![EBK GENERAL, ORGANIC, AND BIOLOGICAL CH](https://www.bartleby.com/isbn_cover_images/8220100853180/8220100853180_largeCoverImage.jpg)
(a)
Interpretation:
The structure of alcohol that is required to prepare the given aldehyde has to be drawn.
Concept Introduction:
Carbonyl compounds such as
(b)
Interpretation:
The structure of alcohol that is required to prepare the given ketone has to be drawn.
Concept Introduction:
Carbonyl compounds such as aldehydes and ketones can be synthesized by oxidation or reduction reaction. When a primary alcohol undergoes oxidation reaction, the product obtained is carboxylic acid that is formed through the intermediate aldehyde. When mild oxidizing agent is used, aldehyde can be obtained as product from primary alcohol. When a secondary alcohol undergoes oxidation reaction, the product obtained is a ketone. This cannot be further oxidized. Tertiary alcohols do not undergo oxidation reaction. Some of the mild oxidizing agents used are
(c)
Interpretation:
The structure of alcohol that is required to prepare the given ketone has to be drawn.
Concept Introduction:
Carbonyl compounds such as aldehydes and ketones can be synthesized by oxidation or reduction reaction. When a primary alcohol undergoes oxidation reaction, the product obtained is carboxylic acid that is formed through the intermediate aldehyde. When mild oxidizing agent is used, aldehyde can be obtained as product from primary alcohol. When a secondary alcohol undergoes oxidation reaction, the product obtained is a ketone. This cannot be further oxidized. Tertiary alcohols do not undergo oxidation reaction. Some of the mild oxidizing agents used are
(d)
Interpretation:
The structure of alcohol that is required to prepare the given ketone has to be drawn.
Concept Introduction:
Carbonyl compounds such as aldehydes and ketones can be synthesized by oxidation or reduction reaction. When a primary alcohol undergoes oxidation reaction, the product obtained is carboxylic acid that is formed through the intermediate aldehyde. When mild oxidizing agent is used, aldehyde can be obtained as product from primary alcohol. When a secondary alcohol undergoes oxidation reaction, the product obtained is a ketone. This cannot be further oxidized. Tertiary alcohols do not undergo oxidation reaction. Some of the mild oxidizing agents used are
![Check Mark](/static/check-mark.png)
Want to see the full answer?
Check out a sample textbook solution![Blurred answer](/static/blurred-answer.jpg)
Chapter 15 Solutions
EBK GENERAL, ORGANIC, AND BIOLOGICAL CH
- What functional group is formed on oxidation of a secondary alcohol? Demonstrate your answer using isopropanol.arrow_forwardName the following compound: HO HO H H OH H. OH но он ÓH H HO, а. Ketose b. Maltose c. Sucrose d. Aldosearrow_forwardIndicate whether the following pairs of monosaccharides are aldoses or ketoses. a. D-altrose & D-xylose b. D-arabinose & D-glyceraldehyde c. D-erythrulose & D-psicose d. D-talose & D-gulose e. dihydroxyacetone & D-tagatose f. D-idose & D-threosearrow_forward
- Galactose can exist as a cyclic hemiacetal because one of the alcohol groups reacts with the aldehyde. 1 2 3 4 он он о Н Он Он о CH2-CH-CH-CH-CH-C-H 6. CH2-OH OH C он 10 он C 8. H. H. OH Which carbon atom of the cyclic hemiacetal was originally a part of the aldehyde group? Carbon: Which alcohol group in the open-chain structure became a part of the cyclic hemiacetal? Alcohol:arrow_forwardPropose a scheme to separate and isolate a mixture containing 4-aminobenzoate, 1,2,4,5-tetrachlorobenzene, and napthalene. Isolate two of the three solids by extraction. (please explain what solvents to use and the process step by step)arrow_forwardd) Consider the following disaccharide C. i. ii. iii. iv. OH HO OH OH HO Disaccharide C OH OH OH Give the IUPAC name for disaccharide C. What is the type of glycosidic linkage. Is disaccharide C a reducing sugar? Does it mutarotate? Explain your answer. What products are formed when disaccharide C is hydrolysed with H3O+.arrow_forward
