Solutions for General Chemistry - Standalone book (MindTap Course List)
Problem 13.2QP:
Define the rate of reaction of HBr in the following reaction. How is this related to the rate of...Problem 13.3QP:
Give at least two physical properties that might be used to determine the rate of a reaction.Problem 13.4QP:
A rate of reaction depends on four variables (Question 13.1). Explain by means of an example how the...Problem 13.6QP:
The reaction 3I(aq)+H3AsO4(aq)+2H(aq)I3(aq)+H3AsO3(aq)+H2O(l) is found to be first order with...Problem 13.7QP:
The rate of a reaction is quadrupled when the concentration of one reactant is doubled. What is the...Problem 13.9QP:
The reaction A(g)B(g)+C(g) is known to be first order in A(g). It takes 28 s for the concentration...Problem 13.12QP:
Sketch a potential-energy diagram for the exothermic, elementary reaction A+BC+D and on it denote...Problem 13.13QP:
Draw a structural formula for the activated complex in the following reaction: NO2+NO3NO+NO2+O2...Problem 13.19QP:
The dissociation of N2O4 into NO2, N2O4(g)2NO2(g) is believed to occur in one step Obtain the...Problem 13.23QP:
You are running the reaction 2A+BC+3D. Your lab partner has conducted the first two experiments to...Problem 13.24QP:
At a constant temperature, which of the following would be expected to affect the rate of a given...Problem 13.25QP:
Consider the reaction E+FG+H, which has the following reaction coordinate diagram. E+FG+H Which one...Problem 13.26QP:
The hypothetical reaction A+B+CD+E has the rate law Rate = k[A]2[B]. Which of the following changes...Problem 13.27QP:
Kinetics I Consider the hypothetical reaction A(g) + 2B(g) h C(g). The four containers below...Problem 13.28QP:
Kinetics II You and a friend are working together in order to obtain as much kinetic information as...Problem 13.29QP:
Consider the reaction 3A2B+C. a One rate expression for the reaction is RateofformationofC=+[C]t...Problem 13.30QP:
Given the reaction 2A+BC+3D, can you write the rate law for this reaction? If so, write the rate...Problem 13.31QP:
The reaction 2A(g)A2(g) is being run in each of the following containers. The reaction is found to...Problem 13.33QP:
You perform some experiments for the reaction AB+C and determine the rate law has the form...Problem 13.34QP:
A friend of yours runs a reaction and generates the following plot. She explains that in following...Problem 13.36QP:
You carry out the following reaction by introducing N2O4 into an evacuated flask and observing the...Problem 13.38QP:
The chemical reaction AB+C has a rate constant that obeys the Arrhenius equation. Predict what...Problem 13.39QP:
Relate the rate of decomposition of NH4NO2 to the rate of formation of N2 for the following...Problem 13.40QP:
For the reaction of hydrogen with iodine H2(g)+I2(g)2HI(g) relate the rate of disappearance of...Problem 13.41QP:
To obtain the rate of the reaction 5Br(aq)+BrO3(aq)+6H(aq)3Br2(aq)+3H2O(l) you might follow the Br...Problem 13.42QP:
To obtain the rate of the reaction 3I(aq)+H3AsO4(aq)+2H(aq)I3(aq)+H3AsO3(aq)+H2O(l) you might follow...Problem 13.43QP:
Ammonium nitrite, NH4NO2, decomposes in solution, as shown here. NH4NO2(aq)N2(g)+2H2O(l) The...Problem 13.44QP:
Iron(III) chloride is reduced by tin(II) chloride. 2FeCl3(aq)+SnCl2(aq)2FeCl2(aq)+SnCl4(aq) The...Problem 13.45QP:
Azomethane, CH3NNCH3, decomposes according to the following equation: CH3NNCH3(g)C2H6(g)+N2(g) The...Problem 13.46QP:
Nitrogen dioxide, NO2, decomposes upon heating to form nitric oxide and oxygen according to the...Problem 13.47QP:
Hydrogen sulfide is oxidized by chlorine in aqueous solution. H2S(aq)+Cl2(aq)S(s)+2HCl(aq) The...Problem 13.48QP:
For the reaction of nitrogen monoxide, NO, with chlorine, Cl2, 2NO(g)+Cl2(g)2NOCl(g) the observed...Problem 13.51QP:
In experiments on the decomposition of azomethane. CH3NHCH3(g)C2H6(g)+N2(g) the following data were...Problem 13.52QP:
Ethylene oxide. C2H4O, decomposes when heated to give methane and carbon monoxide....Problem 13.53QP:
Nitrogen monoxide NO, reacts with hydrogen to give nitrous oxide, N2O, and water....Problem 13.54QP:
In a kinetic study of the reaction 2NO(g)+O2(g)2NO2(g) the following data were obtained for the...Problem 13.55QP:
Chlorine dioxide, ClO2, is a reddish-yellow gas that is soluble in water. In basic solution it gives...Problem 13.56QP:
Iodide ion is oxidized to hypoiodite ion, IO, by hypochlorite ion, ClO, in basic solution. The...Problem 13.57QP:
Sulfuryl chloride, SO2Cl2, decomposes when heated. SO2Cl2(g)SO2(g)+Cl2(g) In an experiment, the...Problem 13.58QP:
Cyclopropane, C3H6, is converted to its isomer propylene, CH2CHCH3, when heated. The rate law is...Problem 13.59QP:
