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ChemistryOrganic And Biological Chemistry7th Edition

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Chapter 5, Problem 5.31EP
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Organic And Biological Chemistry

7th Edition
STOKER + 1 other
ISBN: 9781305081079

Solutions

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Organic And Biological Chemistry

7th Edition
STOKER + 1 other
ISBN: 9781305081079
Textbook Problem

Each of the following acids contains an additional type of functional group besides the carboxyl group. For each acid, specify the noncarboxyl functional group present.

  1. a. Acrylic acid
  2. b. Lactic acid
  3. c. Maleic acid
  4. d. Glycolic acid

(a)

Interpretation Introduction

Interpretation:

The noncarboxyl functional group that is present in acrylic acid has to be given.

Concept Introduction:

Carbonyl groups are the one which contain a double bond between carbon and oxygen atom.  Aldehydes and ketones possess this carbonyl functional group in it.  The structural representation of a carbonyl group can be given as shown below,

Organic And Biological Chemistry, Chapter 5, Problem 5.31EP , additional homework tip 1

If a hydroxyl group is attached to a carbonyl group means it is known as carboxyl group.  This can be represented as shown below,

Organic And Biological Chemistry, Chapter 5, Problem 5.31EP , additional homework tip 2

Apart from carboxyl group, there can be other functional group also that is present in the carboxylic acid.  They are known as polyfunctional carboxylic acids.  These occur naturally also.  Some of the important type of polyfunctional carboxylic acids are hydroxy acids, keto acids, and unsaturated acids.

Explanation

Structure of acrylic acid can be given as,

The functional groups present in acrylic acid can be shown as given below,

(b)

Interpretation Introduction

Interpretation:

The noncarboxyl functional group that is present in lactic acid has to be given.

Concept Introduction:

Carbonyl groups are the one which contain a double bond between carbon and oxygen atom.  Aldehydes and ketones possess this carbonyl functional group in it.  The structural representation of a carbonyl group can be given as shown below,

Organic And Biological Chemistry, Chapter 5, Problem 5.31EP , additional homework tip 3

If a hydroxyl group is attached to a carbonyl group means it is known as carboxyl group.  This can be represented as shown below,

Organic And Biological Chemistry, Chapter 5, Problem 5.31EP , additional homework tip 4

Apart from carboxyl group, there can be other functional group also that is present in the carboxylic acid.  They are known as polyfunctional carboxylic acids.  These occur naturally also.  Some of the important type of polyfunctional carboxylic acids are hydroxy acids, keto acids, and unsaturated acids.

(c)

Interpretation Introduction

Interpretation:

The noncarboxyl functional group that is present in maleic acid has to be given.

Concept Introduction:

Carbonyl groups are the one which contain a double bond between carbon and oxygen atom.  Aldehydes and ketones possess this carbonyl functional group in it.  The structural representation of a carbonyl group can be given as shown below,

Organic And Biological Chemistry, Chapter 5, Problem 5.31EP , additional homework tip 5

If a hydroxyl group is attached to a carbonyl group means it is known as carboxyl group.  This can be represented as shown below,

Organic And Biological Chemistry, Chapter 5, Problem 5.31EP , additional homework tip 6

Apart from carboxyl group, there can be other functional group also that is present in the carboxylic acid.  They are known as polyfunctional carboxylic acids.  These occur naturally also.  Some of the important type of polyfunctional carboxylic acids are hydroxy acids, keto acids, and unsaturated acids.

(d)

Interpretation Introduction

Interpretation:

The noncarboxyl functional group that is present in glycolic acid has to be given.

Concept Introduction:

Carbonyl groups are the one which contain a double bond between carbon and oxygen atom.  Aldehydes and ketones possess this carbonyl functional group in it.  The structural representation of a carbonyl group can be given as shown below,

Organic And Biological Chemistry, Chapter 5, Problem 5.31EP , additional homework tip 7

If a hydroxyl group is attached to a carbonyl group means it is known as carboxyl group.  This can be represented as shown below,

Organic And Biological Chemistry, Chapter 5, Problem 5.31EP , additional homework tip 8

Apart from carboxyl group, there can be other functional group also that is present in the carboxylic acid.  They are known as polyfunctional carboxylic acids.  These occur naturally also.  Some of the important type of polyfunctional carboxylic acids are hydroxy acids, keto acids, and unsaturated acids.

