   Chapter 3, Problem 74GQ

Chapter
Section
Textbook Problem

Identify and name the water-insoluble product in each reaction and write the net ionic equation:(a) CuCl2(aq) + H2S(aq) → CuS + 2 HCl(b) CaCl2(aq) + K2CO3(aq) → 2 KCl + CaCO3(c) AgNO3(aq) + Nal(aq) → AgI + NaNO3

(a)

Interpretation Introduction

Interpretation:

Net ionic equation and water insoluble product should be identified for given reaction.

Concept introduction:

The law of conservation of mass states that no atoms can be created or destroyed in a chemical reaction, therefore, the number of atoms present in the reactants is equal to the number of atoms present in the products.

Most of the ionic compounds are soluble in water, very few of the ionic compounds are sparingly soluble, and some of the ionic compounds are insoluble in water.  When it is soluble in water ions gets separated in the solution.

Soluble compounds in water

Almost all the salts of Na+, K+, NH4+,(NO3-),(ClO3-)(ClO4-)and(CH3CO2-) are soluble.

Almost all the salts of Cl-, Br-, I-(halides) are soluble.  But some of the halides (Ag+, Hg22+, Pb2+) are insoluble.

Salts of F- are soluble.  But some of the fluoride salt of Mg2+, Ca2+, Sr2+, Ba2+, Pb2+ are insoluble.

Salts of sulfate (SO42-) are soluble.  But sulfates of Ca2+, Sr2+, Ba2+, Pb2+, Ag+, are insoluble.

Insoluble compounds in water:

Most of the salts of (CO32-),(PO43-),(C2O42-),(CrO42-)and(S2-) are insoluble but some of the salts of NH4+, alkali metal cations and BaS are soluble.

Most of the metal hydroxides and oxides are insoluble in water bit some of the alkali metal hydroxides, Ba(OH)2and Sr(OH)2 are soluble in water.

Explanation

The equation for the given reaction is shown below

The total net ionic equation is given below,

The net ionic equation of the given reaction is shown below

The water insoluble product is CuS.

Because, Most of the salts of (CO32-

(b)

Interpretation Introduction

Interpretation:

Net ionic equation and water insoluble product should be identified for given reaction.

Concept introduction:

The law of conservation of mass states that no atoms can be created or destroyed in a chemical reaction, therefore, the number of atoms present in the reactants is equal to the number of atoms present in the products.

Most of the ionic compounds are soluble in water, very few of the ionic compounds are sparingly soluble, and some of the ionic compounds are insoluble in water.  When it is soluble in water ions gets separated in the solution.

Soluble compounds in water

Almost all the salts of Na+, K+, NH4+,(NO3-),(ClO3-)(ClO4-)and(CH3CO2-) are soluble.

Almost all the salts of Cl-, Br-, I-(halides) are soluble.  But some of the halides (Ag+, Hg22+, Pb2+) are insoluble.

Salts of F- are soluble.  But some of the fluoride salt of Mg2+, Ca2+, Sr2+, Ba2+, Pb2+ are insoluble.

Salts of sulfate (SO42-) are soluble.  But sulfates of Ca2+, Sr2+, Ba2+, Pb2+, Ag+, are insoluble.

Insoluble compounds in water:

Most of the salts of (CO32-),(PO43-),(C2O42-),(CrO42-)and(S2-) are insoluble but some of the salts of NH4+, alkali metal cations and BaS are soluble.

Most of the metal hydroxides and oxides are insoluble in water bit some of the alkali metal hydroxides, Ba(OH)2and Sr(OH)2 are soluble in water.

(c)

Interpretation Introduction

Interpretation:

Net ionic equation and water insoluble product should be identified for given reaction.

Concept introduction:

The law of conservation of mass states that no atoms can be created or destroyed in a chemical reaction, therefore, the number of atoms present in the reactants is equal to the number of atoms present in the products.

Most of the ionic compounds are soluble in water, very few of the ionic compounds are sparingly soluble, and some of the ionic compounds are insoluble in water.  When it is soluble in water ions gets separated in the solution.

Soluble compounds in water

Almost all the salts of Na+, K+, NH4+,(NO3-),(ClO3-)(ClO4-)and(CH3CO2-) are soluble.

Almost all the salts of Cl-, Br-, I-(halides) are soluble.  But some of the halides (Ag+, Hg22+, Pb2+) are insoluble.

Salts of F- are soluble.  But some of the fluoride salt of Mg2+, Ca2+, Sr2+, Ba2+, Pb2+ are insoluble.

Salts of sulfate (SO42-) are soluble.  But sulfates of Ca2+, Sr2+, Ba2+, Pb2+, Ag+, are insoluble.

Insoluble compounds in water:

Most of the salts of (CO32-),(PO43-),(C2O42-),(CrO42-)and(S2-) are insoluble but some of the salts of NH4+, alkali metal cations and BaS are soluble.

Most of the metal hydroxides and oxides are insoluble in water bit some of the alkali metal hydroxides, Ba(OH)2and Sr(OH)2 are soluble in water.

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