A reaction of the form aA Products is second-order with a rate constant of 0.725 L/(mol s). If the...Problem 13.60QP:
A reaction of the form aA Products is second order with a rate constant of 0.169 L/(mol s). If the...Problem 13.61QP:
Ethyl chloride, CH3CH2Cl, used to produce tetraethyllead gasoline additive, decomposes, when heated,...Problem 13.62QP:
Cyclobutane, C4H8, consisting of molecules in which four carbon atoms form a ring, decomposes, when...Problem 13.63QP:
Methyl isocyanide, CH3NC, isomerizes, when heated, to give acetonitrile (methyl cyanide), CH3CN....Problem 13.64QP:
Dinitrogen pentoxide, N2O5, decomposes when heated in carbon tetrachloride solvent. N2O52NO+12O2(g)...Problem 13.65QP:
In the presence of excess thiocyanate ion, SCN, the following reaction is first order in...Problem 13.66QP:
In the presence of excess thiocyanate ion, SCN, the following reaction is first order in iron(III)...Problem 13.67QP:
A reaction of the form aA Products is second order with a rate constant of 0.164 L/(mol s). What is...Problem 13.68QP:
A reaction of the form aA Products is second order with a half-life of 485 s. What is the rate...Problem 13.69QP:
In the presence of excess thiocyanate ion, SCN, the following reaction is first order in...Problem 13.70QP:
In the presence of excess thiocyanate ion, SCN, the following reaction is first order in iron(III)...Problem 13.71QP:
It is found that a gas undergoes a zero-order decomposition reaction in the presence of a nickel...Problem 13.72QP:
The reaction AB+C is found to be zero order. If it takes 5.2 102 seconds for an initial...Problem 13.73QP:
Chlorine dioxide oxidizes iodide ion in aqueous solution to iodine; chlorine dioxide is reduced to...Problem 13.74QP:
Methyl acetate, CH3COOCH3, reacts in basic solution to give acetate ion, CH3COO, and methanol,...Problem 13.76QP:
Sketch a potential-energy diagram for the decomposition of nitrous oxide. N2O(g)N2(g)+O(g) The...Problem 13.77QP:
In a series of experiments on the decomposition of dinitrogen pentoxide, N2O5, rate constants were...Problem 13.78QP:
The reaction 2NOCl(g)2NO(g)+Cl2(g) has rate-constant values for the reaction of NOCl of 9.3 106/s...Problem 13.79QP:
The rate of a particular reaction increases by a factor of 6 when the temperature is increased from...Problem 13.80QP:
The rate of a particular reaction quadruples when the temperature is increased from 25 to 42C....Problem 13.81QP:
The following values of the rate constant were obtained for the decomposition of nitrogen dioxide at...Problem 13.82QP:
The following values of the rate constant were obtained for the decomposition of hydrogen iodide at...Problem 13.83QP:
Nitrogen monoxide, NO, is believed to react with chlorine according to the following mechanism:...Problem 13.84QP:
The decomposition of ozone is believed to occur in two steps:...Problem 13.85QP:
Identify the molecularity of each of the following elementary reactions. a NO+O3NO2+O2 b...Problem 13.87QP:
Write a rate equation, showing the dependence of rate on reactant concentrations, for each of the...Problem 13.89QP:
The isomerization of cyclopropane, C3H6, is believed to occur by the mechanism shown in the...Problem 13.90QP:
The thermal decomposition of nitryl chloride, NO2Cl, 2NO2Cl(g)2NO2(g)+Cl2(g) is thought to occur by...Problem 13.92QP:
Ozone decomposes to oxygen gas. 2O3(g)3O2(g) A proposed mechanism for this decomposition is...Problem 13.93QP:
The following is a possible mechanism for a reaction involving hydrogen peroxide in aqueous...Problem 13.94QP:
Consider the following mechanism for a reaction in aqueous solution and indicate the species acting...Problem 13.95QP:
A study of the decomposition of azomethane, CH3NNCH3(g)C2H6(g)+N2(g) gave the following...Problem 13.96QP:
Nitrogen dioxide decomposes when heated. 2NO2(g)2NO(g)+O2(g) During an experiment, the concentration...Problem 13.99QP:
Methyl acetate reacts in acidic solution....Problem 13.100QP:
Benzene diazonium chloride, C6H5NNCl, decomposes by a first-order rate law. C6H5NNClC6H5Cl+N2(g) If...Problem 13.101QP:
What is the half-life of methyl acetate hydrolysis at 25C in the acidic solution described in...Problem 13.102QP:
What is the half-life of benzene diazonium chloride decomposition at 20C? See Problem 13.100 for...Problem 13.103QP:
A compound decomposes by a first-order reaction. If the concentration of the compound is 0.0569 M...Problem 13.104QP:
A compound decomposes by a first-order reaction. The concentration of compound decreases from 0.1180...Problem 13.105QP:
