(a) Interpretation: The curved-arrow mechanism for the given decarboxylation reaction is to be stated. Concept introduction: The term decarboxylation means the loss of a carbon dioxide molecule. The decarboxylation of carboxylic acids leads to the formation of alkane . The decarboxylation of the carboxylic acid can be done by heating it in acidic solution.

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Answer 1

Question

Chapter 20, Problem 20.53AP

Interpretation Introduction

(a)

Interpretation:

The curved-arrow mechanism for the given decarboxylation reaction is to be stated.

Concept introduction:

The term decarboxylation means the loss of a carbon dioxide molecule. The decarboxylation of carboxylic acids leads to the formation of alkane. The decarboxylation of the carboxylic acid can be done by heating it in acidic solution.

Interpretation Introduction

(b)

Interpretation:

An explanation as to why neither very low pH nor very high pH is suitable for the decarboxylation of the given reaction is to be stated.

Concept introduction:

The term decarboxylation means the loss of a carbon dioxide molecule. The decarboxylation of carboxylic acids leads to the formation of alkane. The decarboxylation of the carboxylic acid can be done on heating in acidic solution.

Interpretation Introduction

(c)

Interpretation:

An explanation as to how the primary amines catalyze the decarboxylation of acetoacetic acid is to be stated.

Concept introduction:

The term decarboxylation means the loss of a carbon dioxide molecule. The decarboxylation of carboxylic acids leads to the formation of alkane. The decarboxylation of the carboxylic acid can be done on heating in acidic solution.

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Answer 2

Question

Chapter 20, Problem 20.53AP

Interpretation Introduction

(a)

Interpretation:

The curved-arrow mechanism for the given decarboxylation reaction is to be stated.

Concept introduction:

The term decarboxylation means the loss of a carbon dioxide molecule. The decarboxylation of carboxylic acids leads to the formation of alkane. The decarboxylation of the carboxylic acid can be done by heating it in acidic solution.

Interpretation Introduction

(b)

Interpretation:

An explanation as to why neither very low pH nor very high pH is suitable for the decarboxylation of the given reaction is to be stated.

Concept introduction:

The term decarboxylation means the loss of a carbon dioxide molecule. The decarboxylation of carboxylic acids leads to the formation of alkane. The decarboxylation of the carboxylic acid can be done on heating in acidic solution.

Interpretation Introduction

(c)

Interpretation:

An explanation as to how the primary amines catalyze the decarboxylation of acetoacetic acid is to be stated.

Concept introduction:

The term decarboxylation means the loss of a carbon dioxide molecule. The decarboxylation of carboxylic acids leads to the formation of alkane. The decarboxylation of the carboxylic acid can be done on heating in acidic solution.

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Answer 3

Question

Chapter 20, Problem 20.53AP

Interpretation Introduction

(a)

Interpretation:

The curved-arrow mechanism for the given decarboxylation reaction is to be stated.

Concept introduction:

The term decarboxylation means the loss of a carbon dioxide molecule. The decarboxylation of carboxylic acids leads to the formation of alkane. The decarboxylation of the carboxylic acid can be done by heating it in acidic solution.

Interpretation Introduction

(b)

Interpretation:

An explanation as to why neither very low pH nor very high pH is suitable for the decarboxylation of the given reaction is to be stated.

Concept introduction:

The term decarboxylation means the loss of a carbon dioxide molecule. The decarboxylation of carboxylic acids leads to the formation of alkane. The decarboxylation of the carboxylic acid can be done on heating in acidic solution.

Interpretation Introduction

(c)

Interpretation:

An explanation as to how the primary amines catalyze the decarboxylation of acetoacetic acid is to be stated.

Concept introduction:

The term decarboxylation means the loss of a carbon dioxide molecule. The decarboxylation of carboxylic acids leads to the formation of alkane. The decarboxylation of the carboxylic acid can be done on heating in acidic solution.

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Answer 4

Question

Chapter 20, Problem 20.53AP

Interpretation Introduction

(a)

Interpretation:

The curved-arrow mechanism for the given decarboxylation reaction is to be stated.

Concept introduction:

The term decarboxylation means the loss of a carbon dioxide molecule. The decarboxylation of carboxylic acids leads to the formation of alkane. The decarboxylation of the carboxylic acid can be done by heating it in acidic solution.

Interpretation Introduction

(b)

Interpretation:

An explanation as to why neither very low pH nor very high pH is suitable for the decarboxylation of the given reaction is to be stated.

Concept introduction:

The term decarboxylation means the loss of a carbon dioxide molecule. The decarboxylation of carboxylic acids leads to the formation of alkane. The decarboxylation of the carboxylic acid can be done on heating in acidic solution.