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Sect-5.1 P-1QQSect-5.1 P-2QQSect-5.1 P-3QQSect-5.1 P-4QQSect-5.1 P-5QQSect-5.2 P-1QQSect-5.2 P-2QQSect-5.2 P-3QQSect-5.2 P-4QQSect-5.2 P-5QQ
Sect-5.3 P-1QQSect-5.3 P-2QQSect-5.3 P-3QQSect-5.4 P-1QQSect-5.4 P-2QQSect-5.4 P-3QQSect-5.5 P-1QQSect-5.5 P-2QQSect-5.5 P-3QQSect-5.6 P-1QQSect-5.6 P-2QQSect-5.7 P-1QQSect-5.7 P-2QQSect-5.7 P-3QQSect-5.8 P-1QQSect-5.8 P-2QQSect-5.8 P-3QQSect-5.8 P-4QQSect-5.9 P-1QQSect-5.9 P-2QQSect-5.10 P-1QQSect-5.10 P-2QQSect-5.11 P-1QQSect-5.11 P-2QQSect-5.11 P-3QQSect-5.12 P-1QQSect-5.12 P-2QQSect-5.12 P-3QQSect-5.12 P-4QQSect-5.13 P-1QQSect-5.13 P-2QQSect-5.14 P-1QQSect-5.14 P-2QQSect-5.14 P-3QQSect-5.15 P-1QQSect-5.15 P-2QQSect-5.15 P-3QQSect-5.16 P-1QQSect-5.16 P-2QQSect-5.16 P-3QQSect-5.17 P-1QQSect-5.17 P-2QQSect-5.18 P-1QQSect-5.18 P-2QQSect-5.18 P-3QQSect-5.19 P-1QQSect-5.19 P-2QQSect-5.19 P-3QQSect-5.19 P-4QQSect-5.20 P-1QQSect-5.20 P-2QQSect-5.20 P-3QQSect-5.20 P-4QQCh-5 P-5.1EPCh-5 P-5.2EPCh-5 P-5.3EPCh-5 P-5.4EPCh-5 P-5.5EPCh-5 P-5.6EPCh-5 P-5.7EPCh-5 P-5.8EPCh-5 P-5.9EPCh-5 P-5.10EPCh-5 P-5.11EPCh-5 P-5.12EPCh-5 P-5.13EPCh-5 P-5.14EPCh-5 P-5.15EPCh-5 P-5.16EPCh-5 P-5.17EPCh-5 P-5.18EPCh-5 P-5.19EPCh-5 P-5.20EPCh-5 P-5.21EPCh-5 P-5.22EPCh-5 P-5.23EPCh-5 P-5.24EPCh-5 P-5.25EPCh-5 P-5.26EPCh-5 P-5.27EPCh-5 P-5.28EPCh-5 P-5.29EPCh-5 P-5.30EPCh-5 P-5.31EPCh-5 P-5.32EPCh-5 P-5.33EPCh-5 P-5.34EPCh-5 P-5.35EPCh-5 P-5.36EPCh-5 P-5.37EPCh-5 P-5.38EPCh-5 P-5.39EPCh-5 P-5.40EPCh-5 P-5.41EPCh-5 P-5.42EPCh-5 P-5.43EPCh-5 P-5.44EPCh-5 P-5.45EPCh-5 P-5.46EPCh-5 P-5.47EPCh-5 P-5.48EPCh-5 P-5.49EPCh-5 P-5.50EPCh-5 P-5.51EPCh-5 P-5.52EPCh-5 P-5.53EPCh-5 P-5.54EPCh-5 P-5.55EPCh-5 P-5.56EPCh-5 P-5.57EPCh-5 P-5.58EPCh-5 P-5.59EPCh-5 P-5.60EPCh-5 P-5.61EPCh-5 P-5.62EPCh-5 P-5.63EPCh-5 P-5.64EPCh-5 P-5.65EPCh-5 P-5.66EPCh-5 P-5.67EPCh-5 P-5.68EPCh-5 P-5.69EPCh-5 P-5.70EPCh-5 P-5.71EPCh-5 P-5.72EPCh-5 P-5.73EPCh-5 P-5.74EPCh-5 P-5.75EPCh-5 P-5.76EPCh-5 P-5.77EPCh-5 P-5.78EPCh-5 P-5.79EPCh-5 P-5.80EPCh-5 P-5.81EPCh-5 P-5.82EPCh-5 P-5.83EPCh-5 P-5.84EPCh-5 P-5.85EPCh-5 P-5.86EPCh-5 P-5.87EPCh-5 P-5.88EPCh-5 P-5.89EPCh-5 P-5.90EPCh-5 P-5.91EPCh-5 P-5.92EPCh-5 P-5.93EPCh-5 P-5.94EPCh-5 P-5.95EPCh-5 P-5.96EPCh-5 P-5.97EPCh-5 P-5.98EPCh-5 P-5.99EPCh-5 P-5.100EPCh-5 P-5.101EPCh-5 P-5.102EPCh-5 P-5.103EPCh-5 P-5.104EPCh-5 P-5.105EPCh-5 P-5.106EPCh-5 P-5.107EPCh-5 P-5.108EPCh-5 P-5.109EPCh-5 P-5.110EPCh-5 P-5.111EPCh-5 P-5.112EPCh-5 P-5.113EPCh-5 P-5.114EPCh-5 P-5.115EPCh-5 P-5.116EPCh-5 P-5.117EPCh-5 P-5.118EPCh-5 P-5.119EPCh-5 P-5.120EPCh-5 P-5.121EPCh-5 P-5.122EPCh-5 P-5.123EPCh-5 P-5.124EPCh-5 P-5.125EPCh-5 P-5.126EPCh-5 P-5.127EPCh-5 P-5.128EPCh-5 P-5.129EPCh-5 P-5.130EPCh-5 P-5.131EPCh-5 P-5.132EPCh-5 P-5.133EPCh-5 P-5.134EPCh-5 P-5.135EPCh-5 P-5.136EPCh-5 P-5.137EPCh-5 P-5.138EPCh-5 P-5.139EPCh-5 P-5.140EPCh-5 P-5.141EPCh-5 P-5.142EPCh-5 P-5.143EPCh-5 P-5.144EPCh-5 P-5.145EPCh-5 P-5.146EPCh-5 P-5.147EPCh-5 P-5.148EPCh-5 P-5.149EPCh-5 P-5.150EPCh-5 P-5.151EPCh-5 P-5.152EPCh-5 P-5.153EPCh-5 P-5.154EPCh-5 P-5.155EPCh-5 P-5.156EPCh-5 P-5.157EPCh-5 P-5.158EPCh-5 P-5.159EPCh-5 P-5.160EPCh-5 P-5.161EPCh-5 P-5.162EPCh-5 P-5.163EPCh-5 P-5.164EP

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