The amines which can be resolved into enantiomers are to be identified and the reason for the interconversion of the enantiomers takes place or not is to be explained. Concept introduction: Enantiomers of a compound are the stereoisomers which are non-super imposable mirror images. A carbon atom bonded to four different groups is known as a chiral carbon. A compound which has a chiral carbon can be resolved into enantiomers.

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Answer 1

Question

Chapter 19.3, Problem 19.4P

(a)

Interpretation Introduction

Interpretation:

The amines which can be resolved into enantiomers are to be identified and the reason for the interconversion of the enantiomers takes place or not is to be explained.

Concept introduction:

Enantiomers of a compound are the stereoisomers which are non-super imposable mirror images. A carbon atom bonded to four different groups is known as a chiral carbon. A compound which has a chiral carbon can be resolved into enantiomers.

(b)

Interpretation Introduction

Interpretation:

The amines which can be resolved into enantiomers are to be identified and the reason for the interconversion of the enantiomers takes place or not is to be explained.

Concept introduction:

Enantiomers of a compound are the stereoisomers which are non-super imposable mirror images. A carbon atom bonded to four different groups is known as a chiral carbon. A compound which has a chiral carbon can be resolved into enantiomers.

(c)

Interpretation Introduction

Interpretation:

The amines which can be resolved into enantiomers are to be identified and the reason for the interconversion of the enantiomers takes place or not is to be explained.

Concept introduction:

Enantiomers of a compound are the stereoisomers which are non-super imposable mirror images. A carbon atom bonded to four different groups is known as a chiral carbon. A compound which has a chiral carbon can be resolved into enantiomers.

(d)

Interpretation Introduction

Interpretation:

The amines which can be resolved into enantiomers are to be identified and the reason for the interconversion of the enantiomers takes place or not is to be explained.

Concept introduction:

Enantiomers of a compound are the stereoisomers which are non-super imposable mirror images. A carbon atom bonded to four different groups is known as a chiral carbon. A compound which has a chiral carbon can be resolved into enantiomers.

(e)

Interpretation Introduction

Interpretation:

The amines which can be resolved into enantiomers are to be identified and the reason for the interconversion of the enantiomers takes place or not is to be explained.

Concept introduction:

Enantiomers of a compound are the stereoisomers which are non-super imposable mirror images. A carbon atom bonded to four different groups is known as a chiral carbon. A compound which has a chiral carbon can be resolved into enantiomers.

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Draw the possible stereoisomers of 2-methylocta-4,6-dien-1-amine. Note that E-, Z- isomers of each stereoisomer are also possible and would not be accounted for by the formula above; draw any E- or Z- isomers.

(i) Why do actinoids show wide range of oxidation states? (ii) Why is actinoid contraction greater than lanthanoid contraction?

Why do you wash the dichloromethane solution of your reductive amination product with sodium bicarbonate, rather than dilute aqueous HCl? a) Sodium bicarbonate is a good method of removing aldehydes from organic solvent.b) The amine product will be protonated by acid and remain in the aqueous layer as a salt.c) Sodium bicarbonate transfers the amine starting material into the aqueous layer.d) Sodium bicarbonate reacts with leftover NaBH(OAc)3 and removes it from the mixture.

Answer 2

Question

Chapter 19.3, Problem 19.4P

(a)

Interpretation Introduction

Interpretation:

The amines which can be resolved into enantiomers are to be identified and the reason for the interconversion of the enantiomers takes place or not is to be explained.

Concept introduction:

Enantiomers of a compound are the stereoisomers which are non-super imposable mirror images. A carbon atom bonded to four different groups is known as a chiral carbon. A compound which has a chiral carbon can be resolved into enantiomers.

(b)

Interpretation Introduction

Interpretation:

The amines which can be resolved into enantiomers are to be identified and the reason for the interconversion of the enantiomers takes place or not is to be explained.

Concept introduction:

Enantiomers of a compound are the stereoisomers which are non-super imposable mirror images. A carbon atom bonded to four different groups is known as a chiral carbon. A compound which has a chiral carbon can be resolved into enantiomers.

