:

The products of reductive amination of the given compounds are to be predicted.

Concept introduction:

When an aldehyde or a ketone is converted to an amine, the process is known as reductive amination. The conversion takes place through the formation of an intermediate known as imine. Reductive amination is also known as reductive alkylation.

(b)

Interpretation Introduction

Interpretation:

The products of reductive amination of the given compounds are to be predicted.

Concept introduction:

When an aldehyde or a ketone is converted to an amine, the process is known as reductive amination. The conversion takes place through the formation of an intermediate known as imine. Reductive amination is also known as reductive alkylation.

(c)

Interpretation Introduction

Interpretation:

The products of reductive amination of the given compounds are to be predicted.

Concept introduction:

When an aldehyde or a ketone is converted to an amine, the process is known as reductive amination. The conversion takes place through the formation of an intermediate known as imine. Reductive amination is also known as reductive alkylation.

(d)

Interpretation Introduction

Interpretation:

The products of reductive amination of the given compounds are to be predicted.

Concept introduction:

When an aldehyde or a ketone is converted to an amine, the process is known as reductive amination. The conversion takes place through the formation of an intermediate known as imine. Reductive amination is also known as reductive alkylation.

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Answer 3

Question

Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 19, Problem 19.63SP

(a)

Interpretation Introduction

Interpretation:

The products of reductive amination of the given compounds are to be predicted.

Concept introduction:

When an aldehyde or a ketone is converted to an amine, the process is known as reductive amination. The conversion takes place through the formation of an intermediate known as imine. Reductive amination is also known as reductive alkylation.

(b)

Interpretation Introduction

Interpretation:

The products of reductive amination of the given compounds are to be predicted.

Concept introduction:

When an aldehyde or a ketone is converted to an amine, the process is known as reductive amination. The conversion takes place through the formation of an intermediate known as imine. Reductive amination is also known as reductive alkylation.

(c)

Interpretation Introduction

Interpretation:

The products of reductive amination of the given compounds are to be predicted.

Concept introduction:

When an aldehyde or a ketone is converted to an amine, the process is known as reductive amination. The conversion takes place through the formation of an intermediate known as imine. Reductive amination is also known as reductive alkylation.

(d)

Interpretation Introduction

Interpretation:

The products of reductive amination of the given compounds are to be predicted.

Concept introduction:

When an aldehyde or a ketone is converted to an amine, the process is known as reductive amination. The conversion takes place through the formation of an intermediate known as imine. Reductive amination is also known as reductive alkylation.

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Answer 4

Question

Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 19, Problem 19.63SP

(a)

Interpretation Introduction

Interpretation:

The products of reductive amination of the given compounds are to be predicted.

Concept introduction:

When an aldehyde or a ketone is converted to an amine, the process is known as reductive amination. The conversion takes place through the formation of an intermediate known as imine. Reductive amination is also known as reductive alkylation.

(b)

Interpretation Introduction

Interpretation:

The products of reductive amination of the given compounds are to be predicted.

Concept introduction:

When an aldehyde or a ketone is converted to an amine, the process is known as reductive amination. The conversion takes place through the formation of an intermediate known as imine. Reductive amination is also known as reductive alkylation.

(c)

Interpretation Introduction

Interpretation:

The products of reductive amination of the given compounds are to be predicted.

Concept introduction:

When an aldehyde or a ketone is converted to an amine, the process is known as reductive amination. The conversion takes place through the formation of an intermediate known as imine. Reductive amination is also known as reductive alkylation.

(d)

Interpretation Introduction

Interpretation:

The products of reductive amination of the given compounds are to be predicted.

Concept introduction:

When an aldehyde or a ketone is converted to an amine, the process is known as reductive amination. The conversion takes place through the formation of an intermediate known as imine. Reductive amination is also known as reductive alkylation.

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Answer 5

Chapter 19, Problem 19.63SP

(a)

Interpretation Introduction

Interpretation:

The products of reductive amination of the given compounds are to be predicted.

Concept introduction:

When an aldehyde or a ketone is converted to an amine, the process is known as reductive amination. The conversion takes place through the formation of an intermediate known as imine. Reductive amination is also known as reductive alkylation.

(b)

Interpretation Introduction

Interpretation:

The products of reductive amination of the given compounds are to be predicted.

