The structure for the given IUPAC name has to be identified. Concept Introduction: Guidelines in drawing the structure from the given IUPAC name: The parent chain has to be identified by the root word. Illustration: Root word Parent chain identification ane Alkane ene Alkene yne Alkyne The substituents on the parent chain have to be identified by the primary suffix name. The substituent name always follows with a number which indicates at which carbon atom the substituent is attached on the parent chain. Illustration: Primary suffix Substituent identification methyl CH 3 ethyl CH 3 CH 2 isopropyl CH 3 CH 2 CH 3 The functional groups have to be identified by the secondary suffix name. The functional group name always follows with a number which indicates at which carbon atom the functional group is attached on the parent chain. Illustration: Functional group Functional group identification ol Alcohol al Aldehyde one Ketone Finally the structure can be drawn based on these identifications.

Question

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Answer 1

Question

Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 19.2, Problem 4ATS

(a)

Interpretation Introduction

Interpretation: The structure for the given IUPAC name has to be identified.

Concept Introduction:

Guidelines in drawing the structure from the given IUPAC name:

The parent chain has to be identified by the root word.

Illustration:

Root word Parent chain identification
ane Alkane
ene Alkene
yne Alkyne

The substituents on the parent chain have to be identified by the primary suffix name. The substituent name always follows with a number which indicates at which carbon atom the substituent is attached on the parent chain.

Illustration:

Primary suffix Substituent identification
methyl CH3
ethyl CH3CH2
isopropyl CH3CH2CH3

The functional groups have to be identified by the secondary suffix name. The functional group name always follows with a number which indicates at which carbon atom the functional group is attached on the parent chain.

Illustration:

Functional group Functional group identification
ol Alcohol
al Aldehyde
one Ketone

Finally the structure can be drawn based on these identifications.

(b)

Interpretation Introduction

Interpretation: The structure for the given IUPAC name has to be identified.

Concept Introduction:

Guidelines in drawing the structure from the given IUPAC name:

The parent chain has to be identified by the root word.

Illustration:

Root word Parent chain identification
ane Alkane
ene Alkene
yne Alkyne

The substituents on the parent chain have to be identified by the primary suffix name. The substituent name always follows with a number which indicates at which carbon atom the substituent is attached on the parent chain.

Illustration:

Primary suffix Substituent identification
methyl CH3
ethyl CH3CH2
isopropyl CH3CH2CH3

The functional groups have to be identified by the secondary suffix name. The functional group name always follows with a number which indicates at which carbon atom the functional group is attached on the parent chain.

Illustration:

Functional group Functional group identification
ol Alcohol
al Aldehyde
one Ketone

Finally the structure can be drawn based on these identifications.

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Answer 2

Question

Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 19.2, Problem 4ATS

(a)

Interpretation Introduction

Interpretation: The structure for the given IUPAC name has to be identified.

Concept Introduction:

Guidelines in drawing the structure from the given IUPAC name:

The parent chain has to be identified by the root word.

Illustration:

Root word Parent chain identification
ane Alkane
ene Alkene
yne Alkyne

The substituents on the parent chain have to be identified by the primary suffix name. The substituent name always follows with a number which indicates at which carbon atom the substituent is attached on the parent chain.

Illustration:

Primary suffix Substituent identification
methyl CH3
ethyl CH3CH2
isopropyl CH3CH2CH3

The functional groups have to be identified by the secondary suffix name. The functional group name always follows with a number which indicates at which carbon atom the functional group is attached on the parent chain.

Illustration:

Functional group Functional group identification
ol Alcohol
al Aldehyde
one Ketone

Finally the structure can be drawn based on these identifications.

(b)

Interpretation Introduction

Interpretation: The structure for the given IUPAC name has to be identified.

Concept Introduction:

Guidelines in drawing the structure from the given IUPAC name:

The parent chain has to be identified by the root word.

Illustration:

Root word Parent chain identification
ane Alkane
ene Alkene
yne Alkyne

The substituents on the parent chain have to be identified by the primary suffix name. The substituent name always follows with a number which indicates at which carbon atom the substituent is attached on the parent chain.

Illustration:

Primary suffix Substituent identification
methyl CH3
ethyl CH3CH2
isopropyl CH3CH2CH3

The functional groups have to be identified by the secondary suffix name. The functional group name always follows with a number which indicates at which carbon atom the functional group is attached on the parent chain.

Illustration:

Functional group Functional group identification
ol Alcohol
al Aldehyde
one Ketone

Finally the structure can be drawn based on these identifications.

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Answer 3

Question

Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 19.2, Problem 4ATS

(a)

Interpretation Introduction

Interpretation: The structure for the given IUPAC name has to be identified.

Concept Introduction:

Guidelines in drawing the structure from the given IUPAC name:

The parent chain has to be identified by the root word.

