ORGANIC CHEMISTRY SMARTWORK5 - ACCESS
ORGANIC CHEMISTRY SMARTWORK5 - ACCESS
2nd Edition
ISBN: 9780393432534
Author: KARTY
Publisher: NORTON
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Chapter 7, Problem 7.7P
Interpretation Introduction

Interpretation:

Curved arrow notation to show the proton transfer steps that take place between LiAlH4 and H2O is to be drawn, and the product formed in the reaction is to be predicted. Also, curved arrow notations to show the proton transfer between NaBH4 and phenol is to be drawn.

Concept introduction:

The curved arrow notation for an elementary step reflects the flow of electrons from an electron-rich site to an electron-poor site.

Lithium aluminum hydride (LiAlH4) consists of Li+ and AlH4- ions. The reactive species is AlH4- which transfer the hydride ion (H-).

Sodium borohydride (NaBH4) consists of Na+ and BH4- ions. The reactive species is BH4- which transfers the hydride ion (H-).

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Chapter 7 Solutions

ORGANIC CHEMISTRY SMARTWORK5 - ACCESS

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