GENERAL CHEMISTRY-MOD.MASTERINGCHEM.
GENERAL CHEMISTRY-MOD.MASTERINGCHEM.
11th Edition
ISBN: 9780134193601
Author: Petrucci
Publisher: PEARSON
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Chapter 27, Problem 51E
Interpretation Introduction

Interpretation:

The method to synthesized (E)- and (Z)-hept-3-ene from the acetylene should be determined.

Concept introduction:

Alkyne can be reduced to cis-alkenes by the use of Lindlar’s catalyst and alkyne can be reduced to trans-alkenes by the use of Na/NH3 reagent.

Lindlar’s catalyst is a common reducing catalyst used to reduce internal carbon-carbon triple bond to give a cis-alkene. The general reduction reaction is as follows:

GENERAL CHEMISTRY-MOD.MASTERINGCHEM., Chapter 27, Problem 51E , additional homework tip  1

Sodium metal in liquid ammonia reduces internal carbon-carbon triple bond to give trans-alkene. The general reduction reaction of internal alkynes is as follows:

GENERAL CHEMISTRY-MOD.MASTERINGCHEM., Chapter 27, Problem 51E , additional homework tip  2

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Chapter 27 Solutions

GENERAL CHEMISTRY-MOD.MASTERINGCHEM.

Ch. 27 - Substitution and Elimination Reactions Answer the...Ch. 27 - Prob. 12ECh. 27 - Prob. 13ECh. 27 - Prob. 14ECh. 27 - Prob. 15ECh. 27 - Substitution and Elimination Reactions Molecule...Ch. 27 - Prob. 17ECh. 27 - Prob. 18ECh. 27 - Prob. 19ECh. 27 - Prob. 20ECh. 27 - Prob. 21ECh. 27 - Prob. 22ECh. 27 - Prob. 23ECh. 27 - Substitution and Elimination Reactions (R) — 2 —...Ch. 27 - Prob. 25ECh. 27 - Prob. 26ECh. 27 - Prob. 27ECh. 27 - Prob. 28ECh. 27 - Prob. 29ECh. 27 - Alcohols and Alkenes Predict the product(s) of the...Ch. 27 - Prob. 31ECh. 27 - Alcohols and Alkenes Give the structure of the...Ch. 27 - Alcohols and Alkenes Give the major product that...Ch. 27 - Prob. 34ECh. 27 - Prob. 35ECh. 27 - Prob. 36ECh. 27 - Prob. 37ECh. 27 - Prob. 38ECh. 27 - Prob. 39ECh. 27 - Prob. 40ECh. 27 - Prob. 41ECh. 27 - Prob. 42ECh. 27 - Reactions of Alkanes (a) Write the initiation,...Ch. 27 - Reactions of Alkanes Write the initiation,...Ch. 27 - Prob. 45ECh. 27 - Polymerization Reactions Explain why Dacron is...Ch. 27 - Prob. 47ECh. 27 - Prob. 48ECh. 27 - Prob. 49ECh. 27 - Prob. 50ECh. 27 - Prob. 51ECh. 27 - Prob. 52ECh. 27 - Prob. 53ECh. 27 - Prob. 54ECh. 27 - Prob. 55IAECh. 27 - Prob. 56IAECh. 27 - Prob. 57IAECh. 27 - Prob. 58IAECh. 27 - Prob. 59IAECh. 27 - Prob. 60IAECh. 27 - Prob. 61IAECh. 27 - Prob. 62IAECh. 27 - Prob. 63IAECh. 27 - Prob. 64IAECh. 27 - Prob. 65IAECh. 27 - Prob. 66IAECh. 27 - Prob. 67IAECh. 27 - Prob. 68IAECh. 27 - Prob. 69IAECh. 27 - Prob. 70IAECh. 27 - Prob. 71IAECh. 27 - Prob. 72IAECh. 27 - Prob. 73IAECh. 27 - Prob. 74IAECh. 27 - Prob. 75IAECh. 27 - Prob. 76IAECh. 27 - Prob. 77IAECh. 27 - The reduction of aldehydes and ketones with a...Ch. 27 - Explain the important distinctions between each...Ch. 27 - Prob. 80SAECh. 27 - Prob. 81SAECh. 27 - Prob. 82SAECh. 27 - Prob. 83SAECh. 27 - Prob. 84SAECh. 27 - What is the major organic product obtained in the...Ch. 27 - Prob. 86SAE
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