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Science
ChemistryOrganic And Biological Chemistry7th Edition

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Chapter 1, Problem 1.60EP
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Organic And Biological Chemistry

7th Edition
STOKER + 1 other
ISBN: 9781305081079

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Organic And Biological Chemistry

7th Edition
STOKER + 1 other
ISBN: 9781305081079
Textbook Problem

Indicate whether or not the two alkanes in each of the following pairs of alkanes are constitutional isomers.

a. Pentane and hexane

b. 2-Methylpentane and 3-methylpentane

c. Pentane and 2,2-dimethylpropane

d. 3,3-Dimethylpentane and 3,3-dimethylhexane

(a)

Interpretation Introduction

Interpretation:

Whether the given two alkanes are constitutional isomers or not has to be found.

Concept Introduction:

Organic compounds are represented shortly by the molecular formula and structural formula.  Each and every compound has its own molecular formula.  Compounds can have same molecular formula but not same structural formula.

Isomers are the compounds that have same molecular formula but different structural formula.  The main difference lies in the way the atoms are arranged in the structure.  Isomers have different chemical and physical properties even when they have same molecular formula.  This is known as Isomerism.

If there is difference only in the connectivity of the atoms in the molecule, then it is known as constitutional isomerism.  The isomers are known as constitutional isomers.  They will have same molecular formula and same functional group, but they differ in the connectivity between the atoms in the molecule.

Continuous-chain alkane is the one in which all the carbon atoms are bonded in a linear chain (non-branching chain).

Branched-chain alkane is an alkane which has atleast one branch in its structure that is attached to the continuous chain of carbon atoms.

Explanation

Pentane is a five carbon alkane while hexane is a six carbon alkane.  Pentane has molecular formula as C5H12.  The molecular formula for hexane is C

(b)

Interpretation Introduction

Interpretation:

Whether the given two alkanes are constitutional isomers or not has to be found.

Concept Introduction:

Organic compounds are represented shortly by the molecular formula and structural formula.  Each and every compound has its own molecular formula.  Compounds can have same molecular formula but not same structural formula.

Isomers are the compounds that have same molecular formula but different structural formula.  The main difference lies in the way the atoms are arranged in the structure.  Isomers have different chemical and physical properties even when they have same molecular formula.  This is known as Isomerism.

If there is difference only in the connectivity of the atoms in the molecule, then it is known as constitutional isomerism.  The isomers are known as constitutional isomers.  They will have same molecular formula and same functional group, but they differ in the connectivity between the atoms in the molecule.

Continuous-chain alkane is the one in which all the carbon atoms are bonded in a linear chain (non-branching chain).

Branched-chain alkane is an alkane which has atleast one branch in its structure that is attached to the continuous chain of carbon atoms.

(c)

Interpretation Introduction

Interpretation:

Whether the given two alkanes are constitutional isomers or not has to be found.

Concept Introduction:

Organic compounds are represented shortly by the molecular formula and structural formula.  Each and every compound has its own molecular formula.  Compounds can have same molecular formula but not same structural formula.

Isomers are the compounds that have same molecular formula but different structural formula.  The main difference lies in the way the atoms are arranged in the structure.  Isomers have different chemical and physical properties even when they have same molecular formula.  This is known as Isomerism.

If there is difference only in the connectivity of the atoms in the molecule, then it is known as constitutional isomerism.  The isomers are known as constitutional isomers.  They will have same molecular formula and same functional group, but they differ in the connectivity between the atoms in the molecule.

Continuous-chain alkane is the one in which all the carbon atoms are bonded in a linear chain (non-branching chain).

Branched-chain alkane is an alkane which has atleast one branch in its structure that is attached to the continuous chain of carbon atoms.

(d)

Interpretation Introduction

Interpretation:

Whether the given two alkanes are constitutional isomers or not has to be found.

Concept Introduction:

Organic compounds are represented shortly by the molecular formula and structural formula.  Each and every compound has its own molecular formula.  Compounds can have same molecular formula but not same structural formula.

Isomers are the compounds that have same molecular formula but different structural formula.  The main difference lies in the way the atoms are arranged in the structure.  Isomers have different chemical and physical properties even when they have same molecular formula.  This is known as Isomerism.

If there is difference only in the connectivity of the atoms in the molecule, then it is known as constitutional isomerism.  The isomers are known as constitutional isomers.  They will have same molecular formula and same functional group, but they differ in the connectivity between the atoms in the molecule.

Continuous-chain alkane is the one in which all the carbon atoms are bonded in a linear chain (non-branching chain).

Branched-chain alkane is an alkane which has atleast one branch in its structure that is attached to the continuous chain of carbon atoms.

