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(a)
Interpretation:
Condensed structural formula of the organic product that is formed when 3-pentanone is treated with hydrogen in presence of nickel catalyst has to be given.
Concept Introduction:
In
In organic chemistry, reduction reaction is referred to the number
Alcohols undergo oxidation reaction and reduction reaction. This depends upon the number of hydrogen atoms that is bonded to the alpha carbon atom. Primary and secondary alcohol undergoes oxidation reaction while tertiary alcohol does not undergo oxidation reaction. Primary alcohols undergo oxidation to give
Aldehyde undergoes oxidation to give carboxylic acid as the product while ketone does not undergo oxidation reaction.
The reverse of
(b)
Interpretation:
Condensed structural formula of the organic product that is formed when 3-pentanone is treated with methanol in 1 to 1 reacting ratio has to be given.
Concept Introduction:
Aldehydes contain a carbonyl group that is bonded to a hydrogen atom and a carbon atom. Ketones are compounds that contain a carbonyl group bonded to two carbon atoms. Aldehydes and ketones undergo addition reaction across the carbonyl group.
Aldehydes and ketones react with alcohol to form hemiacetal as the product. This reacts with further molecule of aldehyde or ketone to form acetal.
Hemiacetal is an addition product that is obtained by reaction between aldehyde or ketone with alcohol. The general reaction of hemiacetal formation can be given as,
(c)
Interpretation:
Condensed structural formula of the organic product that is formed when 3-pentanone is treated with ethanol in 1 to 2 reacting ratio has to be given.
Concept Introduction:
Aldehydes contain a carbonyl group that is bonded to a hydrogen atom and a carbon atom. Ketones are compounds that contain a carbonyl group bonded to two carbon atoms. Aldehydes and ketones undergo addition reaction across the carbonyl group.
Aldehydes and ketones react with alcohol to form hemiacetal as the product. This reacts with further molecule of aldehyde or ketone to form acetal.
Hemiacetal is an addition product that is obtained by reaction between aldehyde or ketone with alcohol. The general reaction of hemiacetal formation can be given as,
From the above general structure of hemiacetal it is found that it is an organic compound that contains a carbon atom that is bonded to an alkoxy group and a hydroxyl group.
Acetal is formed when the formed hemiacetal reacts with further alcohol molecule so that the hydroxyl group in the hemiacetal is converted into alkoxy group. This can be shown as given below,
The alcohol that is reacting with the hemiacetal can be from the same alcohol which involved in formation of hemiacetal or a different alcohol molecule. Therefore, the ketone or aldehyde must react with two alcohol molecules that may or may not be identical to form acetal.
(d)
Interpretation:
Condensed structural formula of the organic product that is formed when 3-pentanone is treated with
Concept Introduction:
In organic chemistry, oxidation reaction is referred to the number
In organic chemistry, reduction reaction is referred to the number
Alcohols undergo oxidation reaction and reduction reaction. This depends upon the number of hydrogen atoms that is bonded to the alpha carbon atom. Primary and secondary alcohol undergoes oxidation reaction while tertiary alcohol does not undergo oxidation reaction. Primary alcohols undergo oxidation to give aldehyde and carboxylic acid as product. Secondary alcohol undergoes oxidation to give ketone as the product.
Aldehyde undergoes oxidation to give carboxylic acid as the product while ketone does not undergo oxidation reaction.
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Chapter 15 Solutions
EBK GENERAL, ORGANIC, AND BIOLOGICAL CH
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- 3). reactions of the following alkyl iodide. Danny uses potassium tert-butoxide to promote the reaction while Claire uses water and high temperatures. One of their reactions has provided a single elimination isomer while the other has provided a mixture of elimination isomers. Organic chemistry students Danny and Claire are both performing elimination Me H20, heat Danny's Reaction Claire's Reaction H. Me a) Which student's reaction (Danny or Claire) has provided a single elimination isomer? b) Draw all the elimination isomers obtained from both students' reactions. c) Which of the dienes drawn (by you) in question 3b is the most stable? Circle that diene above.arrow_forwardDraw the major organic product for each of the following reactions. You must show the correct stereochemistry of the product where relevant.arrow_forwardIdentify ALL the CORRECT statements regarding the compound shown below. SELECT ALL THAT APPLY A. The compound is a heterocycle B. The compound is found in DNA C. The compound is a pentose sugar D. The compound is a purinearrow_forward
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- What is the major organic product obtained from the following sequence of reactions? 4 1 2 3 2. H3O+ يديا 2 3 NH2arrow_forwardConsider these compounds: A. PbBr, B. MnS C. Ag,CO3 D. AIPO, Complete the following statements by entering the letter(s) corresponding to the correct compound(s). (If more than one compound fits the description, include all the relevant compounds by writing your answer as a string of characters without punctuation, e.g, ABC.) Without doing any calculations it is possible to determine that magnesium fluoride is more soluble than and magnesium fluoride is less soluble than| It is not possible to determine whether magnesium fluoride is more or less soluble than by simply comparing Kgp values.arrow_forwardDraw a structure for the compound, C3H5Br, that fits the following 1H NMR data: δ 2.32 (3H, singlet) δ 5.35 (1H, broad singlet) δ 5.54 (1H, broad singlet)arrow_forward
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