Butadiene can undergo the following reaction to form a dimer (two butadiene molecules hooked...Problem 13.108QP:
A second-order decomposition reaction run at 550oC has a rate constant of 3.1 102 L/(mols). If the...Problem 13.113QP:
The decomposition of nitrogen dioxide, 2NO2(g)2NO(g)+O2(g) has a rate constant of 0.498 M/s at 319oC...Problem 13.117QP:
Nitryl bromide, NO2Br, decomposes into nitrogen dioxide and bromine. 2NO2Br(g)2NO2(g)+Br2(g) A...Problem 13.118QP:
Tertiary butyl chloride reacts in basic solution according to the equation (CH3)3CCl+OH(CH3)3COH+Cl...Problem 13.119QP:
Urea, (NH2)2CO, can be prepared by heating ammonium cyanate, NH4OCN. NH4OCN(NH2)2CO This reaction...Problem 13.121QP:
A study of the gas-phase oxidation of nitrogen monoxide at 25C and 1.00 atm pressure gave the...Problem 13.122QP:
The reaction of water with CH3Cl in acetone as a solvent is represented by the equation...Problem 13.131QP:
The rate constant for a certain reaction is 1.4 105 M1 min1 at 483 K. The activation energy for the...Problem 13.132QP:
The decomposition of hydrogen peroxide is a first order reaction: H2O2(aq)H2O(l)+12O2(g) The...Problem 13.135QP:
A possible mechanism for a gas-phase reaction is given below. What is the rate law predicted by this...Problem 13.136QP:
Say you run the following elementary, termolecular reaction: 2A+BD Using the starting concentrations...Problem 13.138QP:
For the decomposition of one mole of nitrosyl chloride, H = 38 kJ. NOCl(g)NO(g)+12Cl2(g) The...Problem 13.139QP:
Given the following mechanism for a chemical reaction: H2O2+IH2O+IOH2O2+IOH2O+O2+I a Write the...Problem 13.140QP:
The following data were collected for the reaction A(g)+B(g) Products. a Determine the rate law for...Problem 13.141QP:
A hypothetical reaction has the two-step mechanism AB+CABCABC+CAC+BC The potential-energy curve for...Problem 13.145QP:
Dinitrogen pentoxide decomposes according to the reaction 2N2O3(g)4NO2(g)+O2(g) At 45C the rate...Problem 13.147QP:
Dinitrogen pentoxide, N2O5, undergoes first-order decomposition in chloroform solvent to yield NO2...Problem 13.149QP:
Hydrogen peroxide in aqueous solution decomposes by a first-order reaction to water and oxygen. The...Problem 13.150QP:
Nitrogen dioxide reacts with carbon monoxide by the overall equation NO2(g)+CO(g)NO(g)+CO2(g) At a...Browse All Chapters of This Textbook
Chapter 1 - Chemistry And MeasurementChapter 1.3 - Law Of Conservation Of MassChapter 1.4 - Matter: Physical State And Chemical CompositionChapter 1.5 - Measurement And Significant FiguresChapter 1.6 - Si UnitsChapter 1.7 - Derived UnitsChapter 1.8 - Units And Dimensional Analysis (factor-label Method)Chapter 2 - Atoms, Molescules, And IonsChapter 2.1 - Atomic Theory Of MatterChapter 2.2 - The Structure Of The Atom
Chapter 2.3 - Nuclear Structure; IsotopesChapter 2.4 - Atomic WeightsChapter 2.5 - Periodic Table Of The ElementsChapter 2.6 - Chemical Formulas; Molecular And Ionic SubstancesChapter 2.8 - Naming Simple CompoundsChapter 2.10 - Balancing Chemical EquationsChapter 3 - Calculations With Chemical Formulas And EquaitonsChapter 3.1 - Molecular Weight And Formula WeightChapter 3.2 - The Mole ConceptChapter 3.3 - Mass Percentages From The FormulaChapter 3.4 - Elemental Analysis: Percentages Of Carbon, Hydrogen And OxygenChapter 3.5 - Determining FormulasChapter 3.6 - Molar Interpretation Of A Chemical EquationChapter 3.7 - Amounts Of Substances In A Chemical ReactionChapter 3.8 - Limiting Reactant; Theoretical And Percentage YieldsChapter 4 - Chemical ReactionsChapter 4.1 - Ionic Theory Of Solutions And Solubility RulesChapter 4.2 - Molecular And Ionic EquationsChapter 4.3 - Precipitation ReactionsChapter 4.4 - Acid-base ReactionsChapter 4.5 - Oxidation-reduction ReactionsChapter 4.6 - Balancing Simple Oxidation-reduction EquationsChapter 4.7 - Molar ConcentrationChapter 4.8 - Diluting SolutionsChapter 4.9 - Gravimetric AnalysisChapter 4.10 - Volumetric AnalysisChapter 5 - The Gaseous StateChapter 5.1 - Gas Pressure And Its MeasurementChapter 5.2 - Empirical Gas LawsChapter 5.3 - The Ideal Gas LawChapter 5.4 - Stoichiometry Problems Involving Gas VolumesChapter 5.5 - Gas Mixtures; Law Of Partial PressuresChapter 5.6 - Kinetic Theory Of An Ideal GasChapter 5.7 - Moleculat Speeds; Diffusion And EffusionChapter 5.8 - Real GasesChapter 6 - ThermochemistyChapter 6.1 - Energy And Its UnitsChapter 6.2 - First Law Of Thermodynamics; Work And HeatChapter 6.3 - Heat Of Reaction; Enthalpy Of ReactionChapter 6.4 - Thermochemical EquaitonsChapter 6.5 - Applying Stoichiometry To Heats Of ReactionChapter 6.6 - Measuring Heats Of ReactionChapter 6.7 - Hess's LawChapter 6.8 - Standard Enthalpies