Modern Physics
Modern Physics
2nd Edition
ISBN: 9780805303087
Author: Randy Harris
Publisher: Addison Wesley
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Chapter 10, Problem 44E

As noted in Example 10.2, the HD molecule differs from H, in that a deuterium atom replaces a hydrogen atom. (a) What effect, if any, does the replacement have on the bond length and force constant? Explain. (b) What effect does it have on the rotational energy levels? (c) And what effect does it have on the vibrational energy levels?

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Suppose that the wavenumber of the J = 1 ← 0 rotational transition of 1H81Br considered as a rigid rotor was measured to be 18.20 cm-1, what is (a) the moment of inertia of the molecule? _____________kg-m2 (b) the bond length? ________________Angstroms (Given the isotopic masses:(m(79Br) = 78.9183 amu, m(81Br) = 80.9163 amu
The figure above shows the absorption spectrum of the molecule HBr. Following the basic procedures of Section 9.6, find:(a) the energy of the “missing” transition;(b) the effective force constant k;(c) the rotational spacing 2B. Estimate the value of the rotational spacing expected for HBr and compare with the value deduced  from the spectrum. Why are there only single lines and not double lines as in the case of HCl?
Show that the moment of inertia of a diatomic molecule composed of atoms of masses mA and mB and bond length R is equal to meffR2, where meff = mAmB/(mA + mB).

Chapter 10 Solutions

Modern Physics

Ch. 10 - Prob. 11CQCh. 10 - In the boron atom, the single 2p electron does not...Ch. 10 - Prob. 13CQCh. 10 - Prob. 14CQCh. 10 - Prob. 15CQCh. 10 - Prob. 16CQCh. 10 - Prob. 17CQCh. 10 - Prob. 18CQCh. 10 - Prob. 19CQCh. 10 - Prob. 20CQCh. 10 - Prob. 21CQCh. 10 - Prob. 22CQCh. 10 - In a buckyball three of the bonds around each...Ch. 10 - Prob. 24CQCh. 10 - Prob. 25ECh. 10 - Prob. 26ECh. 10 - Prob. 27ECh. 10 - Prob. 28ECh. 10 - Prob. 29ECh. 10 - Prob. 30ECh. 10 - Prob. 31ECh. 10 - Prob. 32ECh. 10 - Prob. 33ECh. 10 - Prob. 34ECh. 10 - By expanding an arbitrary U(x) in a power series...Ch. 10 - Prob. 36ECh. 10 - Prob. 37ECh. 10 - Prob. 38ECh. 10 - Prob. 39ECh. 10 - Prob. 40ECh. 10 - Prob. 41ECh. 10 - Prob. 42ECh. 10 - Prob. 43ECh. 10 - As noted in Example 10.2, the HD molecule differs...Ch. 10 - Prob. 45ECh. 10 - Prob. 46ECh. 10 - Prob. 47ECh. 10 - Prob. 48ECh. 10 - Prob. 49ECh. 10 - Prob. 50ECh. 10 - Prob. 51ECh. 10 - Prob. 52ECh. 10 - Prob. 53ECh. 10 - Prob. 54ECh. 10 - Carry out the integration indicated in equation...Ch. 10 - Prob. 56ECh. 10 - Prob. 57ECh. 10 - Prob. 58ECh. 10 - Prob. 59ECh. 10 - Prob. 60ECh. 10 - Prob. 61ECh. 10 - Prob. 62ECh. 10 - Prob. 63ECh. 10 - Prob. 64ECh. 10 - Prob. 65ECh. 10 - Prob. 66ECh. 10 - Prob. 67ECh. 10 - Prob. 68ECh. 10 - Prob. 69ECh. 10 - Prob. 70ECh. 10 - Prob. 71ECh. 10 - Prob. 72ECh. 10 - Prob. 73ECh. 10 - Prob. 74ECh. 10 - The magnetic field at the surface of a long Wire...Ch. 10 - Prob. 76ECh. 10 - Prob. 77CECh. 10 - Prob. 78CECh. 10 - Prob. 79CE
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