The reason as to why there is difference in the yields of 1 − chlorohexane and chlorocyclohexane . Interpretation: The reason as to why there is difference in the yields of 1 − chlorohexane and chlorocyclohexane is to be stated. Concept introduction: The chemical reaction which proceeds through the formation of radicals is known as chain reaction. It involves three steps, initiation, propagation and termination. The initiation step occurs in the presence of light. The quantum yield of chain reactions is very high.

Question

Want to see the full answer?

Answer 1

Question

Chapter 4.3C, Problem 4.4P

(a)

Interpretation Introduction

To determine: The reason as to why there is difference in the yields of 1−chlorohexane and chlorocyclohexane.

Interpretation: The reason as to why there is difference in the yields of 1−chlorohexane and chlorocyclohexane is to be stated.

Concept introduction: The chemical reaction which proceeds through the formation of radicals is known as chain reaction. It involves three steps, initiation, propagation and termination. The initiation step occurs in the presence of light. The quantum yield of chain reactions is very high.

(b)

Interpretation Introduction

To determine: The ratio of reactants (cyclohexane and chlorine) that would be used for the synthesis of chlorocyclohexane.

Interpretation: The ratio of reactants (Cyclohexane and chlorine) that would be used for the synthesis of chlorocyclohexane is to be predicted.

Concept introduction: The chemical reaction which proceeds through the formation of radicals is known as chain reaction. It involves three steps, initiation, propagation and termination. The initiation step occurs in the presence of light. The quantum yield of chain reactions is very high.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Students have asked these similar questions

Free-radical chlorination of hexane gives very poor yields of 1-chlorohexane, while cyclohexane can be converted to chlorocyclohexane in good yield. How do you account for this difference?

1)Chemistry students are taking an experimental course in organic chemistry at a public university. During an experiment involving conjugated dienes, some doubts arose when discussing the results obtained so far: (a) A student obtained two products from the reaction of 1,3-cyclohexadiene with Br2. His lab partner was surprised to get only one product from the reaction of 1,3 - cyclohexadiene with HBr. Explain these distinct results. (b) One student, seeing the discussion of colleagues, commented that she obtained two distinct products when reacting 1,3,5-hexatriene with HBr, with different yields just by changing the reaction temperature. Explain the results she obtained using reaction mechanism and based on kinetic and thermodynamic control involving conjugated dienes.

1. Using Br2 in C2H4Br2 will result in HBr and ______. a. C2H3Cl3 b. C2H4Cl3 c. C2H2Cl3 d. none of the above 2. How many halogenation are posible in propane? a. 3 b. 8 c. 6 d. 10 3.Sulfonation of pentane will result in ________ and water. a. C5H11SO3H b. C5H12SO3H c. C5H14SO3H d. none of the above 4.Nitration of hexane will result in ________ and water. a. C6H13SO3H b. C6H15NO2 c. C6H13NO2 d. C6H14NO2 5.How many moles of O2 in heating a C12H26 (dodecane) a. 27 b. 37 c. 24 d. none of the above

Answer 2

Question

Chapter 4.3C, Problem 4.4P

(a)

Interpretation Introduction

To determine: The reason as to why there is difference in the yields of 1−chlorohexane and chlorocyclohexane.

Interpretation: The reason as to why there is difference in the yields of 1−chlorohexane and chlorocyclohexane is to be stated.

Concept introduction: The chemical reaction which proceeds through the formation of radicals is known as chain reaction. It involves three steps, initiation, propagation and termination. The initiation step occurs in the presence of light. The quantum yield of chain reactions is very high.

(b)

Interpretation Introduction

To determine: The ratio of reactants (cyclohexane and chlorine) that would be used for the synthesis of chlorocyclohexane.

Interpretation: The ratio of reactants (Cyclohexane and chlorine) that would be used for the synthesis of chlorocyclohexane is to be predicted.

Concept introduction: The chemical reaction which proceeds through the formation of radicals is known as chain reaction. It involves three steps, initiation, propagation and termination. The initiation step occurs in the presence of light. The quantum yield of chain reactions is very high.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 3

Question

Chapter 4.3C, Problem 4.4P

(a)

Interpretation Introduction

To determine: The reason as to why there is difference in the yields of 1−chlorohexane and chlorocyclohexane.

Interpretation: The reason as to why there is difference in the yields of 1−chlorohexane and chlorocyclohexane is to be stated.

Concept introduction: The chemical reaction which proceeds through the formation of radicals is known as chain reaction. It involves three steps, initiation, propagation and termination. The initiation step occurs in the presence of light. The quantum yield of chain reactions is very high.

(b)

Interpretation Introduction

To determine: The ratio of reactants (cyclohexane and chlorine) that would be used for the synthesis of chlorocyclohexane.

Interpretation: The ratio of reactants (Cyclohexane and chlorine) that would be used for the synthesis of chlorocyclohexane is to be predicted.