(c)

Interpretation Introduction

Interpretation:

The amines which can be resolved into enantiomers are to be identified and the reason for the interconversion of the enantiomers takes place or not is to be explained.

Concept introduction:

Enantiomers of a compound are the stereoisomers which are non-super imposable mirror images. A carbon atom bonded to four different groups is known as a chiral carbon. A compound which has a chiral carbon can be resolved into enantiomers.

(d)

Interpretation Introduction

Interpretation:

The amines which can be resolved into enantiomers are to be identified and the reason for the interconversion of the enantiomers takes place or not is to be explained.

Concept introduction:

Enantiomers of a compound are the stereoisomers which are non-super imposable mirror images. A carbon atom bonded to four different groups is known as a chiral carbon. A compound which has a chiral carbon can be resolved into enantiomers.

(e)

Interpretation Introduction

Interpretation:

The amines which can be resolved into enantiomers are to be identified and the reason for the interconversion of the enantiomers takes place or not is to be explained.

Concept introduction:

Enantiomers of a compound are the stereoisomers which are non-super imposable mirror images. A carbon atom bonded to four different groups is known as a chiral carbon. A compound which has a chiral carbon can be resolved into enantiomers.

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Answer 3

Question

Chapter 19.3, Problem 19.4P

(a)

Interpretation Introduction

Interpretation:

The amines which can be resolved into enantiomers are to be identified and the reason for the interconversion of the enantiomers takes place or not is to be explained.

Concept introduction:

Enantiomers of a compound are the stereoisomers which are non-super imposable mirror images. A carbon atom bonded to four different groups is known as a chiral carbon. A compound which has a chiral carbon can be resolved into enantiomers.

(b)

Interpretation Introduction

Interpretation:

The amines which can be resolved into enantiomers are to be identified and the reason for the interconversion of the enantiomers takes place or not is to be explained.

Concept introduction:

Enantiomers of a compound are the stereoisomers which are non-super imposable mirror images. A carbon atom bonded to four different groups is known as a chiral carbon. A compound which has a chiral carbon can be resolved into enantiomers.

(c)

Interpretation Introduction

Interpretation:

The amines which can be resolved into enantiomers are to be identified and the reason for the interconversion of the enantiomers takes place or not is to be explained.

Concept introduction:

Enantiomers of a compound are the stereoisomers which are non-super imposable mirror images. A carbon atom bonded to four different groups is known as a chiral carbon. A compound which has a chiral carbon can be resolved into enantiomers.

(d)

Interpretation Introduction

Interpretation:

The amines which can be resolved into enantiomers are to be identified and the reason for the interconversion of the enantiomers takes place or not is to be explained.

Concept introduction:

Enantiomers of a compound are the stereoisomers which are non-super imposable mirror images. A carbon atom bonded to four different groups is known as a chiral carbon. A compound which has a chiral carbon can be resolved into enantiomers.

(e)

Interpretation Introduction

Interpretation:

The amines which can be resolved into enantiomers are to be identified and the reason for the interconversion of the enantiomers takes place or not is to be explained.

Concept introduction:

Enantiomers of a compound are the stereoisomers which are non-super imposable mirror images. A carbon atom bonded to four different groups is known as a chiral carbon. A compound which has a chiral carbon can be resolved into enantiomers.

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Answer 4

Question

Chapter 19.3, Problem 19.4P

(a)

Interpretation Introduction

Interpretation:

The amines which can be resolved into enantiomers are to be identified and the reason for the interconversion of the enantiomers takes place or not is to be explained.

Concept introduction:

Enantiomers of a compound are the stereoisomers which are non-super imposable mirror images. A carbon atom bonded to four different groups is known as a chiral carbon. A compound which has a chiral carbon can be resolved into enantiomers.

(b)

Interpretation Introduction

Interpretation:

The amines which can be resolved into enantiomers are to be identified and the reason for the interconversion of the enantiomers takes place or not is to be explained.

Concept introduction:

Enantiomers of a compound are the stereoisomers which are non-super imposable mirror images. A carbon atom bonded to four different groups is known as a chiral carbon. A compound which has a chiral carbon can be resolved into enantiomers.