Of FormationChapter 7 - Quantum Theory Of The AtomChapter 7.1 - The Wave Nature Of LightChapter 7.2 - Quantum Effects And PhotonsChapter 7.3 - The Bohr Theory Of The Hydrogen AtomChapter 7.4 - Quantum MechanicsChapter 7.5 - Quantum Numbers And Atomic OrbitalsChapter 8 - Electron Configurations And PeriodicityChapter 8.1 - Electron Spin And The Pauli Exclusion PrincipleChapter 8.2 - Building-up Principle And The Periodic TableChapter 8.3 - Writing Electron Configurations Using The Periodic TableChapter 8.4 - Orbital Diagrams Of Atoms; Hund's RuleChapter 8.6 - Some Periodic PropertiesChapter 8.7 - Periodicity In The Main-group ElementsChapter 9 - Ionic And Covalent BondingChapter 9.1 - Describing Ionic BondsChapter 9.2 - Electron Configurations Of IonsChapter 9.3 - Ionic RadiiChapter 9.5 - Polar Covalent Bonds; ElectronegativityChapter 9.6 - Writing Lewis Electron-dot FormulasChapter 9.7 - Delocalized Bonding: ResonanceChapter 9.8 - Exceptions To The Octet RuleChapter 9.9 - Formal Charge And Lewis FormulasChapter 9.10 - Bond Length And Bond OrderChapter 9.11 - Bond EnthalpyChapter 10 - Molecular Geometry And Chemical Bonding TheoryChapter 10.1 - The Valence-shell Electron-pair Repulsion (vsepr) ModelChapter 10.2 - Dipole Moment And Molecular GeometryChapter 10.3 - Valence Bond TheoryChapter 10.4 - Description Of Multiple BondingChapter 10.6 - Electron Configurations Of Diatomic Moleucles Of The Second-period ElementsChapter 11 - States Of Matter; Liquids And SolidsChapter 11.2 - Phase TransitionsChapter 11.3 - Phase DiagramsChapter 11.5 - Intermolecular Forces; Explaining Liquid PropertiesChapter 11.6 - Classification Of Solids By Type Of Attraction Of UnitsChapter 11.7 - Crystalline Solids; Crystal Lattices And Unit CellsChapter 11.8 - Structures Of Some Crystalline SolidsChapter 11.9 - Calculations Involving Unit-cell DimensionsChapter 12 - SolutionsChapter 12.1 - Types Of SolutionsChapter 12.2 - Solubility And The Solution ProcessChapter 12.3 - Effects Of Temperature And Pressure On SolubilityChapter 12.4 - Ways Of Expressing ConcentrationChapter 12.5 - Vapor Pressure Of A SolutionChapter 12.6 - Boiling-point Elevation And Freezing-point DepressionChapter 12.7 - OsmosisChapter 12.8 - Colligative Properites Of Ionic SolutoinsChapter 12.9 - ColloidsChapter 13 - Rates Of ReactionChapter 13.1 - Definition Of Reaction RateChapter 13.3 - Dependence Of Rate On ConcentrationChapter 13.4 - Change Of Concentration With TimeChapter 13.5 - Temperature And Rate; Collision And Transisiton-state TheoriesChapter 13.6 - Arrhenius EquationChapter 13.7 - Elementary ReactionsChapter 13.8 - The Rate Law And The MechanismChapter 14 - Chemical EquilibirumChapter 14.1 - Chemical Equilbrium - A Dynamic EquilibriumChapter 14.2 - The Equilibrium ConstantChapter 14.3 - Heterogenous Equilibria; Solvents In Homogenous EquilibriaChapter 14.4 - Qualitativelys Interpreting The Equilibrium ConstantChapter 14.5 - Predicting The Direction Of ReactionChapter 14.6 - Calculating Equilibrium ConcentrationsChapter 14.7 - Removing Products Or Adding ReactantsChapter 14.8 - Changing The Pressure And TemperatureChapter 15 - Acids And BasesChapter 15.2 - Bronsted-lowry Concept Of Acids And BassesChapter 15.3 - Lewis Concept Of Acids And BasesChapter 15.4 - Relative Strengths Of Acids And BasesChapter 15.5 - Moleculat Structure And Acid StrengthChapter 15.7 - Solutions Of A Strong Acid Or BaseChapter 15.8 - The Ph Of A SolutionChapter 16 - Acid-base EquilibriaChapter 16.1 - Acid-ionization EquilibriaChapter 16.2 - Polyprotic AcidsChapter 16.3 - Base-ionization Of EquilibriaChapter 16.4 - Acid-base Properties Of Salt SolutionsChapter 16.5 - Common-ion EffectChapter 16.6 - BuffersChapter 16.7 - Acid-base Titration CurvesChapter 17 - Solubility And Complex-ion EquilibriaChapter 17.1 - The Solubility Product ConstantChapter 17.2 - Solubility And The Common-ion EffectChapter 17.3 - Precipitation CalculationsChapter 17.4 - Effect Of Ph On SolubilityChapter 17.5 - Complex-ion FormationChapter 17.6 - Complex Ions And SolubilityChapter 18 - Thermodynamics And EquilibriumChapter 18.2 - Entropy And The Second Law Of ThermodynamicsChapter 18.3 - Strandard Entropies And The Third Law Of ThermodynamicsChapter 18.4 - Free Energy And SpontaneityChapter 18.6 - Relating ?g° To The Equilibrium ConstantChapter 18.7 - Change Of Free Energy With TemperatureChapter 19 - ElectrochemistryChapter 19.1 - Balancing Oxidation-reduction Reactions In Acidic And Basic SolutionsChapter 19.2 - Construction Of Voltaic CellsChapter 19.3 - Notation For Voltaic CellsChapter 19.4 - Cell PotentialChapter 19.5 - Standard Cell Potentials