(a)
Interpretation:
The structural formulas for the products of hydrolysis of the given acetal in aqueous acid has to be drawn.
Concept introduction:
Acetals are a group of organic compound that contain two alkoxy (-OR) groups on the same carbon atom.
Acetals can be hydrolysed by addition of dilute acid. The excess of water drives the equilibrium toward the formation of the
(b)
Interpretation:
The structural formulas for the products of hydrolysis of the given acetal in aqueous acid has to be drawn.
Concept introduction:
Acetals are a group of organic compound that contain two alkoxy (-OR) groups on the same carbon atom.
Acetals can be hydrolysed by addition of dilute acid. The excess of water drives the equilibrium toward the formation of the ketone or aldehyde and two molecules of alcohol or one molecule of diol.
(c)
Interpretation:
The structural formulas for the products of hydrolysis of the given acetal in aqueous acid has to be drawn.
Concept introduction:
Acetals are a group of organic compound that contain two alkoxy (-OR) groups on the same carbon atom.
Acetals can be hydrolysed by addition of dilute acid. The excess of water drives the equilibrium toward the formation of the ketone or aldehyde and two molecules of alcohol or one molecule of diol.
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Chapter 16 Solutions
Organic Chemistry
- Aldehydes and ketones react with one molecule of an alcohol to form compounds called hemiacetals, in which there is one hydroxyl group and one ether-like group. Reaction of a hemiacetal with a second molecule of alcohol gives an acetal and a molecule of water. We study this reaction in Chapter 16. Draw structural formulas for the hemiacetal and acetal formed from these reagents. The stoichiometry of each reaction is given in the problem.arrow_forwardDraw the structural formula for each of the following and give the classification 10, 20, 30. Draw any oxidation products resulting from a reaction with chromic acid. cyclopropanol 1-methylcyclobutanol 2-methyl-1-hexanol 1-methylcyclohexanol 3-methylcyclohexanol 2,2-dimethylcyclohexanolarrow_forwardOxidation of an aldehyde yields a carboxylic acidarrow_forward
- Draw structural formulas for the products of hydrolysis of the following acetal in aqueous HCl.arrow_forwardThe reaction of a ketone with an alcohol in acidic conditions will result in: an alkane an acetal a geminal (gem) diol an alkenearrow_forwardComplete the following statements: a. Oxidation of a secondary alcohol produces ___________. b. Oxidation of a primary alcohol produces an aldehyde that can be further oxidized to a ________. c. Hydrogenation of a ketone produces __________. d. Hydrogenation of an aldehyde produces __________. e. Hydrolysis of an acetal produces _________. f. Hydrolysis of a ketal produces _________.arrow_forward
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