General Chemistry: Atoms First
2nd Edition
ISBN: 9780321809261
Author: John E. McMurry, Robert C. Fay
Publisher: Prentice Hall
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Textbook Question
Chapter 3, Problem 3.116CHP
Given the following information, construct a Born-Haber cycle to calculate the lattice energy of CrCl2I(s):
Net energy change for the formation of CrCl2I(s) = –420 kJ/mol
Bond dissociation energy for I2(g) = +151 kJ/mol
Heat of sublimation for I2(s) =+62 kJ/mol
Heat of sublimation for Cr(s) =+397 kJ/mol
Ei1 for Cr(g) = +652 kJ/mol
Ei2 for Cr(g) = +1588 kJ/mol
Ei3 for Cr(g) = +2882 kJ/mol
Eea for Cl(g) = –349 kJ/mol
Eea for I(g) = – 295 kJ/mol
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Using a Born-Haber cycle, calculate the enthalpy of formation of calcium fluoride, CaF2(s), given the following data:
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F(g) + e- → F-(g), -330 kJ/mol
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Calculate the change in energy for the following processes:
Na(g) + Cl(g) → Na^+1(g) + Cl^-1(g)
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Use the data provided below to calculate the lattice energy of RbCl. Is this value greater or less than thelattice energy of NaCl? Explain.Electron affinity of Cl = –349 kJ/mol1st ionization energy of Rb = 403 kJ/molBond energy of Cl2 = 242 kJ/molSublimation energy of Rb = 86.5 kJ/molΔHf [RbCl (s)] = –430.5 kJ/mol
Chapter 3 Solutions
General Chemistry: Atoms First
Ch. 3.1 - Prob. 3.1PCh. 3.1 - Which of the following drawings is most likely to...Ch. 3.2 - Give systematic names for the following compounds:...Ch. 3.2 - Write formulas for the following compounds: (a)...Ch. 3.2 - Prob. 3.5CPCh. 3.2 - Give systematic names for the following compounds:...Ch. 3.2 - Prob. 3.7PCh. 3.2 - Prob. 3.8CPCh. 3.3 - Predict the ground-state electron configuration...Ch. 3.3 - What doubly positive ion has the following...
Ch. 3.4 - Prob. 3.11PCh. 3.4 - which of the following spheres represents a K+...Ch. 3.5 - Using the periodic table as your guide, predict...Ch. 3.6 - (a) Which has the larger third ionization energy,...Ch. 3.6 - Three atoms have the following electron...Ch. 3.6 - Order the indicated three elements according to...Ch. 3.7 - Prob. 3.17PCh. 3.7 - Which of the indicated three elements has the...Ch. 3.8 - What noble-gas configurations are the following...Ch. 3.8 - Prob. 3.20PCh. 3.9 - Calculate the net energy change in kilojoules per...Ch. 3.10 - Which substance in each of the following pairs has...Ch. 3.10 - One of the following pictures represents NaCl and...Ch. 3.11 - Prob. 3.24PCh. 3.11 - Complete the following equations so that the same...Ch. 3.12 - Prob. 3.26PCh. 3.12 - Prob. 3.27PCh. 3.14 - Prob. 3.28PCh. 3 - In the following drawings, red spheres represent...Ch. 3 - Which of the following drawings is more likely to...Ch. 3 - Prob. 3.31CPCh. 3 - Prob. 3.32CPCh. 3 - Prob. 3.33CPCh. 3 - Prob. 3.34CPCh. 3 - Prob. 3.35CPCh. 3 - Prob. 3.36CPCh. 3 - Prob. 3.37CPCh. 3 - Prob. 3.38SPCh. 3 - Prob. 3.39SPCh. 3 - Prob. 3.40SPCh. 3 - Prob. 3.41SPCh. 3 - Prob. 3.42SPCh. 3 - Prob. 3.43SPCh. 3 - Prob. 3.44SPCh. 3 - Prob. 3.45SPCh. 3 - Prob. 3.46SPCh. 3 - Prob. 3.47SPCh. 3 - Prob. 3.48SPCh. 3 - Prob. 3.49SPCh. 3 - Prob. 3.50SPCh. 3 - Prob. 3.51SPCh. 3 - Prob. 3.52SPCh. 3 - What is the identity of the element X in the...Ch. 3 - Prob. 3.54SPCh. 3 - Prob. 3.55SPCh. 3 - Prob. 3.56SPCh. 3 - Prob. 3.57SPCh. 3 - Prob. 3.58SPCh. 3 - Prob. 3.59SPCh. 3 - Prob. 3.60SPCh. 3 - Prob. 3.61SPCh. 3 - Prob. 3.62SPCh. 3 - Prob. 3.63SPCh. 3 - Prob. 3.64SPCh. 3 - Prob. 3.65SPCh. 3 - Prob. 3.66SPCh. 3 - Prob. 3.67SPCh. 3 - Which element in each of the following sets has...Ch. 3 - Prob. 3.69SPCh. 3 - Prob. 3.70SPCh. 3 - Prob. 3.71SPCh. 3 - Prob. 3.72SPCh. 3 - Prob. 3.73SPCh. 3 - Prob. 3.74SPCh. 3 - Prob. 3.75SPCh. 3 - Prob. 3.76SPCh. 3 - Prob. 3.77SPCh. 3 - Prob. 3.78SPCh. 3 - Order the following compounds according to their...Ch. 3 - Calculate the energy change in kilojoules per mole...Ch. 3 - Prob. 3.81SPCh. 3 - Prob. 3.82SPCh. 3 - Prob. 3.83SPCh. 3 - Prob. 3.84SPCh. 3 - Prob. 3.85SPCh. 3 - Calculate the overall energy change in kilojoules...Ch. 3 - The estimated lattice energy for CsF2(s) is +2347...Ch. 3 - Prob. 3.88SPCh. 3 - Prob. 3.89SPCh. 3 - Prob. 3.90SPCh. 3 - Prob. 3.91SPCh. 3 - Prob. 3.92SPCh. 3 - Prob. 3.93SPCh. 3 - Prob. 3.94SPCh. 3 - Prob. 3.95SPCh. 3 - Prob. 3.96SPCh. 3 - Prob. 3.97SPCh. 3 - Prob. 3.98SPCh. 3 - Prob. 3.99SPCh. 3 - Prob. 3.100CHPCh. 3 - Prob. 3.101CHPCh. 3 - Prob. 3.102CHPCh. 3 - Prob. 3.103CHPCh. 3 - Prob. 3.104CHPCh. 3 - Prob. 3.105CHPCh. 3 - Prob. 3.106CHPCh. 3 - Prob. 3.107CHPCh. 3 - Prob. 3.108CHPCh. 3 - Prob. 3.109CHPCh. 3 - Prob. 3.110CHPCh. 3 - Prob. 3.111CHPCh. 3 - Prob. 3.112CHPCh. 3 - Prob. 3.113CHPCh. 3 - Prob. 3.114CHPCh. 3 - Given the following information, construct a...Ch. 3 - Given the following information, construct a...Ch. 3 - Consider the electronic structure of the element...Ch. 3 - Prob. 3.118MPCh. 3 - Prob. 3.119MP
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