And Standard Electrode PotentialsChapter 19.6 - Equilibrium Constants From Cell PotentialsChapter 19.7 - Dependence Of Cell Potential On ConcentrationChapter 19.8 - Some Commercial Voltaic CellsChapter 19.9 - Electrolysis Of Molten SaltsChapter 19.10 - Aquesous ElectrolysisChapter 19.11 - Stiochiometry Of ElectrolysisChapter 20 - Nuclear ChemistryChapter 20.1 - RadioactivityChapter 20.2 - Nuclear Bombardment ReactionsChapter 20.3 - Radations And Matter: Detection And Biological EffectsChapter 20.4 - Rate Of Radioactive DecayChapter 20.6 - Mass-energy CalculationsChapter 21 - Chemistry Of The Main-group ElementsChapter 21.9 - Group 5a: Nitrogen And The Phosphorus FamilyChapter 21.10 - Group 6a: Oxygen And The Sulfur FamilyChapter 22 - The Transition Elements And Coordination CompoundsChapter 22.3 - Formation And Structure Of ComplexesChapter 22.4 - Naming Coordination CompoundsChapter 22.5 - Structure And Isomerism In Coordination CompoundsChapter 22.7 - Crystal Field TheoryChapter 23 - Organic ChemistryChapter 23.2 - Alkanes And CycloalkanesChapter 23.3 - Alkenes And AlkynesChapter 23.5 - Naming HydrocarbonsChapter 23.6 - Organic Compounds Containing OxygenChapter 24 - Polymer Materials: Synthetic And BiologicalChapter 24.1 - Synthesis Of Organic PolymersChapter 24.3 - ProteinsChapter 24.4 - Nucleic AcidsChapter A.1 - Scientific (exponential) NotationChapter A.2 - LogarithmsChapter A.3 - Algebraic Operations And Graphing
Book Details
GENERAL CHEMISTRY is better than ever with this eleventh edition. It includes essential updates--such as modern artwork, higher integration with OWLv2, revised end-of-chapter questions, added Capstone Problems, narrative revisions, and more--to help you succeed in your chemistry course.
Sample Solutions for this Textbook
We offer sample solutions for General Chemistry - Standalone book (MindTap Course List) homework problems. See examples below:
Chapter 1, Problem 1.1QPChapter 1, Problem 1.57QPChapter 1, Problem 1.58QPChapter 1, Problem 1.65QPChapter 1, Problem 1.66QPChapter 1, Problem 1.67QPChapter 1, Problem 1.68QPChapter 1, Problem 1.69QPChapter 1, Problem 1.70QP
Chapter 1, Problem 1.109QPChapter 1, Problem 1.113QPChapter 1, Problem 1.114QPExplanation: Given mass in problem statement is 8.45 kg . Since, 1 kg = 103 g and 1 μg = 10-6 g , we...Explanation: Given distance in problem statement is 127 Å . Since, 1 Å = 10−10 m and 1 mg = 10-3 g ,...Chapter 1, Problem 1.135QPChapter 1, Problem 1.136QPChapter 1, Problem 1.169QPChapter 1, Problem 1.170QPChapter 2, Problem 2.1QPChapter 2, Problem 2.25QPChapter 2, Problem 2.26QPExplanation: The product in the given chemical equation is Lithium chloride. Hence, the starting...Chapter 2, Problem 2.97QPChapter 2, Problem 2.98QPExplanation: The given reaction in the problem statement is ammonium chloride and barium hydroxide...Explanation: The raw chemical equation given in the problem statement is, C2H6 + O2 → CO2 + H2O The...Chapter 2, Problem 2.126QPExplanation: Molecule is the term that is used for compounds which contain only covalent bonding...Chapter 3, Problem 3.1QPExplanation: To calculate the number of candy pieces in 0.2 kg of candy. Given, 1.0 kg of candy has...Chapter 3, Problem 3.18QPChapter 3, Problem 3.33QPChapter 3, Problem 3.37QPChapter 3, Problem 3.41QPChapter 3, Problem 3.42QPChapter 3, Problem 3.45QPChapter 3, Problem 3.46QPChapter 3, Problem 3.57QPChapter 3, Problem 3.58QPChapter 3, Problem 3.63QPExplanation: To calculate the masses of Carbon, Hydrogen and Oxygen. Molar mass of Carbon is 12.01 g...Explanation: To determine the produced mass of K2SO4 The given reaction is, 2 KOH+ H2SO4→K2SO4 +...Chapter 3, Problem 3.141QPChapter 4, Problem 4.1QPChapter 4, Problem 4.33QPChapter 4, Problem 4.34QPChapter 4, Problem 4.38QPChapter 4, Problem 4.39QPChapter 4, Problem 4.40QPChapter 4, Problem 4.43QPChapter 4, Problem 4.44QPChapter 4, Problem 4.45QPChapter 4, Problem 4.46QPExplanation: The complete molecular equation for the reaction between potassium hydroxide and...Chapter 4, Problem 4.48QPExplanation: The molecular equation for the reaction between HCN and lithium hydroxide is given...Chapter 4, Problem 4.100QPChapter 4, Problem 4.101QPChapter 4, Problem 4.103QPExplanation: Assume that both hydrogen atoms of H2SO4 ionize completely. H2SO4(aq) + Ba(OH)2(aq) →...Explanation: When an object having one kilogram of mass and it is placed in one square meter area...Explanation: Figure 1 According to kinetic theory of gases the molecules in a container are...Explanation: From Ideal gas equation, PV = nRT we can observe that pressure is directly proportional...Explanation: Figure 1 From Ideal gas law, PV = nRT Pressure and volume are inversely proportional to...Chapter 5, Problem 5.32QPExplanation: From the ideal gas equation and density formula, Both the density and pressure are...Explanation: To Calculate: The partial pressure of each of the gases from a certain volcano whose...Explanation: To Calculate: The rms speed (in m/s) of nitrogen (N2) molecules at 25∘C and at 125∘C...Chapter 5, Problem 5.136QPExplanation: Given data: A container is filled with 16.0 g of O2 and 14.0 g of N2 Moles of oxygen:...Chapter 5, Problem 5.147QPChapter 5, Problem 5.153QPExplanation: Given, A sample of Zinc with pressure 751 mmHg and temperature 170C . The level of...Chapter 5, Problem 5.158QPChapter 5, Problem 5.159QPExplanation: Given, An ideal gas with RMS of a gas is 5.00×102m/s and pressure of 2.5 atm and...Explanation: Given, Power plant driven by fossil fuel combustion generate substantial greenhouse...Chapter 6, Problem 6.1QPChapter 6, Problem 6.32QPChapter 6, Problem 6.36QPChapter 6, Problem 6.75QPChapter 6, Problem 6.76QPChapter 6, Problem 6.80QPChapter 6, Problem 6.81QPChapter 6, Problem 6.82QPChapter 6, Problem 6.115QPChapter 6, Problem 6.125QPExplanation: Given information, 2Al(s) + Fe2O3(s) → 2Fe(l) + Al2O3(s)ΔHf : 2 × 0 - 825.5 2 × 12.40...Explanation: Given information, 4KO2(s) + 2H2O(l) → 4KOH(s) + 3O2(g)ΔHof : 4 × - 284.5 2 × -285.8 4...Explanation: Given information, 2Na(s) + 2H2O(l) → 2Na+(aq) + 2OH-(aq) + H2(g)ΔHf : 0 2 × -285.8 2 ×...Explanation: Given information Total mass of hydrogen and oxygen gas is 2.500 g.Temperature is 25 oC...Chapter 6, Problem 6.151QPChapter 6, Problem 6.152QPExplanation: Figure 1 Calculate the HHV for propane by using the trend line equation, Molar mass for...Chapter 7, Problem 7.1QPChapter 7, Problem 7.23QPChapter 7, Problem 7.24QPChapter 7, Problem 7.67QPChapter 7, Problem 7.69QPChapter 7, Problem 7.70QPChapter 7, Problem 7.82QPChapter 7, Problem 7.83QPExplanation: To calculate: The wavelength of emitted light when an electron from hydrogen atom...Chapter 7, Problem 7.105QPChapter 7, Problem 7.106QPChapter 7, Problem 7.108QPChapter 7, Problem 7.112QPChapter 8, Problem 8.1QPExplanation: Bohr formula is ΔE=-RH[22∞2−2212]=-RH[-4]= 4 RH 4 × 2.179×10-18J1 He+ ion I.E= 4 ×...Chapter 9, Problem 9.1QPChapter 9, Problem 9.24QPChapter 9, Problem 9.71QPChapter 9, Problem 9.72QPChapter 9, Problem 9.75QPChapter 9, Problem 9.81QPChapter 9, Problem 9.118QPExplanation: The electronic configuration of Cl atom is Cl17:[Ne]3s2 3p5 But the Chlorine atom gain...Chapter 9, Problem 9.137QPChapter 9, Problem 9.138QPChapter 10, Problem 10.1QPChapter 10, Problem 10.37QPChapter 10, Problem 10.38QPChapter 11, Problem 11.1QPChapter 11, Problem 11.25QPChapter 11, Problem 11.28QPChapter 11, Problem 11.63QPChapter 11, Problem 11.74QPExplanation: Intermolecular force in each compound In a 1-Pentanol, the intermolecular forces are...Explanation: Intermolecular force in each compound CH3CHO is found to be polar molecule, therefore...Chapter 11, Problem 11.157QPExplanation: Gaseous solution is made of gases. One best example for gaseous solution is air – it is...Chapter 12, Problem 12.25QPChapter 12, Problem 12.26QPChapter 12, Problem 12.70QPExplanation: Assume that volume of solution is 1.000 L which is equivalent to 1.040 kg as density of...Explanation: Assume that volume of solution is 1.000 L which is equivalent to 1.127 kg as density of...Chapter 12, Problem 12.95QPChapter 12, Problem 12.96QPChapter 12, Problem 12.107QPChapter 12, Problem 12.108QPExplanation: Parts per million is expressed as, ppm = mass of solutemass of solution × 106 The term...Explanation: Determine the number of moles of each ion present in the solution. Totally five types...Explanation: Determine the number of moles of each ion present in the solution. Totally five types...Chapter 12, Problem 12.141QPChapter 12, Problem 12.142QPChapter 13, Problem 13.1QPChapter 13, Problem 13.27QPExplanation: The reaction follows first order with presence of half-life of ten seconds. There are...Chapter 13, Problem 13.65QPChapter 13, Problem 13.95QPChapter 13, Problem 13.96QPExplanation: Given, Time[CH3NNCH3]0.0min1.50×10-2 M 1.0min1.26×10-2 M2.0min1.10×10-2 M3.0...Explanation: Given, Time[NO2]0.0min0.1103 M 1.0min0.1076 M2.0min0.1050 M3.0 min0.1026 M Time Average...Chapter 13, Problem 13.105QPExplanation: To calculate the concentration of NO2 after 2.5×102 sec The integrated rate law for...Chapter 13, Problem 13.132QPChapter 13, Problem 13.140QPChapter 13, Problem 13.141QPChapter 13, Problem 13.145QPExplanation: The plot of 1[A] (vs) time gives a straight line and the