Modern Physics
2nd Edition
ISBN: 9780805303087
Author: Randy Harris
Publisher: Addison Wesley
expand_more
expand_more
format_list_bulleted
Question
Chapter 10, Problem 42E
To determine
Four wavelengthsthat might be absorbed by CO in vibration rotation transitions.
Expert Solution & Answer
Want to see the full answer?
Check out a sample textbook solution
Students have asked these similar questions
Assume that the H2 molecule behaves exactly like a harmonic oscillator with a force constant of 573N/m.
(a) Find the energy (in eV) of its ground and first excited vibrational states.
(b) Find the vibrational quantum number that approximately corresponds to its 4.5-eV dissociation energy.
A CO molecule is initially in the n = 2 vibrational level. If this molecule loses both vibrational and rotational energy and emits a photon, what are the photon wavelength and frequency if the initial angular momentum quantum number is l = 3?
A 1H 19F molecule, with a bond length of 91.68 pm, absorbed on the surface and rotates in twodimensions.
A) What is the smallest quantum energy that can be absorbed by this molecule in afirst rotational excitation?B) Calculate the zero-point energy for this molecule
Chapter 10 Solutions
Modern Physics
Ch. 10 - Prob. 1CQCh. 10 - Prob. 2CQCh. 10 - Prob. 3CQCh. 10 - Of N2,O2 , and F2 , none has an electric dipole...Ch. 10 - It takes less energy to dissociate a diatomic...Ch. 10 - Prob. 6CQCh. 10 - Prob. 7CQCh. 10 - Prob. 8CQCh. 10 - Prob. 9CQCh. 10 - Prob. 10CQ
Ch. 10 - Prob. 11CQCh. 10 - In the boron atom, the single 2p electron does not...Ch. 10 - Prob. 13CQCh. 10 - Prob. 14CQCh. 10 - Prob. 15CQCh. 10 - Prob. 16CQCh. 10 - Prob. 17CQCh. 10 - Prob. 18CQCh. 10 - Prob. 19CQCh. 10 - Prob. 20CQCh. 10 - Prob. 21CQCh. 10 - Prob. 22CQCh. 10 - In a buckyball three of the bonds around each...Ch. 10 - Prob. 24CQCh. 10 - Prob. 25ECh. 10 - Prob. 26ECh. 10 - Prob. 27ECh. 10 - Prob. 28ECh. 10 - Prob. 29ECh. 10 - Prob. 30ECh. 10 - Prob. 31ECh. 10 - Prob. 32ECh. 10 - Prob. 33ECh. 10 - Prob. 34ECh. 10 - By expanding an arbitrary U(x) in a power series...Ch. 10 - Prob. 36ECh. 10 - Prob. 37ECh. 10 - Prob. 38ECh. 10 - Prob. 39ECh. 10 - Prob. 40ECh. 10 - Prob. 41ECh. 10 - Prob. 42ECh. 10 - Prob. 43ECh. 10 - As noted in Example 10.2, the HD molecule differs...Ch. 10 - Prob. 45ECh. 10 - Prob. 46ECh. 10 - Prob. 47ECh. 10 - Prob. 48ECh. 10 - Prob. 49ECh. 10 - Prob. 50ECh. 10 - Prob. 51ECh. 10 - Prob. 52ECh. 10 - Prob. 53ECh. 10 - Prob. 54ECh. 10 - Carry out the integration indicated in equation...Ch. 10 - Prob. 56ECh. 10 - Prob. 57ECh. 10 - Prob. 58ECh. 10 - Prob. 59ECh. 10 - Prob. 60ECh. 10 - Prob. 61ECh. 10 - Prob. 62ECh. 10 - Prob. 63ECh. 10 - Prob. 64ECh. 10 - Prob. 65ECh. 10 - Prob. 66ECh. 10 - Prob. 67ECh. 10 - Prob. 68ECh. 10 - Prob. 69ECh. 10 - Prob. 70ECh. 10 - Prob. 71ECh. 10 - Prob. 72ECh. 10 - Prob. 73ECh. 10 - Prob. 74ECh. 10 - The magnetic field at the surface of a long Wire...Ch. 10 - Prob. 76ECh. 10 - Prob. 77CECh. 10 - Prob. 78CECh. 10 - Prob. 79CE
Knowledge Booster
Similar questions
- The measured density of a KCl crystal is 1.984 g/cm3. What is the equilibrium separation distance of K+ and Cl- ions?arrow_forwardCompare the effective force constant for the CO molecule deduced here with that of an ordinary laboratory spring that stretches 0.5 m when a 1.0 kg mass is suspended from it.arrow_forwardThe photon frequency that would be absorbed by the NO molecule in a transition from vibration state v = 0 to v = 1, with no change in rotation state, is 56.3 THz. The bond between the atoms has an effective spring constant of 1 530 N/m. (a) Use this information to calculate the reduced mass of the NO molecule. (b) Compute a value for using Equation 42.4. (c) Compare your results to parts (a) and (b) and explain their difference, if any.arrow_forward
