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Interpretation:
Skeletal structural formula of three isomeric trisubstituted ammonium ions that have chemical formula of
Concept Introduction:
Substituted ammonium ion is the one in which one or more alkyl, aryl, or cycloalkyl groups are substituted instead of hydrogen atoms. There are two important generalizations that is applied to the substituted ammonium ion and they are,
- Substituted ammonium ions are not neutral molecules. They are charged species.
- Nitrogen atom has four bonds in ammonium ion or substituted ammonium ion. The species is positively charged as the fourth bond formed is a coordinate covalent bond.
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Chapter 17 Solutions
EBK GENERAL, ORGANIC, AND BIOLOGICAL CH
- Given the titration curve of the hypothetical polyprotic acid X at 0.100 M concentration (pKa1=4.0, pKa2=8.0, pKa3=12.0) titrated with 0.600 M NaOH, identify the pH at point C, H, E, and M.arrow_forwardWrite the structural formula of a triacylglycerol that contains one unit each of lauric acid, palmitic acid, and oleic acid. How many other triacylglycerols, each containing all three of these acids, are possible?arrow_forwardDraw the condensed structural formula for the fatty acid whose numerical shorthand designation is 18:2 (△ 9,12)arrow_forward
- Sketch a titration curve and the structures of the major ionic forms of glutamic acid that exist in solution at the noted parts of the titration curve. Refer to the fully pronated glutamic acid and the pKa.arrow_forward9. 1.4 g of glucose (C6H1206) is dissolved in 150 ml of water (final volume). What is the final number of moles and the molarity of the solution?arrow_forwardDraw dipeptide Arg-Thr at pH 6.0. Circle the six atoms that are restricted in one plane. Calculate its approximate pI assuming pKa for NH3+ is 10.0, pKa for COOH is 3.0, PKR for Arg is 12.0arrow_forward
- What is the pH of a glycine solution in which the alpha-carboxyl group is one third dissociated? Given pka1=2.3, pka2=9.6arrow_forwardDraw structures of glyceryl tripalmitate and glyceryl trioleate. Which would you expect to have a higher melting point?arrow_forwardUsing skeletal structures, draw the structure of a simple triacylglyceride containing 1 eicosapentanoic acid, 1 myristic acid and 1 oleic acid residues, with label.arrow_forward
- Draw the structures of the following acids:(a) 2-Ethyl-3-hydroxyhexanoic acid (b) m-Nitrobenzoic acidarrow_forwardDraw condensed structural formulas for all products obtained from the complete hydrolysis of the following triacylglycerol.arrow_forwardGlycine hydrochloride (Cl− H3N+CH2COOH) is a diprotic acid that contains a carboxylic acid group and an ammonium group and is therefore called an amino acid. It is often used in biochemical buffers. Solve, (b) Write the chemical equations describing the dissociation of the first and second protons of Cl−H3N+CH2COOH.arrow_forward
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