(a)
Interpretation:
The reason as to why excess of acetylene is avoided in reaction of acetylene and ethylmagnesium bromide and its mechanism are tobe stated.
Concept introduction:
The compounds that contain carbon and hydrogen atoms are known as hydrocarbon compounds. These compounds originate from plants and animals. These are also known as organic compounds. There are two classes of hydrocarbon compounds which are saturated and
(b)
Interpretation:
The reason as to why excess of acetylene is avoided in reaction of ethynylmagnesium bromide and ethylmagnesium bromide and its mechanism are to be stated.
Concept introduction:
The compounds that contain carbon and hydrogen atoms are known as hydrocarbon compounds. These compounds originate from plants and animals. These are also known as organic compounds. There are two classes of hydrocarbon compounds which are saturated and unsaturated hydrocarbons. Unsaturated hydrocarbon compound are of two types alkenes and alkynes. The alkene contains a double bond between two carbon atoms. The alkynes contains a triple bond between two carbon atoms and follow general formula
(c)
Interpretation:
The reason as to why is it important for the side product to be soluble to minimize both side reactions discussed in part (a) and (b) is to be stated.
Concept introduction:
The compounds that contain carbon and hydrogen atoms are known as hydrocarbon compounds. These compounds originate from plants and animals. These are also known as organic compounds. There are two classes of hydrocarbon compounds which are saturated and unsaturated hydrocarbons. Unsaturated hydrocarbon compound are of two types alkenes and alkynes. The alkene contains a double bond between two carbon atoms. The alkynes contains a triple bond between two carbon atoms and follow general formula
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EBK ORGANIC CHEMISTRY
- (b) A student wanted to synthesize methyl tert-butyl ether. He attempted the synthesis by adding sodium methoxide to tert-butyl chloride, but he obtained none of the desired product (1) (ii) Use an equation to show the product formed in this reaction Propose a suitable William ether synthetic route for methyl tert-butyl ether tach l.arrow_forwardThe natural product halomon could theoretically arise from another naturally occurring compound known as myrcene. To accomplish this, a biochemical process that could deliver the synthetic equivalent of BrCi to all three double bonds would be required. (Chem Comm. 2014, 50, 13725) (a) Using three molar equivalents of BrCL please provide a mechanism to account for the formation of the bracketed structure (you do not need to show stereochemistry in this mechanism) HB (3 equiv) myrcene balomon 8.61a Add curved arrow(s) to show the mechanism steps. Edit Drawing sitsarrow_forwardSuggest the most appropriate method for each of the following laboratory syntheses.(a) cyclopentanol ¡ cyclopentanonearrow_forward
- 23.14arrow_forward(b) Analyze the major monosubstitution product from the Friedel-Crafts reaction of benzene with 1-chloro-2-methylpropane in the presence of AlCl3. Show your analysis using a mechanistic explanation. (c) Identify the carboxylic acid chloride that might be used in a Friedel-Crafts acylation reaction to prepare each of the following acylbenzene. or (i) Oarrow_forward(a) Explain the mechanism of a nucleophilic attack on the carbonyl group of an aldehyde or a ketone.(b) An organic compound (A) (molecular formula CgH16Q2) was hydrolysed with dilute sulphuric acid to give a carboxylic acid (B) and an alcohol (C). Oxidation of (C) with chromic acid also produced (B). On dehydration (C) gives but-1-ene. Write the equations for the reactions involved.arrow_forward
- Give an example for each describe the following reactions (i) Hoffmann’s bromide reaction (ii) Gattermann reaction (in) A coupling reactionarrow_forward(a) Given and Scara were given a task of synthesising (2-methylprop-1- enyl)cyclohexane 2 (A potential TB drug). After a brief discussion with each other, Given proposed Method A to synthesise 2 from cyclohexanecarbaldehyde 1 while Scara proposed Method B that started from hydroxymethylcyclohexane 3. When designing a synthetic route for drug molecule, you have to make sure the synthetic process is as efficient as possible (e.g. few synthetic steps, mostly making one product and more). THF A Ph Ph Ph B 3 1. PCC 2. isopropyl magnesium vromide 3. H₂SO4 100 °C OH Method B is not preferred synthetic route due to the number of steps involve (3 steps vs 1 step for Method A). What else is making method A unfavorable synthetic method? Use curly arrows to explain this effect. (Ctrl) -arrow_forward10.16 Design a preparation of each of the following compounds from an alcohol using sulfonate ester methodology. (a) (b) -CH,CH,CH,– SCH, 10.21 (a) According to the mechanism of the reaction shown in Eq. 10.34, what would be the absolute configuration of the alkyl chloride obtained from the reaction of thionyl chloride with (S)-CH,CH,CH,CHD-OH? Explain. (b) According to the mechanism shown in Eqs, 10,36a and 10.36b, what would be the absolute configuration of 2-bromopentane obtained from the reaction of Ph,PBr, with the R enantiomer of 2-pentanol? Explain.arrow_forward
- Organic ChemistryChemistryISBN:9781305580350Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. FootePublisher:Cengage Learning