Concept explainers
Interpretation:
For the given MO diagram of
Concept introduction:
The MO arises from interacting p AOs of two atoms. MO energies differ as a result of constructive and destructive interference among contributing AOs. Each pair of overlapping AOs with the same phase lowers the MO energy and corresponds to a bonding interaction in an MO while each pair of overlapping AOs with the opposite phases raises the MO energy and corresponds to an antibonding interaction in an MO. The destructive interference gives rise to a nodal plane. The contributions of the AOs to produce a bonding, nonbonding, or antibonding MO depend on the net interaction. In the MO diagram, only
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ORGANIC CHEMISTRY E-BOOK W/SMARTWORK5
- Please construct the MO diagrams of NH3 and NH4+and use their MO’s toexplain the protonation (acid-base reaction) of NH3arrow_forwardPlease solve correctly. Need both subparts to be solv. (Gpt/Ai wrong ans not allowed)arrow_forwardDraw an exact 3-D representation of the molecule from the model. Please must mention: valency electron, molecular geometryarrow_forward
- Draw one all-bonding MO, thena pair of degenerate MOs, and then a final pair of degenerate MOs. Draw the energydiagram, fill in the electrons, and confirm the electronic configurations of the cyclopentadienyl cation and anionarrow_forward( plz complete the follow , do all plz as they are subpart)arrow_forwardHelp,please provide explanation! (a) Draw the orbital picture for diazomethane (shown below) showing the explicit overlap of the contributing AO's. (b) Draw the MO energy diagram for diazomethane and identify the HOMO and LUMO.arrow_forward
- 1. A species that is magnetic will have ____________ electrons. 2. When two sets of two p orbitals on different atoms combine at a total of _____ molecular orbitals are formed. Please do it neat and clean correctly Don't copy by somewhere posting third please do it correctlyarrow_forwarda.Determine the number of nodes and rank them in order of increasing energy. b.Draw the p atomic orbital contributions on each carbon atom (AO mixing pattern) that would give rise to the MO. c. Based on your answer to part (c) -determine whether each MO is overall bonding, nonbonding, or antibonding. Please explain stepsarrow_forwardHelp me complete these MO diagrams and the questionsarrow_forward
- Determine the absolute configuration of the chiral C in this molecule. (kindly show explanation or illustration. thank you!) Choices: A. R/S not applicableB. SC. Rarrow_forwardalso specify the integration valuesfor all Hs in each molecule.arrow_forward3) Combine any Atomic orbitals to form Molecular orbitals assuming they fulfill the phase and energy requirement. Construct MO diagram (include AOs, MOs, pictures of each, electrons, HOMO, LUMO, B.O., and comparative energies, etc.). REMOVE an ELECTRON to form CATION Please only do part 3. The first image shows the problemarrow_forward
- Organic Chemistry: A Guided InquiryChemistryISBN:9780618974122Author:Andrei StraumanisPublisher:Cengage Learning