Concept explainers
Interpretation: The important resonances of molecules mentioned below should be drawn.
Concept introduction:When one single structure is unable to describe all the properties of single molecule, a phenomenon called resonance comes into play. This arises when two or more than two Lewis structures are possible for one molecule. All such structures are called resonating structures and have same placement of atoms in them but these have different locations of bond pairs and lone pairs. The resonating structures are inter-convertible with each other. The resultant of all the resonating or contributing structures is called the resonance hybrid.
Rules to form resonance structure are as follows:
1. Use arrow types 1 and 2 for resonance structure of anions in movement of negative charge.Arrow type 1 shows the movement of lone pair toward adjacent atom and then converted into
2. Use only arrow type 3 to move a positive charge for resonance structure of cations.Arrow type 3 is used to move
3. The sigma bond should not be broken. Any atom must not move from its place and total number of electrons must be same in all resonance structures.
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Check out a sample textbook solutionChapter 5 Solutions
Organic Chemistry: A Guided Inquiry
- For each proposed set of resonance structures: a. (E) Add curved arrows (starting from left) to show how each successive r.s. was generated. b. Cross out any resonance structures that are NOT important, and explain your reasoning.arrow_forwardDraws resonance structures for each substancearrow_forwarddraw all the significant resonance structures of this moleculearrow_forward
- Chemistry: Matter and ChangeChemistryISBN:9780078746376Author:Dinah Zike, Laurel Dingrando, Nicholas Hainen, Cheryl WistromPublisher:Glencoe/McGraw-Hill School Pub CoOrganic Chemistry: A Guided InquiryChemistryISBN:9780618974122Author:Andrei StraumanisPublisher:Cengage Learning