(c)

Interpretation Introduction

Interpretation:

The amines which can be resolved into enantiomers are to be identified and the reason for the interconversion of the enantiomers takes place or not is to be explained.

Concept introduction:

Enantiomers of a compound are the stereoisomers which are non-super imposable mirror images. A carbon atom bonded to four different groups is known as a chiral carbon. A compound which has a chiral carbon can be resolved into enantiomers.

(d)

Interpretation Introduction

Interpretation:

The amines which can be resolved into enantiomers are to be identified and the reason for the interconversion of the enantiomers takes place or not is to be explained.

Concept introduction:

Enantiomers of a compound are the stereoisomers which are non-super imposable mirror images. A carbon atom bonded to four different groups is known as a chiral carbon. A compound which has a chiral carbon can be resolved into enantiomers.

(e)

Interpretation Introduction

Interpretation:

The amines which can be resolved into enantiomers are to be identified and the reason for the interconversion of the enantiomers takes place or not is to be explained.

Concept introduction:

Enantiomers of a compound are the stereoisomers which are non-super imposable mirror images. A carbon atom bonded to four different groups is known as a chiral carbon. A compound which has a chiral carbon can be resolved into enantiomers.

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Answer 5

Chapter 19.3, Problem 19.4P

(a)

Interpretation Introduction

Interpretation:

The amines which can be resolved into enantiomers are to be identified and the reason for the interconversion of the enantiomers takes place or not is to be explained.

Concept introduction:

Enantiomers of a compound are the stereoisomers which are non-super imposable mirror images. A carbon atom bonded to four different groups is known as a chiral carbon. A compound which has a chiral carbon can be resolved into enantiomers.

(b)

Interpretation Introduction

Interpretation:

The amines which can be resolved into enantiomers are to be identified and the reason for the interconversion of the enantiomers takes place or not is to be explained.

Concept introduction:

Enantiomers of a compound are the stereoisomers which are non-super imposable mirror images. A carbon atom bonded to four different groups is known as a chiral carbon. A compound which has a chiral carbon can be resolved into enantiomers.

(c)

Interpretation Introduction

Interpretation:

The amines which can be resolved into enantiomers are to be identified and the reason for the interconversion of the enantiomers takes place or not is to be explained.

Concept introduction:

Enantiomers of a compound are the stereoisomers which are non-super imposable mirror images. A carbon atom bonded to four different groups is known as a chiral carbon. A compound which has a chiral carbon can be resolved into enantiomers.

(d)

Interpretation Introduction

Interpretation:

The amines which can be resolved into enantiomers are to be identified and the reason for the interconversion of the enantiomers takes place or not is to be explained.

Concept introduction:

Enantiomers of a compound are the stereoisomers which are non-super imposable mirror images. A carbon atom bonded to four different groups is known as a chiral carbon. A compound which has a chiral carbon can be resolved into enantiomers.

(e)

Interpretation Introduction

Interpretation:

The amines which can be resolved into enantiomers are to be identified and the reason for the interconversion of the enantiomers takes place or not is to be explained.

Concept introduction:

Enantiomers of a compound are the stereoisomers which are non-super imposable mirror images. A carbon atom bonded to four different groups is known as a chiral carbon. A compound which has a chiral carbon can be resolved into enantiomers.

Answer 6

Chapter 19.3, Problem 19.4P

(a)

Interpretation Introduction

Interpretation:

The amines which can be resolved into enantiomers are to be identified and the reason for the interconversion of the enantiomers takes place or not is to be explained.

Concept introduction:

Enantiomers of a compound are the stereoisomers which are non-super imposable mirror images. A carbon atom bonded to four different groups is known as a chiral carbon. A compound which has a chiral carbon can be resolved into enantiomers.

Answer 7

Chapter 19.3, Problem 19.4P

(a)

Interpretation Introduction

Interpretation:

The amines which can be resolved into enantiomers are to be identified and the reason for the interconversion of the enantiomers takes place or not is to be explained.