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Sect-1.1 P-1QQSect-1.1 P-2QQSect-1.2 P-1QQSect-1.2 P-2QQSect-1.3 P-1QQSect-1.3 P-2QQSect-1.4 P-1QQSect-1.4 P-2QQSect-1.4 P-3QQSect-1.5 P-1QQ
Sect-1.5 P-2QQSect-1.5 P-3QQSect-1.6 P-1QQSect-1.6 P-2QQSect-1.6 P-3QQSect-1.6 P-4QQSect-1.7 P-1QQSect-1.7 P-2QQSect-1.8 P-1QQSect-1.8 P-2QQSect-1.8 P-3QQSect-1.8 P-4QQSect-1.8 P-5QQSect-1.8 P-6QQSect-1.8 P-7QQSect-1.9 P-1QQSect-1.9 P-2QQSect-1.10 P-1QQSect-1.10 P-2QQSect-1.11 P-1QQSect-1.11 P-2QQSect-1.11 P-3QQSect-1.12 P-1QQSect-1.12 P-2QQSect-1.12 P-3QQSect-1.13 P-1QQSect-1.13 P-2QQSect-1.13 P-3QQSect-1.14 P-1QQSect-1.14 P-2QQSect-1.14 P-3QQSect-1.15 P-1QQSect-1.15 P-2QQSect-1.16 P-1QQSect-1.16 P-2QQSect-1.16 P-3QQSect-1.17 P-1QQSect-1.17 P-2QQSect-1.17 P-3QQSect-1.17 P-4QQSect-1.18 P-1QQSect-1.18 P-2QQSect-1.18 P-3QQSect-1.18 P-4QQCh-1 P-1.1EPCh-1 P-1.2EPCh-1 P-1.3EPCh-1 P-1.4EPCh-1 P-1.5EPCh-1 P-1.6EPCh-1 P-1.7EPCh-1 P-1.8EPCh-1 P-1.9EPCh-1 P-1.10EPCh-1 P-1.11EPCh-1 P-1.12EPCh-1 P-1.13EPCh-1 P-1.14EPCh-1 P-1.15EPCh-1 P-1.16EPCh-1 P-1.17EPCh-1 P-1.18EPCh-1 P-1.19EPCh-1 P-1.20EPCh-1 P-1.21EPCh-1 P-1.22EPCh-1 P-1.23EPCh-1 P-1.24EPCh-1 P-1.25EPCh-1 P-1.26EPCh-1 P-1.27EPCh-1 P-1.28EPCh-1 P-1.29EPCh-1 P-1.30EPCh-1 P-1.31EPCh-1 P-1.32EPCh-1 P-1.33EPCh-1 P-1.34EPCh-1 P-1.35EPCh-1 P-1.36EPCh-1 P-1.37EPCh-1 P-1.38EPCh-1 P-1.39EPCh-1 P-1.40EPCh-1 P-1.41EPCh-1 P-1.42EPCh-1 P-1.43EPCh-1 P-1.44EPCh-1 P-1.45EPCh-1 P-1.46EPCh-1 P-1.47EPCh-1 P-1.48EPCh-1 P-1.49EPCh-1 P-1.50EPCh-1 P-1.51EPCh-1 P-1.52EPCh-1 P-1.53EPCh-1 P-1.54EPCh-1 P-1.55EPCh-1 P-1.56EPCh-1 P-1.57EPCh-1 P-1.58EPCh-1 P-1.59EPCh-1 P-1.60EPCh-1 P-1.61EPCh-1 P-1.62EPCh-1 P-1.63EPCh-1 P-1.64EPCh-1 P-1.65EPCh-1 P-1.66EPCh-1 P-1.67EPCh-1 P-1.68EPCh-1 P-1.69EPCh-1 P-1.70EPCh-1 P-1.71EPCh-1 P-1.72EPCh-1 P-1.73EPCh-1 P-1.74EPCh-1 P-1.75EPCh-1 P-1.76EPCh-1 P-1.77EPCh-1 P-1.78EPCh-1 P-1.79EPCh-1 P-1.80EPCh-1 P-1.81EPCh-1 P-1.82EPCh-1 P-1.83EPCh-1 P-1.84EPCh-1 P-1.85EPCh-1 P-1.86EPCh-1 P-1.87EPCh-1 P-1.88EPCh-1 P-1.89EPCh-1 P-1.90EPCh-1 P-1.91EPCh-1 P-1.92EPCh-1 P-1.93EPCh-1 P-1.94EPCh-1 P-1.95EPCh-1 P-1.96EPCh-1 P-1.97EPCh-1 P-1.98EPCh-1 P-1.99EPCh-1 P-1.100EPCh-1 P-1.101EPCh-1 P-1.102EPCh-1 P-1.103EPCh-1 P-1.104EPCh-1 P-1.105EPCh-1 P-1.106EPCh-1 P-1.107EPCh-1 P-1.108EPCh-1 P-1.109EPCh-1 P-1.110EPCh-1 P-1.111EPCh-1 P-1.112EPCh-1 P-1.113EPCh-1 P-1.114EPCh-1 P-1.115EPCh-1 P-1.116EPCh-1 P-1.117EPCh-1 P-1.118EPCh-1 P-1.119EPCh-1 P-1.120EPCh-1 P-1.121EPCh-1 P-1.122EPCh-1 P-1.123EPCh-1 P-1.124EPCh-1 P-1.125EPCh-1 P-1.126EPCh-1 P-1.127EPCh-1 P-1.128EPCh-1 P-1.129EPCh-1 P-1.130EPCh-1 P-1.131EPCh-1 P-1.132EPCh-1 P-1.133EPCh-1 P-1.134EPCh-1 P-1.135EPCh-1 P-1.136EPCh-1 P-1.137EPCh-1 P-1.138EPCh-1 P-1.139EPCh-1 P-1.140EPCh-1 P-1.141EPCh-1 P-1.142EPCh-1 P-1.143EPCh-1 P-1.144EPCh-1 P-1.145EPCh-1 P-1.146EPCh-1 P-1.147EPCh-1 P-1.148EP

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