- The Madelung constant for the NaCl structure may be found by summing an infinite alternating series of terms giving the electrostatic potential energy between an Na+ ion and its 6 nearest Cl neighbors, its 12 next-nearest N+ neighbors, and so on (see Fig. 12.1a). (a) From this expression, show that the first three terms of the infinite series for the Madelung constant for the NaCl structure yield = 2.13. (b) Does this infinite series converge rapidly? Calculate the fourth term as a check.arrow_forwardThe figure above shows the absorption spectrum of the molecule HBr. Following the basic procedures of Section 9.6, find:(a) the energy of the “missing” transition;(b) the effective force constant k;(c) the rotational spacing 2B. Estimate the value of the rotational spacing expected for HBr and compare with the value deduced from the spectrum. Why are there only single lines and not double lines as in the case of HCl?arrow_forwardIf the moment of inertia of 1H 127I is 4.31 x 10-47 kg m2. Determine the bond length of HI and the rotational energy at quantum number J=5 Please to respond quickly.arrow_forward
- The equilibrium separation between the two ions in the KCl molecule is 0.267 nm. (a) Assuming that the K+ and Cl- ions are point particles, compute the electric dipole moment of the molecule. (b) Compute the ratio of your result in (a) to the measured electric dipole moment of 5.41 x 10-29 C*m. This ratio is known as the fractional ionic character of the molecular bond.arrow_forwardThe first three absorption lines in the pure rotational spectrum of gaseous 12C16O are found to have the frequencies 1.15 × 1011, 2.30 × 1011, and 3.46 × 1011 s21. Calculate:(a) The moment of inertia I of CO (in kg m2)(b) The energies of the J 5 1, J 5 2, and J 5 3 rotational levels of CO, measured from the J 5 0 state (in joules)(c) The CUO bond length (in angstroms)arrow_forwardThe rotational constant of 12C160 2 (from Raman spectroscopy) is 11.70 GHz. What is the CO bond length in themolecule?arrow_forward
- Explain why “bands” may not be the most accurate descriptionof bonding in a solid when the solid has nanoscaledimensionsarrow_forwardFind the amplitude of the ground-state vibrations of the CO molecule. What percentage of the bond length is this? Assume the molecule vibrates like a harmonic oscillator.arrow_forwardSuppose that the wavenumber of the J = 1 ← 0 rotational transition of 1H81Br considered as a rigid rotor was measured to be 18.20 cm-1, what is (a) the moment of inertia of the molecule? _____________kg-m2 (b) the bond length? ________________Angstroms (Given the isotopic masses:(m(79Br) = 78.9183 amu, m(81Br) = 80.9163 amuarrow_forward
arrow_back_ios
SEE MORE QUESTIONS
arrow_forward_ios
Recommended textbooks for you
Modern PhysicsPhysicsISBN:9781111794378Author:Raymond A. Serway, Clement J. Moses, Curt A. MoyerPublisher:Cengage Learning
Physics for Scientists and Engineers with Modern ...PhysicsISBN:9781337553292Author:Raymond A. Serway, John W. JewettPublisher:Cengage Learning
Glencoe Physics: Principles and Problems, Student...PhysicsISBN:9780078807213Author:Paul W. ZitzewitzPublisher:Glencoe/McGraw-Hill
University Physics Volume 3PhysicsISBN:9781938168185Author:William Moebs, Jeff SannyPublisher:OpenStax
Modern Physics
Physics
ISBN:9781111794378
Author:Raymond A. Serway, Clement J. Moses, Curt A. Moyer
Publisher:Cengage Learning
Physics for Scientists and Engineers with Modern ...
Physics
ISBN:9781337553292
Author:Raymond A. Serway, John W. Jewett
Publisher:Cengage Learning
Glencoe Physics: Principles and Problems, Student...
Physics
ISBN:9780078807213
Author:Paul W. Zitzewitz
Publisher:Glencoe/McGraw-Hill
University Physics Volume 3
Physics
ISBN:9781938168185
Author:William Moebs, Jeff Sanny
Publisher:OpenStax