Concept introduction: The chemical reaction which proceeds through the formation of radicals is known as chain reaction. It involves three steps, initiation, propagation and termination. The initiation step occurs in the presence of light. The quantum yield of chain reactions is very high.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 4

Question

Chapter 4.3C, Problem 4.4P

(a)

Interpretation Introduction

To determine: The reason as to why there is difference in the yields of 1−chlorohexane and chlorocyclohexane.

Interpretation: The reason as to why there is difference in the yields of 1−chlorohexane and chlorocyclohexane is to be stated.

Concept introduction: The chemical reaction which proceeds through the formation of radicals is known as chain reaction. It involves three steps, initiation, propagation and termination. The initiation step occurs in the presence of light. The quantum yield of chain reactions is very high.

(b)

Interpretation Introduction

To determine: The ratio of reactants (cyclohexane and chlorine) that would be used for the synthesis of chlorocyclohexane.

Interpretation: The ratio of reactants (Cyclohexane and chlorine) that would be used for the synthesis of chlorocyclohexane is to be predicted.

Concept introduction: The chemical reaction which proceeds through the formation of radicals is known as chain reaction. It involves three steps, initiation, propagation and termination. The initiation step occurs in the presence of light. The quantum yield of chain reactions is very high.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 5

Chapter 4.3C, Problem 4.4P

(a)

Interpretation Introduction

To determine: The reason as to why there is difference in the yields of 1−chlorohexane and chlorocyclohexane.

Interpretation: The reason as to why there is difference in the yields of 1−chlorohexane and chlorocyclohexane is to be stated.

Concept introduction: The chemical reaction which proceeds through the formation of radicals is known as chain reaction. It involves three steps, initiation, propagation and termination. The initiation step occurs in the presence of light. The quantum yield of chain reactions is very high.

(b)

Interpretation Introduction

To determine: The ratio of reactants (cyclohexane and chlorine) that would be used for the synthesis of chlorocyclohexane.

Interpretation: The ratio of reactants (Cyclohexane and chlorine) that would be used for the synthesis of chlorocyclohexane is to be predicted.

Concept introduction: The chemical reaction which proceeds through the formation of radicals is known as chain reaction. It involves three steps, initiation, propagation and termination. The initiation step occurs in the presence of light. The quantum yield of chain reactions is very high.

Answer 6

Chapter 4.3C, Problem 4.4P

(a)

Interpretation Introduction

To determine: The reason as to why there is difference in the yields of 1−chlorohexane and chlorocyclohexane.

Interpretation: The reason as to why there is difference in the yields of 1−chlorohexane and chlorocyclohexane is to be stated.

Concept introduction: The chemical reaction which proceeds through the formation of radicals is known as chain reaction. It involves three steps, initiation, propagation and termination. The initiation step occurs in the presence of light. The quantum yield of chain reactions is very high.

Answer 7

Chapter 4.3C, Problem 4.4P

(a)

Interpretation Introduction

To determine: The reason as to why there is difference in the yields of 1−chlorohexane and chlorocyclohexane.

Interpretation: The reason as to why there is difference in the yields of 1−chlorohexane and chlorocyclohexane is to be stated.

Concept introduction: The chemical reaction which proceeds through the formation of radicals is known as chain reaction. It involves three steps, initiation, propagation and termination. The initiation step occurs in the presence of light. The quantum yield of chain reactions is very high.

Answer 8

(b)

Interpretation Introduction

To determine: The ratio of reactants (cyclohexane and chlorine) that would be used for the synthesis of chlorocyclohexane.

Interpretation: The ratio of reactants (Cyclohexane and chlorine) that would be used for the synthesis of chlorocyclohexane is to be predicted.

Concept introduction: The chemical reaction which proceeds through the formation of radicals is known as chain reaction. It involves three steps, initiation, propagation and termination. The initiation step occurs in the presence of light. The quantum yield of chain reactions is very high.

Answer 9

(b)

Interpretation Introduction

To determine: The ratio of reactants (cyclohexane and chlorine) that would be used for the synthesis of chlorocyclohexane.

Interpretation: The ratio of reactants (Cyclohexane and chlorine) that would be used for the synthesis of chlorocyclohexane is to be predicted.

Concept introduction: The chemical reaction which proceeds through the formation of radicals is known as chain reaction. It involves three steps, initiation, propagation and termination. The initiation step occurs in the presence of light. The quantum yield of chain reactions is very high.

Answer 10

Expert Solution & Answer

Answer 11

Expert Solution & Answer

Answer 12

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 13

Ch. 4.3A - Draw Lewis structures for the following free...Ch. 4.3B - a. Write the propagation steps leading to the...Ch. 4.3C - Prob. 4.3P Ch. 4.3C - Prob. 4.4P Ch. 4.4 - The following reaction has a value of G =...Ch. 4.4 - Under base-catalyzed conditions two molecules of...Ch. 4.5B - When ethene is mixed with hydrogen in the presence...Ch. 4.5B - For each reaction, estimate whether S for the...Ch. 4.7 - a. Propose a mechanism for the free radical...Ch. 4.7 - a. Using bond-dissociation enthalpies from...

Solution Summary: The author explains the reason for the difference in the yields of 1-chlorohexane and ''

Concept explainers

Want to see the full answer?

Chapter 4 Solutions