Illustration:

Root word Parent chain identification
ane Alkane
ene Alkene
yne Alkyne

The substituents on the parent chain have to be identified by the primary suffix name. The substituent name always follows with a number which indicates at which carbon atom the substituent is attached on the parent chain.

Illustration:

Primary suffix Substituent identification
methyl CH3
ethyl CH3CH2
isopropyl CH3CH2CH3

The functional groups have to be identified by the secondary suffix name. The functional group name always follows with a number which indicates at which carbon atom the functional group is attached on the parent chain.

Illustration:

Functional group Functional group identification
ol Alcohol
al Aldehyde
one Ketone

Finally the structure can be drawn based on these identifications.

(b)

Interpretation Introduction

Interpretation: The structure for the given IUPAC name has to be identified.

Concept Introduction:

Guidelines in drawing the structure from the given IUPAC name:

The parent chain has to be identified by the root word.

Illustration:

Root word Parent chain identification
ane Alkane
ene Alkene
yne Alkyne

The substituents on the parent chain have to be identified by the primary suffix name. The substituent name always follows with a number which indicates at which carbon atom the substituent is attached on the parent chain.

Illustration:

Primary suffix Substituent identification
methyl CH3
ethyl CH3CH2
isopropyl CH3CH2CH3

The functional groups have to be identified by the secondary suffix name. The functional group name always follows with a number which indicates at which carbon atom the functional group is attached on the parent chain.

Illustration:

Functional group Functional group identification
ol Alcohol
al Aldehyde
one Ketone

Finally the structure can be drawn based on these identifications.

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Answer 4

Question

Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 19.2, Problem 4ATS

(a)

Interpretation Introduction

Interpretation: The structure for the given IUPAC name has to be identified.

Concept Introduction:

Guidelines in drawing the structure from the given IUPAC name:

The parent chain has to be identified by the root word.

Illustration:

Root word Parent chain identification
ane Alkane
ene Alkene
yne Alkyne

The substituents on the parent chain have to be identified by the primary suffix name. The substituent name always follows with a number which indicates at which carbon atom the substituent is attached on the parent chain.

Illustration:

Primary suffix Substituent identification
methyl CH3
ethyl CH3CH2
isopropyl CH3CH2CH3

The functional groups have to be identified by the secondary suffix name. The functional group name always follows with a number which indicates at which carbon atom the functional group is attached on the parent chain.

Illustration:

Functional group Functional group identification
ol Alcohol
al Aldehyde
one Ketone

Finally the structure can be drawn based on these identifications.

(b)

Interpretation Introduction

Interpretation: The structure for the given IUPAC name has to be identified.

Concept Introduction:

Guidelines in drawing the structure from the given IUPAC name:

The parent chain has to be identified by the root word.

Illustration:

Root word Parent chain identification
ane Alkane
ene Alkene
yne Alkyne

The substituents on the parent chain have to be identified by the primary suffix name. The substituent name always follows with a number which indicates at which carbon atom the substituent is attached on the parent chain.

Illustration:

Primary suffix Substituent identification
methyl CH3
ethyl CH3CH2
isopropyl CH3CH2CH3

The functional groups have to be identified by the secondary suffix name. The functional group name always follows with a number which indicates at which carbon atom the functional group is attached on the parent chain.

Illustration:

Functional group Functional group identification
ol Alcohol
al Aldehyde
one Ketone

Finally the structure can be drawn based on these identifications.

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Answer 5

Chapter 19.2, Problem 4ATS

(a)

Interpretation Introduction

Interpretation: The structure for the given IUPAC name has to be identified.

Concept Introduction:

Guidelines in drawing the structure from the given IUPAC name:

The parent chain has to be identified by the root word.

Illustration:

Root word Parent chain identification
ane Alkane
ene Alkene
yne Alkyne

The substituents on the parent chain have to be identified by the primary suffix name. The substituent name always follows with a number which indicates at which carbon atom the substituent is attached on the parent chain.

Illustration:

Primary suffix Substituent identification
methyl CH3
ethyl CH3CH2
isopropyl CH3CH2CH3

The functional groups have to be identified by the secondary suffix name. The functional group name always follows with a number which indicates at which carbon atom the functional group is attached on the parent chain.

Illustration:

Functional group Functional group identification
ol Alcohol
al Aldehyde
one Ketone

Finally the structure can be drawn based on these identifications.

(b)

Interpretation Introduction

Interpretation: The structure for the given IUPAC name has to be identified.

Concept Introduction:

Guidelines in drawing the structure from the given IUPAC name:

The parent chain has to be identified by the root word.

Illustration:

Root word Parent chain identification
ane Alkane
ene Alkene
yne Alkyne

The substituents on the parent chain have to be identified by the primary suffix name. The substituent name always follows with a number which indicates at which carbon atom the substituent is attached on the parent chain.

Illustration:

Primary suffix Substituent identification
methyl CH3
ethyl CH3CH2
isopropyl CH3CH2CH3

The functional groups have to be identified by the secondary suffix name. The functional group name always follows with a number which indicates at which carbon atom the functional group is attached on the parent chain.