Concept introduction:

Enantiomers of a compound are the stereoisomers which are non-super imposable mirror images. A carbon atom bonded to four different groups is known as a chiral carbon. A compound which has a chiral carbon can be resolved into enantiomers.

Answer 8

(b)

Interpretation Introduction

Interpretation:

The amines which can be resolved into enantiomers are to be identified and the reason for the interconversion of the enantiomers takes place or not is to be explained.

Concept introduction:

Enantiomers of a compound are the stereoisomers which are non-super imposable mirror images. A carbon atom bonded to four different groups is known as a chiral carbon. A compound which has a chiral carbon can be resolved into enantiomers.

Answer 9

(b)

Interpretation Introduction

Interpretation:

The amines which can be resolved into enantiomers are to be identified and the reason for the interconversion of the enantiomers takes place or not is to be explained.

Concept introduction:

Enantiomers of a compound are the stereoisomers which are non-super imposable mirror images. A carbon atom bonded to four different groups is known as a chiral carbon. A compound which has a chiral carbon can be resolved into enantiomers.

Answer 10

(c)

Interpretation Introduction

Interpretation:

The amines which can be resolved into enantiomers are to be identified and the reason for the interconversion of the enantiomers takes place or not is to be explained.

Concept introduction:

Enantiomers of a compound are the stereoisomers which are non-super imposable mirror images. A carbon atom bonded to four different groups is known as a chiral carbon. A compound which has a chiral carbon can be resolved into enantiomers.

Answer 11

(c)

Interpretation Introduction

Interpretation:

The amines which can be resolved into enantiomers are to be identified and the reason for the interconversion of the enantiomers takes place or not is to be explained.

Concept introduction:

Enantiomers of a compound are the stereoisomers which are non-super imposable mirror images. A carbon atom bonded to four different groups is known as a chiral carbon. A compound which has a chiral carbon can be resolved into enantiomers.

Answer 12

(d)

Interpretation Introduction

Interpretation:

The amines which can be resolved into enantiomers are to be identified and the reason for the interconversion of the enantiomers takes place or not is to be explained.

Concept introduction:

Enantiomers of a compound are the stereoisomers which are non-super imposable mirror images. A carbon atom bonded to four different groups is known as a chiral carbon. A compound which has a chiral carbon can be resolved into enantiomers.

Answer 13

(d)

Interpretation Introduction

Interpretation:

The amines which can be resolved into enantiomers are to be identified and the reason for the interconversion of the enantiomers takes place or not is to be explained.

Concept introduction:

Enantiomers of a compound are the stereoisomers which are non-super imposable mirror images. A carbon atom bonded to four different groups is known as a chiral carbon. A compound which has a chiral carbon can be resolved into enantiomers.

Answer 14

(e)

Interpretation Introduction

Interpretation:

The amines which can be resolved into enantiomers are to be identified and the reason for the interconversion of the enantiomers takes place or not is to be explained.

Concept introduction:

Enantiomers of a compound are the stereoisomers which are non-super imposable mirror images. A carbon atom bonded to four different groups is known as a chiral carbon. A compound which has a chiral carbon can be resolved into enantiomers.

Answer 15

(e)

Interpretation Introduction

Interpretation:

The amines which can be resolved into enantiomers are to be identified and the reason for the interconversion of the enantiomers takes place or not is to be explained.

Concept introduction:

Enantiomers of a compound are the stereoisomers which are non-super imposable mirror images. A carbon atom bonded to four different groups is known as a chiral carbon. A compound which has a chiral carbon can be resolved into enantiomers.

Answer 16

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Answer 17

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Answer 18

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Answer 19

Ch. 19.2A - Prob. 19.1P Ch. 19.2B - Prob. 19.2P Ch. 19.2B - Give correct names for the following amines:Ch. 19.3 - Prob. 19.4P Ch. 19.4 - Prob. 19.5P Ch. 19.6 - Rank each set of compounds in order of increasing...Ch. 19.8A - Prob. 19.7P Ch. 19.8C - Prob. 19.8P Ch. 19.8C - Prob. 19.9P Ch. 19.8D - a. Show how fragmentation occurs to give the base...

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Chapter 19 Solutions