Concept introduction:

When an aldehyde or a ketone is converted to an amine, the process is known as reductive amination. The conversion takes place through the formation of an intermediate known as imine. Reductive amination is also known as reductive alkylation.

(c)

Interpretation Introduction

Interpretation:

The products of reductive amination of the given compounds are to be predicted.

Concept introduction:

When an aldehyde or a ketone is converted to an amine, the process is known as reductive amination. The conversion takes place through the formation of an intermediate known as imine. Reductive amination is also known as reductive alkylation.

(d)

Interpretation Introduction

Interpretation:

The products of reductive amination of the given compounds are to be predicted.

Concept introduction:

When an aldehyde or a ketone is converted to an amine, the process is known as reductive amination. The conversion takes place through the formation of an intermediate known as imine. Reductive amination is also known as reductive alkylation.

Answer 6

Chapter 19, Problem 19.63SP

(a)

Interpretation Introduction

Interpretation:

The products of reductive amination of the given compounds are to be predicted.

Concept introduction:

When an aldehyde or a ketone is converted to an amine, the process is known as reductive amination. The conversion takes place through the formation of an intermediate known as imine. Reductive amination is also known as reductive alkylation.

Answer 7

Chapter 19, Problem 19.63SP

(a)

Interpretation Introduction

Interpretation:

The products of reductive amination of the given compounds are to be predicted.

Concept introduction:

When an aldehyde or a ketone is converted to an amine, the process is known as reductive amination. The conversion takes place through the formation of an intermediate known as imine. Reductive amination is also known as reductive alkylation.

Answer 8

(b)

Interpretation Introduction

Interpretation:

The products of reductive amination of the given compounds are to be predicted.

Concept introduction:

When an aldehyde or a ketone is converted to an amine, the process is known as reductive amination. The conversion takes place through the formation of an intermediate known as imine. Reductive amination is also known as reductive alkylation.

Answer 9

(b)

Interpretation Introduction

Interpretation:

The products of reductive amination of the given compounds are to be predicted.

Concept introduction:

When an aldehyde or a ketone is converted to an amine, the process is known as reductive amination. The conversion takes place through the formation of an intermediate known as imine. Reductive amination is also known as reductive alkylation.

Answer 10

(c)

Interpretation Introduction

Interpretation:

The products of reductive amination of the given compounds are to be predicted.

Concept introduction:

When an aldehyde or a ketone is converted to an amine, the process is known as reductive amination. The conversion takes place through the formation of an intermediate known as imine. Reductive amination is also known as reductive alkylation.

Answer 11

(c)

Interpretation Introduction

Interpretation:

The products of reductive amination of the given compounds are to be predicted.

Concept introduction:

When an aldehyde or a ketone is converted to an amine, the process is known as reductive amination. The conversion takes place through the formation of an intermediate known as imine. Reductive amination is also known as reductive alkylation.

Answer 12

(d)

Interpretation Introduction

Interpretation:

The products of reductive amination of the given compounds are to be predicted.

Concept introduction:

When an aldehyde or a ketone is converted to an amine, the process is known as reductive amination. The conversion takes place through the formation of an intermediate known as imine. Reductive amination is also known as reductive alkylation.

Answer 13

(d)

Interpretation Introduction

Interpretation:

The products of reductive amination of the given compounds are to be predicted.

Concept introduction:

When an aldehyde or a ketone is converted to an amine, the process is known as reductive amination. The conversion takes place through the formation of an intermediate known as imine. Reductive amination is also known as reductive alkylation.

Answer 14

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Answer 15

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Answer 16

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Answer 17

Ch. 19.2A - Prob. 19.1P Ch. 19.2B - Prob. 19.2P Ch. 19.2B - Give correct names for the following amines:Ch. 19.3 - Prob. 19.4P Ch. 19.4 - Prob. 19.5P Ch. 19.6 - Rank each set of compounds in order of increasing...Ch. 19.8A - Prob. 19.7P Ch. 19.8C - Prob. 19.8P Ch. 19.8C - Prob. 19.9P Ch. 19.8D - a. Show how fragmentation occurs to give the base...

Solution Summary: The author explains the process of reductive amination, which takes place through the formation of an intermediate known as imine.

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