Interpretation Introduction

(c)

Interpretation:

An explanation as to how the primary amines catalyze the decarboxylation of acetoacetic acid is to be stated.

Concept introduction:

The term decarboxylation means the loss of a carbon dioxide molecule. The decarboxylation of carboxylic acids leads to the formation of alkane. The decarboxylation of the carboxylic acid can be done on heating in acidic solution.

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Answer 5

Chapter 20, Problem 20.53AP

Interpretation Introduction

(a)

Interpretation:

The curved-arrow mechanism for the given decarboxylation reaction is to be stated.

Concept introduction:

The term decarboxylation means the loss of a carbon dioxide molecule. The decarboxylation of carboxylic acids leads to the formation of alkane. The decarboxylation of the carboxylic acid can be done by heating it in acidic solution.

Interpretation Introduction

(b)

Interpretation:

An explanation as to why neither very low pH nor very high pH is suitable for the decarboxylation of the given reaction is to be stated.

Concept introduction:

The term decarboxylation means the loss of a carbon dioxide molecule. The decarboxylation of carboxylic acids leads to the formation of alkane. The decarboxylation of the carboxylic acid can be done on heating in acidic solution.

Interpretation Introduction

(c)

Interpretation:

An explanation as to how the primary amines catalyze the decarboxylation of acetoacetic acid is to be stated.

Concept introduction:

The term decarboxylation means the loss of a carbon dioxide molecule. The decarboxylation of carboxylic acids leads to the formation of alkane. The decarboxylation of the carboxylic acid can be done on heating in acidic solution.

Answer 6

Chapter 20, Problem 20.53AP

Interpretation Introduction

(a)

Interpretation:

The curved-arrow mechanism for the given decarboxylation reaction is to be stated.

Concept introduction:

The term decarboxylation means the loss of a carbon dioxide molecule. The decarboxylation of carboxylic acids leads to the formation of alkane. The decarboxylation of the carboxylic acid can be done by heating it in acidic solution.

Answer 7

Chapter 20, Problem 20.53AP

Interpretation Introduction

(a)

Interpretation:

The curved-arrow mechanism for the given decarboxylation reaction is to be stated.

Concept introduction:

The term decarboxylation means the loss of a carbon dioxide molecule. The decarboxylation of carboxylic acids leads to the formation of alkane. The decarboxylation of the carboxylic acid can be done by heating it in acidic solution.

Answer 8

Interpretation Introduction

(b)

Interpretation:

An explanation as to why neither very low pH nor very high pH is suitable for the decarboxylation of the given reaction is to be stated.

Concept introduction:

The term decarboxylation means the loss of a carbon dioxide molecule. The decarboxylation of carboxylic acids leads to the formation of alkane. The decarboxylation of the carboxylic acid can be done on heating in acidic solution.

Answer 9

Interpretation Introduction

(b)

Interpretation:

An explanation as to why neither very low pH nor very high pH is suitable for the decarboxylation of the given reaction is to be stated.

Concept introduction:

The term decarboxylation means the loss of a carbon dioxide molecule. The decarboxylation of carboxylic acids leads to the formation of alkane. The decarboxylation of the carboxylic acid can be done on heating in acidic solution.

Answer 10

Interpretation Introduction

(c)

Interpretation:

An explanation as to how the primary amines catalyze the decarboxylation of acetoacetic acid is to be stated.

Concept introduction:

The term decarboxylation means the loss of a carbon dioxide molecule. The decarboxylation of carboxylic acids leads to the formation of alkane. The decarboxylation of the carboxylic acid can be done on heating in acidic solution.

Answer 11

Interpretation Introduction

(c)

Interpretation:

An explanation as to how the primary amines catalyze the decarboxylation of acetoacetic acid is to be stated.

Concept introduction:

The term decarboxylation means the loss of a carbon dioxide molecule. The decarboxylation of carboxylic acids leads to the formation of alkane. The decarboxylation of the carboxylic acid can be done on heating in acidic solution.

Answer 12

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Answer 13

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Answer 14

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Answer 15

Ch. 20 - Prob. 20.1P Ch. 20 - Prob. 20.2P Ch. 20 - Prob. 20.3P Ch. 20 - Prob. 20.4P Ch. 20 - Prob. 20.5P Ch. 20 - Prob. 20.6P Ch. 20 - Prob. 20.7P Ch. 20 - Prob. 20.8P Ch. 20 - Prob. 20.9P Ch. 20 - Prob. 20.10P

Solution Summary: The author explains that the curved-arrow mechanism for the given decarboxylation reaction is shown in Figure 2 to 6.

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Chapter 20 Solutions