- Mestranol, sold under the brand names Enovid, Norinyl, and Ortho-Novum among others, is an estrogen medication which has been used in birth control pills. Select all of the functional group families, to which mestranol belongs. Choose one or more: O A. ester OB. alkene OC. ether O D. thiol O E. alcohol OF. arene OG. aldehyde OH. ketone O 1. alkyne OHarrow_forward(a) Label all the O atoms that are part of a glycoside in rebaudioside A. Rebaudioside A, marketed under the trade name Truvia, is a sweet glycoside obtained from the stevia plant, which has been used for centuries in Paraguay to sweeten foods. (b) The alcohol or phenol formed from the hydrolysis of a glycoside is called an aglycon. What aglycon and monosaccharides are formed by the hydrolysis of rebaudioside A?arrow_forwardDescribe any two heteropolysaccharides in terms of: a. The types of monosaccharides involved b. types of glycosidic linkages, and c. possible hydrolysatesarrow_forward
- In the monosaccharide derivatives known as sugar alcohols, the carbonyl oxygen is reduced to a hydroxyl group. For example, D-glyceraldehyde can be reduced to glycerol. However, this sugar alcohol is no longer designated D or L. Why?arrow_forwardIdentify the type of isomerism exhibited by the following pairs of monosaccharides D-glyceraldehyde & dihydroxyacetone D-glucose & D-mannose α-D-glucose & β-D-glucose d-galactose & l-galactose D-glucose & D-allose A. optical isomers B. Diastereomers C. Epimers D. enantiomers E. Functional Isomersarrow_forwardDaclatasvir is formulated at the dihydrochloride salt. Which functional group in Daclatasvir will be protonated? (structure shown below) OA Carbonyl B. Ester OC Imidazole OD. Amide O E. Carbamatearrow_forward
- Human Anatomy & Physiology (11th Edition)BiologyISBN:9780134580999Author:Elaine N. Marieb, Katja N. HoehnPublisher:PEARSONBiology 2eBiologyISBN:9781947172517Author:Matthew Douglas, Jung Choi, Mary Ann ClarkPublisher:OpenStaxAnatomy & PhysiologyBiologyISBN:9781259398629Author:McKinley, Michael P., O'loughlin, Valerie Dean, Bidle, Theresa StouterPublisher:Mcgraw Hill Education,
- Molecular Biology of the Cell (Sixth Edition)BiologyISBN:9780815344322Author:Bruce Alberts, Alexander D. Johnson, Julian Lewis, David Morgan, Martin Raff, Keith Roberts, Peter WalterPublisher:W. W. Norton & CompanyLaboratory Manual For Human Anatomy & PhysiologyBiologyISBN:9781260159363Author:Martin, Terry R., Prentice-craver, CynthiaPublisher:McGraw-Hill Publishing Co.Inquiry Into Life (16th Edition)BiologyISBN:9781260231700Author:Sylvia S. Mader, Michael WindelspechtPublisher:McGraw Hill Education
![Text book image](https://www.bartleby.com/isbn_cover_images/9780134580999/9780134580999_smallCoverImage.gif)
![Text book image](https://www.bartleby.com/isbn_cover_images/9781947172517/9781947172517_coverImage_Textbooks.gif)
![Text book image](https://www.bartleby.com/isbn_cover_images/9781259398629/9781259398629_smallCoverImage.gif)
![Text book image](https://www.bartleby.com/isbn_cover_images/9780815344322/9780815344322_smallCoverImage.gif)
![Text book image](https://www.bartleby.com/isbn_cover_images/9781260159363/9781260159363_smallCoverImage.gif)
![Text book image](https://www.bartleby.com/isbn_cover_images/9781260231700/9781260231700_smallCoverImage.gif)