EBK GENERAL, ORGANIC, & BIOLOGICAL CHEM
3rd Edition
ISBN: 9781259298424
Author: SMITH
Publisher: VST
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Textbook Question
Chapter 11, Problem 11.68P
1,1-Dichloroethylene
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Compare the polarity of the C-Cl bond in (CH3)3C-Cl with the polarity of the Si-Cl bond in (CH3)3Si-Cl.
Your chemistry professor draws a number of molecules on the board: (1) CH4 ; (2) H2C=CH2 ; (3) H2C=C=CH2 ; and (4) H2C=C=C=CH2. You muse about all the molecules that chemists draw on a two-dimensional board and wonder which ones are actually planar, existing basically as they appear on the board, and which ones are not plane but rather three-dimensional.
Answer ALL of the following questions.
What are the specific orbital overlaps (i.e., sp3-sp3) that are in each of the molecules?
What are the bond angles for each central atom in each molecule?
Which molecules are planar and which are non-planar?
Your chemistry professor draws a number of molecules on the board: (1) CH4 ; (2) H2C=CH2 ; (3) H2C=C=CH2 ; and (4) H2C=C=C=CH2. You muse about all the molecules that chemists draw on a two-dimensional board and wonder which ones are actually planar, existing basically as they appear on the board, and which ones are not plane but rather three-dimensional.
Answer the following questions.
What is the geometry and hybridization of the carbon in CH4?
What is the geometry and hybridization of each central carbon atom in the remaining molecules?
Draw each molecule showing the bonds and identify each bond in all the molecules as s or p.
What are the specific orbital overlaps (i.e., sp3-sp3) that are in each of the molecules?
What are the bond angles for each central atom in each molecule?
Which molecules are planar and which are non-planar?
Chapter 11 Solutions
EBK GENERAL, ORGANIC, & BIOLOGICAL CHEM
Ch. 11.1 - Prob. 11.1PCh. 11.2 - Fill in all H's and lone pairs in each compound.Ch. 11.3 - Prob. 11.3PCh. 11.3 - Prob. 11.4PCh. 11.3 - Prob. 11.5PCh. 11.3 - Prob. 11.6PCh. 11.3 - How many lone pairs are present in lidocaine, the...Ch. 11.4 - Convert each compound to a condensed formula.Ch. 11.4 - Convert each condensed formula to a complete...Ch. 11.4 - Convert each skeletal structure to a complete...
Ch. 11.4 - How many H’s are bonded to each indicated carbon...Ch. 11.5 - Prob. 11.12PCh. 11.5 - For each compound: [1] Identify the functional...Ch. 11.5 - Prob. 11.14PCh. 11.5 - Prob. 11.15PCh. 11.5 - Prob. 11.16PCh. 11.5 - Identify all of the functional groups in atenolol,...Ch. 11.5 - Prob. 11.18PCh. 11.5 - Prob. 11.19PCh. 11.6 - Indicate the polar bonds in each compound. Label...Ch. 11.6 - Prob. 11.21PCh. 11.6 - Prob. 11.22PCh. 11.6 - Predict the water solubility of each compound....Ch. 11.6 - Prob. 11.24PCh. 11.7 - Prob. 11.25PCh. 11.7 - Prob. 11.26PCh. 11 - Prob. 11.27PCh. 11 - Prob. 11.28PCh. 11 - Complete each structure by filling in all H’s and...Ch. 11 - Prob. 11.30PCh. 11 - Prob. 11.31PCh. 11 - Prob. 11.32PCh. 11 - Prob. 11.33PCh. 11 - Prob. 11.34PCh. 11 - “Ecstasy” is a widely used illegal stimulant....Ch. 11 - Prob. 11.36PCh. 11 - Explain why each C—C—C bond angle in benzene...Ch. 11 - Prob. 11.38PCh. 11 - Prob. 11.39PCh. 11 - Prob. 11.40PCh. 11 - Convert each compound to a skeletal structure.Ch. 11 - Convert each compound to a skeletal structure.Ch. 11 - Convert each shorthand structure to a complete...Ch. 11 - Convert each shorthand structure to a complete...Ch. 11 - A and B are ball-and-stick models of two compounds...Ch. 11 - Prob. 11.46PCh. 11 - What is wrong in each of the following shorthand...Ch. 11 - Prob. 11.48PCh. 11 - Prob. 11.49PCh. 11 - Albuterol (trade names Proventil and Ventolin) is...Ch. 11 - Prob. 11.51PCh. 11 - Prob. 11.52PCh. 11 - Prob. 11.53PCh. 11 - Prob. 11.54PCh. 11 - Prob. 11.55PCh. 11 - GHB is an addictive, illegal recreational drug...Ch. 11 - Prob. 11.57PCh. 11 - Prob. 11.58PCh. 11 - Prob. 11.59PCh. 11 - Prob. 11.60PCh. 11 - Prob. 11.61PCh. 11 - Prob. 11.62PCh. 11 - You are given two unlabeled bottles of solids, one...Ch. 11 - State how potassium iodide (KI) and pentane...Ch. 11 - The given beaker contains 100 mL of the organic...Ch. 11 - Prob. 11.66PCh. 11 - Why do we need to know the shape of a molecule...Ch. 11 - 1,1-Dichloroethylene (CH2=CCl2) is a starting...Ch. 11 - Indicate the polar bonds in each molecule. Label...Ch. 11 - Indicate the polar bonds in each molecule. Label...Ch. 11 - Classify each molecule as polar or nonpolar.Ch. 11 - Classify each molecule as polar or nonpolar. a....Ch. 11 - Which molecule is more water soluble? Explain.Ch. 11 - Explain why pantothenic acid, vitamin B5, is water...Ch. 11 - Prob. 11.75PCh. 11 - Prob. 11.76PCh. 11 - Explain why regularly taking a large excess of a...Ch. 11 - You can obtain the minimum daily requirement of...Ch. 11 - Prob. 11.79PCh. 11 - Vitamin B6 is obtained by eating a diet that...Ch. 11 - Prob. 11.81PCh. 11 - Can an oxygen-containing organic compound, have...Ch. 11 - Prob. 11.83PCh. 11 - Prob. 11.84PCh. 11 - Benzocaine is the active ingredient in topical...Ch. 11 - Methyl salicylate is responsible for the...Ch. 11 - Answer the following questions about aldosterone,...Ch. 11 - Answer the following questions about...Ch. 11 - Prob. 11.89PCh. 11 - Skin moisturizers come in two types, (a) One type...Ch. 11 - THC is the active component in marijuana (Section...Ch. 11 - Cocaine is a widely abused, addicting drug....
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