reaction is said to be second...Chapter 13, Problem 13.150QPChapter 14, Problem 14.1QPChapter 14, Problem 14.45QPChapter 14, Problem 14.71QPChapter 14, Problem 14.72QPExplanation: Given, The equilibrium constant Kc =3.92 The initial amount of CO = 1.00 mol The...Explanation: Given, The equilibrium constant Kc =0.153 The initial amount of N2 = 1.00 mol The...Chapter 14, Problem 14.101QPChapter 14, Problem 14.103QPChapter 14, Problem 14.107QPChapter 14, Problem 14.108QPExplanation: Given, Volume of the flask =2.00 L Pressure = 1.00atm Partial pressure of N2=0.781 atm...Explanation: Given, The initial amount of I2 = 0.500 mol The initial amount of Br2 = 0.500 mol The...Chapter 14, Problem 14.137QPChapter 14, Problem 14.138QPChapter 15, Problem 15.1QPChapter 15, Problem 15.20QPChapter 15, Problem 15.35QPChapter 15, Problem 15.36QPChapter 15, Problem 15.53QPChapter 15, Problem 15.54QPChapter 15, Problem 15.85QPChapter 15, Problem 15.99QPChapter 15, Problem 15.100QPExplanation: Illustration of amphiprotic behavior of bicarbonate ion with water by writing...Chapter 15, Problem 15.102QPExplanation: The hydrated aluminum ion acts as Bronsted-Lowry acid and it can react with ammonia a...Chapter 15, Problem 15.119QPExplanation: The equilibrium of the given reaction can be represented as follows. Conc. (M) H3O+(aq)...Chapter 16, Problem 16.1QPChapter 16, Problem 16.21QPChapter 16, Problem 16.22QPChapter 16, Problem 16.47QPChapter 16, Problem 16.91QPChapter 16, Problem 16.92QPChapter 16, Problem 16.113QPChapter 16, Problem 16.114QPChapter 16, Problem 16.116QPChapter 16, Problem 16.119QPChapter 16, Problem 16.120QPChapter 16, Problem 16.129QPChapter 16, Problem 16.130QPChapter 16, Problem 16.135QPExplanation: To Calculate: The pH prior to the addition of any HCl Given data: A 0.150 M solution of...Chapter 16, Problem 16.157QPChapter 17, Problem 17.1QPChapter 17, Problem 17.31QPChapter 17, Problem 17.33QPChapter 17, Problem 17.34QPChapter 17, Problem 17.41QPChapter 17, Problem 17.42QPChapter 17, Problem 17.43QPChapter 17, Problem 17.67QPChapter 17, Problem 17.68QPChapter 17, Problem 17.91QPExplanation: To calculate: The molar solubility of AgI in 2.2 M NH3 . Given, The strength of NH3 is...Explanation: To calculate: The concentration of calcium ion, sodium ion, chloride ion and fluoride...Explanation: To calculate: The quantity of water and ammonia required to dissolve silver chloride....Chapter 17, Problem 17.128QPChapter 18, Problem 18.1QPExplanation: To give: The change in the water sample Given information, temperature of the water is...Explanation: To explain: The change in standard free energy for the given reaction Given reaction...Chapter 18, Problem 18.50QPExplanation: To calculate: the value of ΔHo Given reaction and information ΔHo (kJ)CO2(g) + 2H2(g) →...Chapter 18, Problem 18.88QPExplanation: To calculate: The value of ΔHo and ΔSo for the given reactions For the first reaction,...Chapter 18, Problem 18.92QPChapter 18, Problem 18.97QPChapter 18, Problem 18.98QPExplanation: To calculate: The value of ΔHof The value of standard enthalpy change of formation...Explanation: Given reaction and information 2NH3(g) → 3H2(g) + N2(g)ΔHfo: 2 × -45.90 0 0 kJ So: 2 ×...Explanation: Given reaction and information CO(g) + 3H2(g) → CH4(g) + H2O(g)ΔHfo: -110.5 0 -74.87...Chapter 19, Problem 19.1QPChapter 19, Problem 19.23QPChapter 19, Problem 19.32QPExplanation: To write the equations for two half-reactions, Oxidation half reaction: C2O42- →2CO2 +...Explanation: To write the equations for two half-reactions, Oxidation half reaction: Mn2+ →MnO4- +...Chapter 19, Problem 19.37QPChapter 19, Problem 19.38QPChapter 19, Problem 19.39QPExplanation: To write the equations for two half-reactions, Oxidation half reaction: 8H2S → S8 +...Chapter 19, Problem 19.41QPExplanation: To write the equations for two half-reactions, Oxidation half reaction: H2O2 →O2 + 2e-...Chapter 19, Problem 19.101QPExplanation: To write the equations for two half-reactions, Oxidation half reaction: S2-→ S8...Chapter 19, Problem 19.113QPExplanation: Given: Reduction of 2.0 mol Fe3+ to Fe2+ In above reduction 1 mole of electron is...Explanation: To calculate the cell potential (EMF) of given cell The standard reduction potentials...Explanation: Two types of nuclear reactions are, Radioactive decay Nuclear bombardment reactions...Explanation: Alpha emission ( α ): An unstable nucleus emits 24He nucleus or alpha particle....Explanation: Given nuclear reaction is, 4H11→H24e + 2e10 This reaction is found to be fusion...Explanation: To determine: Nuclear masses of each nucleus Nuclear mass of 12H = 2.01400 amu -...Explanation: To determine: Nuclear mass of 11H nucleus Nuclear mass of 12H = 2.01400 amu -...Explanation: Given: Mass of I-136 nuclei = 135.8401 amu Mass of Y-96 nuclei = 95.8629 amu Nuclear...Explanation: Given: Nuclear mass of 24He= 4.00260 amu-(2×0.000549amu)=4.001502amu Write the...Explanation: When Bromine-82 undergoes beta ( -10β ) decay it gives Krypton-82. This balanced...Explanation: When Tellurium-132 undergoes beta ( -10β ) decay it gives Xenon-132. This balanced...Given incomplete nuclear reaction is, 1431Si→ 1531P + ? This is written as, 1431Si→ 1531P + ZAX...Explanation: To calculate: Mass defect of Sodium Atomic mass of Na = 22.99 amu Mass of eleven...Explanation: Given Mass of electron = 0.000549 amu Temperature = 25°C 2p + 2n→ 24He Nuclear mass of...Explanation: Given Mass of electron = 0.000549 amu Temperature = 25°C 94239Pu→ 92235U + 24H...Explanation: Alloy is a mixture of one or more metals in a solid form. Examples for alloys are...Explanation: Halide ions and Halogens act as oxidizing and reducing agents. Reaction between halide...Explanation: To Write: The complete balanced equation for the given incomplete reaction. Potassium...Explanation: To Write: The complete balanced equation for the given incomplete reaction. Lithium...Explanation: To Write: The complete balanced equation for the given incomplete reaction. Barium...Explanation: Given Equation: KOH(aq) + MgCl2(aq)→ Complete Equation: A complete equation will have...Explanation: Given data: Lead(IV) oxide is prepared by oxidizing plumbite ion, Pb(OH)3- which exists...Explanation: Given Equation: Al2O3(s) + H2SO4(aq)→ Complete Equation: A complete equation will have...Explanation: Given Equation: Pb(NO3)2(aq) + Al(s)→ Complete Equation: A complete equation will have...Explanation: Given: The given molecule is ethylene and carbon is group 4A element. Carbon atom has 4...Explanation: Given data: The given cracking reaction is: CH4(g) →C(graphite) + 2H2(g) To Calculate:...Explanation: Given data: The given reaction involving synthesis of gas is: CO(g) + 2H2(g)→ CH3OH(g)...Explanation: Given Equation: CO2(g) + Ba(OH)2(aq)→ Complete Equation: A complete equation will have...Explanation: Given Equation: NaHCO3(aq) + HC2H3O2(aq)→ Complete Equation: A complete equation will...Explanation: Given data: Burning of lithium metal in oxygen. Chemical Equation: The chemical...Explanation: Given data: Burning of calcium metal in oxygen. Chemical Equation: The chemical...Explanation: Given data: Water vapor decomposes to atoms in gas phase. Hydrogen peroxide vapor...Explanation: To write: The complete and balanced equation for given combustion. P4(s) + 5O2(g) →...Explanation: To determine: The percentage of sodium acetate in a mixture of sodium acetate and...Explanation: To write: Chemical equation for given reaction Carbon burns in a air it gives Carbon...Explanation: To write: The reaction between copper and hydrochloric acid, iron and hydrochloric...Chapter 22, Problem 22.1QPExplanation: Atomic number of Vanadium is 23 and its electronic configuration is...Explanation: Atomic number of Zirconium is 40 and its electronic configuration is [Kr]4d25s2 . In...Explanation: In the complex ion [Pt(NH3)2]2+ the central metal ion Platinum is in +2 oxidation state...Explanation: In the complex ion [Pt(NH3)2(NO2)2]2+ the central metal ion Platinum is in +4 oxidation...Explanation: The reaction between Cu2+(aq) , NH3(aq) and [Cu(NH3)4]2+(aq) can be represented as,...Explanation: The reaction between Ag+(aq) , NH3(aq) and [Ag(NH3)2]+(aq) can be represented as,...Explanation: The complex ion [CoF6]3− has six fluoro ligands. Hence, the co-ordination number is six...Explanation: Oxidation state of Chromium in the complex [Cr(H2O)6]3+ , oxidation state of Cr =...Explanation: Oxidation state of Cobalt in the complex [Co(NH3)6]3+ , oxidation state of Co = charge...Chapter 23, Problem 23.1QPExplanation: By looking at the formula of the given compound we can identify that a carbonyl group...Explanation: For First structure: In the given ball-stick model, the black spheres are carbon atoms,...Chapter 23, Problem 23.24QPChapter 23, Problem 23.31QPExplanation: The given reaction in the problem statement is an combustion reaction and hence, the...Explanation: From the given name of the hydrocarbon, the parent carbon is identified as octane....Chapter 23, Problem 23.40QPExplanation: 2-methylpentane has the molecular formula of C6H14 . When this undergoes combustion...Explanation: Differentiation between condensation and addition polymer are as follows, Addition...
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