General, Organic, and Biological Chemistry - 4th edition
4th Edition
ISBN: 9781259883989
Author: by Janice Smith
Publisher: McGraw-Hill Education
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Chapter 4, Problem 52P
Considering each of the given ball-and stick models: [1] Does the dark red atom have one or more lone pairs of electrons on it? Explain your choice. [2] Give an example of a molecule that has the indicated geometry![Chapter 4, Problem 52P, Considering each of the given ball-and stick models: [1] Does the dark red atom have one or more](http://dev-ingestion-image-output.s3-website-us-east-1.amazonaws.com/9781259883989/Chapter-4/images/html_83989-4-52p_image001.jpg)
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Considering each of the given ball-and-stick models: [1] Does the dark red atom have one or more lone pairs of electrons on it? Explain your choice. [2] Give an example of a molecule that has the indicated geometry.
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Using the principles of VSEPR theory, you can predict the geometry around any atom in any molecule, no matter how complex. Enanthotoxin is a poisonous compound isolated from a common variety of hemlock grown in England. Predict the geometry around the highlighted atoms in enanthotoxin.
Chapter 4 Solutions
General, Organic, and Biological Chemistry - 4th edition
Ch. 4.1 - Use electron-dot symbols to show how a hydrogen...Ch. 4.1 - Use electron-dot symbols to show how two chlorine...Ch. 4.1 - How many covalent bonds are predicted for each...Ch. 4.1 - Fill in the lone pairs on each atom to give every...Ch. 4.1 - Prob. 4.4PCh. 4.2 - Draw a Lewis structure for each covalent molecule....Ch. 4.2 - Draw a Lewis structure for dimethyl ether (C2H6O)...Ch. 4.2 - Prob. 4.4PPCh. 4.2 - Prob. 4.5PCh. 4.2 - Prob. 4.6P
Ch. 4.3 - Prob. 4.7PCh. 4.3 - Prob. 4.8PCh. 4.4 - Prob. 4.5PPCh. 4.4 - Draw resonance structures for each polyatomic...Ch. 4.4 - Nitrous oxide, N2O, is a sweet-smelling gas...Ch. 4.5 - Name each compound: (a) CS2; (b) SO2; (c) PCl5;...Ch. 4.5 - Prob. 4.6PPCh. 4.6 - What is the shape around the indicated atom in...Ch. 4.6 - NaNH2, sodium amid, is a salt that contains a...Ch. 4.6 - Prob. 4.13PCh. 4.7 - Using the trends in the periodic table, rank the...Ch. 4.7 - Use electronegativity values to classify the...Ch. 4.8 - Label the polar bonds in each molecule, and then...Ch. 4.9 - Label the polar bonds in each molecule, and then...Ch. 4.9 - Use the ball-and-stick model of dihydrocapsaicin...Ch. 4 - For each pair of compounds, classify the bonding...Ch. 4 - For each pair of compounds, classify the bonding...Ch. 4 - Prob. 17PCh. 4 - How many bonds and lone pairs are typically...Ch. 4 - Prob. 19PCh. 4 - Fill in the lone pairs needed to give the main...Ch. 4 - Prob. 21PCh. 4 - Convert the 3-D model of the general anesthetic...Ch. 4 - Draw a valid Lewis structure for each molecule. Hl...Ch. 4 - Draw a valid Lewis structure for each molecule....Ch. 4 - Prob. 25PCh. 4 - Prob. 26PCh. 4 - Draw a valid Lewis structure for...Ch. 4 - Draw a valid Lewis structure for phosgene, CCl2O ,...Ch. 4 - Draw a valid Lewis structure for each ion: (a)...Ch. 4 - Draw a valid Lewis structure for each ion: (a)...Ch. 4 - Prob. 31PCh. 4 - Keeping in mind that some elements violate the...Ch. 4 - Prob. 33PCh. 4 - Prob. 34PCh. 4 - Prob. 35PCh. 4 - Prob. 36PCh. 4 - Prob. 37PCh. 4 - Label each pair of compounds are resonance...Ch. 4 - Prob. 39PCh. 4 - Draw three resonance structures for the nitrate...Ch. 4 - Name each covalent compound. PBr3 SO3 NCl3 P2S5Ch. 4 - Name each covalent compound. SF6 CBr4 N2O P4O10Ch. 4 - Prob. 43PCh. 4 - Prob. 44PCh. 4 - Add lone pairs where needed to give octets and...Ch. 4 - Add lone pairs where needed to give octets and...Ch. 4 - Prob. 47PCh. 4 - Match each compound with one of the molecular...Ch. 4 - Prob. 49PCh. 4 - Add lone pairs where needed to give octets and...Ch. 4 - Prob. 51PCh. 4 - Considering each of the given ball-and stick...Ch. 4 - Prob. 53PCh. 4 - Prob. 54PCh. 4 - Prob. 55PCh. 4 - Predict the bond