Illustration:

Functional group Functional group identification
ol Alcohol
al Aldehyde
one Ketone

Finally the structure can be drawn based on these identifications.

Answer 6

Chapter 19.2, Problem 4ATS

(a)

Interpretation Introduction

Interpretation: The structure for the given IUPAC name has to be identified.

Concept Introduction:

Guidelines in drawing the structure from the given IUPAC name:

The parent chain has to be identified by the root word.

Illustration:

Root word Parent chain identification
ane Alkane
ene Alkene
yne Alkyne

The substituents on the parent chain have to be identified by the primary suffix name. The substituent name always follows with a number which indicates at which carbon atom the substituent is attached on the parent chain.

Illustration:

Primary suffix Substituent identification
methyl CH3
ethyl CH3CH2
isopropyl CH3CH2CH3

The functional groups have to be identified by the secondary suffix name. The functional group name always follows with a number which indicates at which carbon atom the functional group is attached on the parent chain.

Illustration:

Functional group Functional group identification
ol Alcohol
al Aldehyde
one Ketone

Finally the structure can be drawn based on these identifications.

Answer 7

Chapter 19.2, Problem 4ATS

(a)

Interpretation Introduction

Interpretation: The structure for the given IUPAC name has to be identified.

Concept Introduction:

Guidelines in drawing the structure from the given IUPAC name:

The parent chain has to be identified by the root word.

Illustration:

Root word Parent chain identification
ane Alkane
ene Alkene
yne Alkyne

The substituents on the parent chain have to be identified by the primary suffix name. The substituent name always follows with a number which indicates at which carbon atom the substituent is attached on the parent chain.

Illustration:

Primary suffix Substituent identification
methyl CH3
ethyl CH3CH2
isopropyl CH3CH2CH3

The functional groups have to be identified by the secondary suffix name. The functional group name always follows with a number which indicates at which carbon atom the functional group is attached on the parent chain.

Illustration:

Functional group Functional group identification
ol Alcohol
al Aldehyde
one Ketone

Finally the structure can be drawn based on these identifications.

Answer 8

(b)

Interpretation Introduction

Interpretation: The structure for the given IUPAC name has to be identified.

Concept Introduction:

Guidelines in drawing the structure from the given IUPAC name:

The parent chain has to be identified by the root word.

Illustration:

Root word Parent chain identification
ane Alkane
ene Alkene
yne Alkyne

The substituents on the parent chain have to be identified by the primary suffix name. The substituent name always follows with a number which indicates at which carbon atom the substituent is attached on the parent chain.

Illustration:

Primary suffix Substituent identification
methyl CH3
ethyl CH3CH2
isopropyl CH3CH2CH3

The functional groups have to be identified by the secondary suffix name. The functional group name always follows with a number which indicates at which carbon atom the functional group is attached on the parent chain.

Illustration:

Functional group Functional group identification
ol Alcohol
al Aldehyde
one Ketone

Finally the structure can be drawn based on these identifications.

Answer 9

(b)

Interpretation Introduction

Interpretation: The structure for the given IUPAC name has to be identified.

Concept Introduction:

Guidelines in drawing the structure from the given IUPAC name:

The parent chain has to be identified by the root word.

Illustration:

Root word Parent chain identification
ane Alkane
ene Alkene
yne Alkyne

The substituents on the parent chain have to be identified by the primary suffix name. The substituent name always follows with a number which indicates at which carbon atom the substituent is attached on the parent chain.

Illustration:

Primary suffix Substituent identification
methyl CH3
ethyl CH3CH2
isopropyl CH3CH2CH3

The functional groups have to be identified by the secondary suffix name. The functional group name always follows with a number which indicates at which carbon atom the functional group is attached on the parent chain.

Illustration:

Functional group Functional group identification
ol Alcohol
al Aldehyde
one Ketone

Finally the structure can be drawn based on these identifications.

Answer 10

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Answer 11

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Answer 12

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Answer 13

Ch. 19.2 - Prob. 1LTS Ch. 19.2 - Prob. 1PTS Ch. 19.2 - Prob. 2PTS Ch. 19.2 - APPLY the skill Compounds with two ketone groups...Ch. 19.2 - Prob. 4ATS Ch. 19.3 - Prob. 5CC Ch. 19.4 - Prob. 6CC Ch. 19.5 - Prob. 7CC Ch. 19.5 - Prob. 2LTS Ch. 19.5 - Prob. 8PTS

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Chapter 19 Solutions

Root word	Parent chain identification
ane	Alkane
ene	Alkene
yne	Alkyne

Primary suffix	Substituent identification
methyl	CH3
ethyl	CH3CH2
isopropyl	CH3CH2CH3

Functional group	Functional group identification
ol	Alcohol
al	Aldehyde
one	Ketone