Organic Chemistry (9th Edition)
9th Edition
ISBN: 9780321971371
Author: Leroy G. Wade, Jan W. Simek
Publisher: PEARSON
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Textbook Question
Chapter 3, Problem 3.44SP
Use a Newman projection about the indicated bond to draw the most stable conformer for each compound.
- a. 3-methylpentane about the C2—C3 bond
- b. 3,3-dimethylhexane about the C3—C4 bond
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1. Use a Newman projection about the indicated bond to draw the most stable conformer for each compound. (a) 3-methylpentane about the C2 ¬ C3 bond (b) 3,3-dimethylhexane about the C3 ¬ C4 bond2. refer to the questions below:
Use a Newman projection about the indicated bond to draw the most stable conformer for each compound. (a) 3-methylpentane about the C2¬C3 bond
Arrange the alkanes in each set in order of increasing boiling point.(a) 2-Methylbutane, 2,2-dimethylpropane, and pentane(b) 3,3-Dimethylheptane, 2,2,4-trimethylhexane, and nonane
Chapter 3 Solutions
Organic Chemistry (9th Edition)
Ch. 3.2 - Using the general molecular formula for alkanes:...Ch. 3.3B - Name the following alkanes and haloalkanes. When...Ch. 3.3B - Write structures for the following compounds. a....Ch. 3.3B - Provide IUPAC names for the following compounds....Ch. 3.3B - Prob. 3.5PCh. 3.3B - Prob. 3.6PCh. 3.3B - Prob. 3.7PCh. 3.3B - Draw the structures of the following compounds. a....Ch. 3.3B - Without looking at the structures, give molecular...Ch. 3.4C - Prob. 3.10P
Ch. 3.7B - Prob. 3.11PCh. 3.7C - Draw a graph similar to Figure 3-9, of the...Ch. 3.8B - Draw a graph similar to Figure 3-11, of the...Ch. 3.9 - Draw a perspective representation of the most...Ch. 3.10C - Give IUPAC names for the following compounds.Ch. 3.10C - Draw the structure and give the molecular formula...Ch. 3.11 - Which of the following cycloalkanes are capable of...Ch. 3.11 - Give IUPAC names for the following cycloalkanes.Ch. 3.12B - The heat of combustion of...Ch. 3.12C - Prob. 3.20PCh. 3.13B - The cyclohexane chair shown in Figure 3-22 has the...Ch. 3.13B - Draw 1,2,3,4,5,6-hexamethylcyclohexane with all...Ch. 3.14 - Prob. 3.23PCh. 3.14 - Prob. 3.24PCh. 3.14 - Draw the most stable conformation of a....Ch. 3.15 - Prob. 3.26PCh. 3.15 - a. Draw both chair conformations of cis-1...Ch. 3.15 - Prob. 3.28PCh. 3.15A - Draw the two chair conformations of each of the...Ch. 3.15B - Draw the most stable conformation of a....Ch. 3.16A - Name the following compounds.Ch. 3.16B - Prob. 3.32PCh. 3 - Prob. 3.33SPCh. 3 - Prob. 3.34SPCh. 3 - 3-35 a. Draw and name the five cycloalkane...Ch. 3 - Draw the structure that corresponds with each...Ch. 3 - Each of the following descriptions applies to more...Ch. 3 - Write structures for a homologous series of...Ch. 3 - Prob. 3.39SPCh. 3 - Construct a graph, similar to Figure 3-11, of the...Ch. 3 - The following names are all incorrect or...Ch. 3 - In each pair of compounds, which compound has the...Ch. 3 - There are eight different five-carbon alkyl...Ch. 3 - Use a Newman projection about the indicated bond...Ch. 3 - a. Draw the two chair conformations of...Ch. 3 - Draw the two chair conformations of each compound,...Ch. 3 - Using what you know about the conformational...Ch. 3 - Prob. 3.48SPCh. 3 - Draw Newman projections along the C3C4 bond to...Ch. 3 - Prob. 3.50SPCh. 3 - The most stable form of the common sugar glucose...Ch. 3 - This is a Newman projection of a substituted...
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- Four haloalkanes have approximate boiling points of 50°C, 70°C, 90°C and 102°C. Which compound in Figure 4 has an approximate boiling point of 90°C? * A B C Darrow_forwardConsider the tricyclic structure B. (a) Label each substituent on the rings as axial or equatorial. (b) Draw B using chair conformations for each six-membered ring. (c) Label the atoms on the ring fusions (the carbons that join each set of two rings together) as cis or trans to each other.arrow_forwardusing newman projections draw the least and most stable conformations with respect to the bond indicated 1-hexyne (C3 is front carbon and C4 is back carbon)arrow_forward
- 1,1-dimethylcyclopentane (draw condensed structural diagram)arrow_forwardBy adding tetraethyl lead to iso-octane: A. Exhaust smoke can be reduced B. Knocking can be completely suppressed C. Octane number above 100 can be obtained D. Specific fuel consumption can be reducedarrow_forwardMake a model of cyclohexane and draw its shape. Comment on its bond angles and how easily the model fitted together. Draw the boat and chair conformations of cyclohexane. Which arrangement do you think is the most stable?arrow_forward
- Draw stuctural formulas for two atoms butene that would be enantiomers. Butene is an alkene with a single double bond between 2 of its 4 carbon atoms and single bonds from its carbon atoms to 8 hydrogen atoms. Explain why your drawing shows them as enantiomers in 25 words or lessarrow_forwardDraw the structures based on iupac name digitally (use chem-space .com for easy drawing and screenshot) 1,1-Dibromo-4-isopropylcyclohexane 4-sec-Butyl-2-chlorononane 1.1-Dibromo-4-Pert-Butylcyclohexanearrow_forward1. Explain why 5,6-dichlorocyclohexene is an incorrect name for that compound. 2. Explain why 1,1-dimethylethene is an incorrect name for that compound.arrow_forward
- Alkenes are not soluble in water because they are a. polar b. hydrophilic c. hydrophobic d. less dense than waterarrow_forwardConsider the attached tricyclic structure B. (a) Label each substituent on the rings as axial or equatorial. (b) Draw B using chair conformations for each sixmembered ring. (c) Label the atoms on the ring fusions (the carbons that join each set of two rings together) as cis or trans to each other.arrow_forwardName each alkene and show the configuration about each double bond using the cis,trans systemarrow_forward
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