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EBK ORGANIC CHEMISTRY
6th Edition
ISBN: 8220103151757
Author: LOUDON
Publisher: MAC HIGHER
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Chapter 14, Problem 14.7P
Interpretation Introduction
Interpretation:
The product which results from the addition of one equivalent of
Concept introduction:
A halogen group and a hydrogen halide group can be added to an alkyne to give a substituted alkene. The addition in
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Students have asked these similar questions
Draw the alkene that would react with the reagent given to account for the product formed.
CH3
HCI
CH3 CHCCH,
? +
Či CH3
You do not have to consider stereochemistry.
• You do not have to explicitly draw H atoms.
• In cases where there is more than one answer, just draw one.
What three alkenes (excluding stereoisomers) can be used to prepare 3chloro-3-methylhexane by addition of HCl?
Give the main organic product that would form after the
following reaction.
OMe
OMe
H₂O
H*
Chapter 14 Solutions
EBK ORGANIC CHEMISTRY
Ch. 14 - Prob. 14.1PCh. 14 - Prob. 14.2PCh. 14 - Prob. 14.3PCh. 14 - Prob. 14.4PCh. 14 - Prob. 14.5PCh. 14 - Prob. 14.6PCh. 14 - Prob. 14.7PCh. 14 - Prob. 14.8PCh. 14 - Prob. 14.9PCh. 14 - Prob. 14.10P
Ch. 14 - Prob. 14.11PCh. 14 - Prob. 14.12PCh. 14 - Prob. 14.13PCh. 14 - Prob. 14.14PCh. 14 - Prob. 14.15PCh. 14 - Prob. 14.16PCh. 14 - Prob. 14.17PCh. 14 - Prob. 14.18PCh. 14 - Prob. 14.19PCh. 14 - Prob. 14.20PCh. 14 - Prob. 14.21PCh. 14 - Prob. 14.22PCh. 14 - Prob. 14.23PCh. 14 - Prob. 14.24PCh. 14 - Prob. 14.25PCh. 14 - Prob. 14.26APCh. 14 - Prob. 14.27APCh. 14 - Prob. 14.28APCh. 14 - Prob. 14.29APCh. 14 - Prob. 14.30APCh. 14 - Prob. 14.31APCh. 14 - Prob. 14.32APCh. 14 - Prob. 14.33APCh. 14 - Prob. 14.34APCh. 14 - Prob. 14.35APCh. 14 - Prob. 14.36APCh. 14 - Prob. 14.37APCh. 14 - Prob. 14.38APCh. 14 - Prob. 14.39APCh. 14 - Prob. 14.40APCh. 14 - Prob. 14.41APCh. 14 - Prob. 14.42APCh. 14 - Prob. 14.43APCh. 14 - Prob. 14.44APCh. 14 - Prob. 14.45APCh. 14 - Prob. 14.46APCh. 14 - Prob. 14.47AP
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- Complete the following reaction by drawing a structural formula for the product. CH₂CH₂CCH3 + H₂ Ni or Pt • You do not have to consider stereochemistry. • You do not have to explicitly draw H atoms. CH4 - [ ] در ? ChemDoodlearrow_forwardSelect the reagent that you would use to convert an alkene to a Markovnikov (more substituted) alcohol without possibility of carbocation rearrangement. o H2SO4, H2O OBH3-THF, then H2O2, H2O, NaOH Hg(OAc)2, H2O, then NaBH4 o OsO4, TBHP, H2Oarrow_forwardIn the following series of reactions, write the product (s) or the reagents needed to obtain the indicated product.arrow_forward
- When 3-bromo-2,3-dimethylbutane is heated in sodium tert-butoxide, one major alkene is formed. In Part 1, draw this major alkene and all byproducts. In Part 2, indicate what type of mechanism leads to the formation of the alkene drawn in Part 1.arrow_forwardExplain why methyl trifluoroacetate, CF3CO2CH3, is more reactive than methyl acetate, CH3CO2CH3, in nucleophilic acyl substitution reactions.arrow_forwardConsider an acid-catalyzed dehydration reaction of 2-methyl-2-pentanol. Which product(s) would be produced?arrow_forward
- Explain why pentane-2,4-dione forms two different alkylation products (Aor B) when the number of equivalents of base is increased from one totwo.arrow_forward2. The following carbocation is generated as an intermediate in the addition of H-Br to an alkene. Draw the structure of all possible alkenes that could have formed this intermediate.arrow_forwardShow how to control the stereochemistry and regiochemistry (orientation) of additions to alkenes to obtain the products we want.arrow_forward
- Alkynes do not react directly with aqueous acid as do alkenes, but will do so in the presence of mercury(II) sulfate as a Lewis acid catalyst. The reaction occurs with Markovnikov regiochemistry, so the OH group adds to the more highly substituted carbon and the H adds to the less highly substituted carbon. The initial product of the reaction is a vinyl alcohol, also called an enol. The enol immediately rearranges to a more stable ketone via tautomerization. Draw curved arrows to show the movement of electrons in this step of the mechanism. Arrow-pushing Instructions -X티 Hö: H-O -CH3 -CH3 H30*arrow_forwardDraw one of the major products from this reaction. Use wedge and dash bonds to indicate relative stereochemistry where appropriate. Ignore inorganic byproducts. E CH212, Zn/Cu etherarrow_forwardDraw a structural formula of an alkene or alkenes (if more than one) that undergo acid-catalyzed hydration and without rearrangement give 1-methylcyclohexanol as the major product. You do not have to consider stereochemistry. • You do not have to explicitly draw H atoms. ● If more than one structure fits the description, draw them all. • Draw one structure per sketcher. Add additional sketchers using the drop-down menu in the bottom right corner. Separate structures with + signs from the drop-down menu. ● ● ✓ ? ChemDoodleⓇ n [ ]#arrow_forward
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