angles around the indicated atoms...Ch. 4 - Prob. 57PCh. 4 - Prob. 58PCh. 4 - Rank the atoms in each group in order of...Ch. 4 - Prob. 60PCh. 4 - Prob. 61PCh. 4 - Identify elements D, E, and F and rank them in...Ch. 4 - Prob. 63PCh. 4 - Using electronegativity values, classify the bond...Ch. 4 - Label the bond formed between carbon and each of...Ch. 4 - Label the bond formed between fluroine and each of...Ch. 4 - Which bond in each pair is more polar-that is, has...Ch. 4 - Which bond in each pair is more polar-that is, has...Ch. 4 - Prob. 69PCh. 4 - Prob. 70PCh. 4 - Label the polar bonds and then decide if each...Ch. 4 - Label the polar bonds and then decide if each...Ch. 4 - Prob. 73PCh. 4 - Explain why H2O is a polar molecule but H2S is...Ch. 4 - Convert each ball-and-stick model to a Lewis...Ch. 4 - Convert each ball-and-stick model to a Lewis...Ch. 4 - Answer the following questions about the molecule...Ch. 4 - Answer the following question about the molecule...Ch. 4 - Prob. 79PCh. 4 - Lactic acid gives sour milk its distinctive taste....Ch. 4 - Use the ball-and-stick model of zingerone, a...Ch. 4 - Prob. 82PCh. 4 - Prob. 83PCh. 4 - Prob. 84PCh. 4 - Isobutyl cyanoacrylate is used in medical glues to...Ch. 4 - Prob. 86PCh. 4 - Cyclopropane is a stable compound that contains...Ch. 4 - Prob. 88CPCh. 4 - Prob. 89CPCh. 4 - Prob. 90CP
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- omplete the Lewis diagram before answering the following questions. How many sigma bonds are there in a molecule of allylcyanide? How many valence electrons are there in a molecule of allylcyanide? How many pi bonds are there in a molecule of allylcyanide?arrow_forwardUsing the principles of VSEPR theory, you can predict the geometry around any atom in any molecule, no matter how complex. Cicutoxin is a poisonous compound isolated from water hemlock, a highly toxic plant that grows in temperate regions in North America. Predict the geometry around the highlighted atoms in cicutoxin.arrow_forwardGive an example of a molecule containing both aσ- and a π-bond and indicate the two types ofbonds in your molecule.arrow_forward
- How are the bond angles around a central atom affected by lone pairs on the central atom and when there is a double bond involving the cental atom?arrow_forwardUsing the principles of VSEPR theory, you can predict the geometry around any atom in any molecule, no matter howcomplex. Enanthotoxin is a poisonous compound isolated from a common variety of hemlock grown in England. Predictthe geometry around the highlighted atoms in enanthotoxin.arrow_forwardWhat is the term when you can create more than one valid structure for a molecule, such as in SO3?arrow_forward
- Which of the following molecular formulas are correctly represented by line-bond structures that are consistent with valence rules?arrow_forwardYour assigneed ion is : AlCl4- please give a brief description that includes: (a) total valence electron count, (b) the Lewis structure, (c) the arrangement (or shape) of the electron grouping (includes lone pairs), (d) ideal bond angle, (e) actual molecular geometry (may be the same or different than answer (c), (f) actual bond angles (may use > or< symbols where appropriate). Please note that for an ion don't forget about charges.arrow_forwardUsing the principles of VSEPR theory, you can predict the geometry around any atom in any molecule, no matter how complex. Enanthotoxin is a poisonous compound isolated from a common variety of hemlock grown in England. Predict the geometry around the indicated atoms in enanthotoxin. a b c d e farrow_forward
- What effect does the presence of lone-pair electrons have on the bond angles in a molecule?arrow_forwardIn the actual structure of acetic acid, which bond angle isexpected to be the smallest?arrow_forwardWrite both electron-dot and line-bond structures for the following molecules, showing all nonbonded electrons:(a)CHCl3, chloroform (b)H2S, hydrogen sulfide (c)CH3NH2, methylaminearrow_forward
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