Concept explainers
Consider the following reaction for the combustion of octane,
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at volume of oxygen gas at STP would be needed for the complete combustion of
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Chapter 13 Solutions
Introductory Chemistry: A Foundation
- An organic compound contains C, H, N, and O. Combustion of 0.1023 g of the compound in excess oxygen yielded 0.2766 g CO2 and 0.0991 g H2O. A sample of 0.4831 g of the compound was analyzed for nitrogen by the Dumas method (see Exercise 129). At STP, 27.6 mL of dry N2 was obtained. In a third experiment, the density of the compound as a gas was found to be 4.02 g/L at 127C and 256 torr. What are the empirical and molecular formulas of the compound?arrow_forward5-118 Isooctane, which has a chemical formula C8H18 is the component of gasoline from which the term octane rating derives. (a) Write the balanced chemical equation for the combustion of isooctane. (b) The density of isooctane is 0.792 g/mL. How many kg of C02 are produced each year by the annual U.S. gasoline consumption of L? (c) What is the volume in liters of this CO2 at STP? (d) The chemical formula for isooctane can be represented by (CH3)3CCH2CH(CH3)2. Draw a Lewis structure of isooctane. (e) Another molecule with the same molecular formula is octane, which can be represented by: When comparing isooctane and octane, one structure is observed to have a boiling point of 99°C, while another is known to have a boiling point Of 125°C. Which substance, isooctane or octane, is expected to have the higher boiling point? (f) Determine whether isooctane or octane is expected to have the greater vapor pressure.arrow_forwardYou have an equimolar mixture of the gases SO2 and O2, along with some He, in a container fitted with a piston. The density of this mixture at STP is 1.924 g/L. Assume ideal behavior and constant temperature and pressure. a. What is the mole fraction of He in the original mixture? b. The SO2 and O2 react to completion to form SO3. What is the density of the gas mixture after the reaction is complete?arrow_forward
- 5-114 Carbon dioxide gas, saturated with water vapor, can be produced by the addition of aqueous acid to calcium carbonate based on the following balanced net ionic equation: (a) How many moles of wet CO (g), collected at 60.°C and 774 torr total pressure, are produced by the complete reaction of 10.0 g of CaCO3 with excess acid? (b) What volume does this wet CO2 occupy? (c) What volume would the CO2 occupy at 774 torr if a desiccant (a chemical drying agent) were added to remove the water? The vapor pressure of water at 60.°C is 149.4 mm Hg.arrow_forwardA sample of a smoke stack emission was collected into a 1.25-L tank at 752 mm Hg and analyzed. The analysis showed 92% CO2, 3.6% NO, 1.2% SO2, and 4.1% H2O by mass. What is the partial pressure exerted by each gas?arrow_forwardEthanol, C2H5OH, is produced industrially from ethylene, C2H4, by the following sequence of reactions: 3C2H4+2H2SO4C2H5HSO4+( C 2 H 5)2SO4C2H5HSO4+( C 2 H 5)2SO4+3H2O3C2H5OH+2H2SO4 What volume of ethylene at STP is required to produce 1.000 metric ton (1000 kg) of ethanol if the overall yield of ethanol is 90.1%?arrow_forward
- In the anaerobic oxidation of glucose by yeast, CO2 is produced: If 1.56 L of CO2 were produced at 22.0 C and 0.965 atm, what mass of C6H12O6 is consumed by the yeast? Assume the ideal gas law applied.arrow_forwardA chemist weighed out 5.14 g of a mixture containing unknown amounts of BaO(s) and CaO(s) and placed the sample in a 1.50-L flask containing CO2(g) at 30.0C and 750. torr. After the reaction to form BaCO3(s) and CaCO3(s) was completed, the pressure of CO2(g) remaining was 230. torr. Calculate the mass percentages of CaO(s) and BaO(s) in the mixture.arrow_forwardA 275-mL sample of CO gas is collected over water at 31C and 755 mmHg. If the temperature of the gas collection apparatus rises to 39C, what is the new volume of the sample? Assume that the barometric pressure does not change.arrow_forward
- A mixture contained calcium carbonate, CaCO3, and magnesium carbonate, MgCO3. A sample of this mixture weighing 7.85 g was reacted with excess hydrochloric acid. The reactions are CaCO3(g)+2HCL(aq)CaCl2(aq)+H2O(I)+CO2(g)MgCO3(s)+2HCL(aq)MgCl2(aq)+H2O(I)+CO2(g) If the sample reacted completely and produced 1.94 L of carbon dioxide, CO2, at 25C and 785 mmHg, what were the percentages of CaCO3 and MgCO3 in the mixture?arrow_forwardA person exhales about 5.8 102 L of carbon dioxide per day (at STP). The carbon dioxide exhaled by an astronaut is absorbed from the air of a space capsule by reaction with lithium hydroxide, LiOH. 2LiOH(s)+CO2(g)Li2CO3(s)+H2O(l) How many grams of lithium hydroxide are required per astronaut per day?arrow_forward51 What volume of oxygen at 24 C and 0.88 atm is needed to completely react via combustion with 45 g of methane gas?arrow_forward
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