Chemistry: An Atoms First Approach
Chemistry: An Atoms First Approach
2nd Edition
ISBN: 9781305079243
Author: Steven S. Zumdahl, Susan A. Zumdahl
Publisher: Cengage Learning
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Chapter 3, Problem 43E

Would you expect each of the following atoms to gain or lose electrons when forming ions? What ion is the most likely in each case?

a. Ra

b. In

c. P

d. Te

e. Br

f. Rb

(a)

Expert Solution
Check Mark
Interpretation Introduction

Interpretation: The ability to lose or gain electrons of the given atom when forming ions is to be calculated. The ion most likely formed in each case is to be stated.

Concept introduction: Any atom or molecule gain or lose electrons to acquire stable state. An ion is a charged atom formed by the loss or gain of electron.

To determine: The Radium (Ra) atom loses or gain electrons while forming ion; the ion formed by Radium (Ra) atom.

Answer to Problem 43E

The Radium (Ra) atom loses electrons. The Radium (Ra) forms Ra2+ ion.

Explanation of Solution

  • To determine: The Radium atom loses or gain electrons.

Metals always loose electrons to form positive ion. They lose electron to acquire more stable state.

The electronic configuration of Radium is:

1s22s22p63s23p63d104s24p64d105s25p64f145d106s26p67s2

Radium is a metal hence, it lose electrons.

  • To determine: The ion formed by Radium (Ra) atom.

Explanation:

Radium atom contains two electrons in last s-sub shell. Hence it can loose two electrons to form Ra2+. The electronic configuration of Ra2+ is:

1s22s22p63s23p63d104s24p64d105s25p64f145d106s26p6

Conclusion

Generally metals lose electrons to acquire stable state whereas non- metals gain electrons.

(b)

Expert Solution
Check Mark
Interpretation Introduction

Interpretation: The ability to lose or gain electrons of the given atom when forming ions is to be calculated. The ion most likely formed in each case is to be stated.

Concept introduction: Any atom or molecule gain or lose electrons to acquire stable state. An ion is a charged atom formed by the loss or gain of electron.

To determine: The Indium (In) atom loses or gain electrons; the ion formed by Indium (In) atom.

Answer to Problem 43E

The Indium (In) atom loses electrons. The Indium (In) atom form In+,In3+ ions.

Explanation of Solution

  • To determine: The Indium atom loses or gain electrons.

Metals always loose electrons to form positive ion. They lose electron to acquire more stable state.

The electronic configuration of Indium is:

1s22s22p63s23p63d104s24p64d105s25p1

Indium is a metal hence, it lose electrons.

  • To determine: The ion formed by Indium (In) atom.

Indium atom contains one electron in last p-sub shell and two electrons in last s-sub shell. Hence it can loose one electron to form In+ and three electrons to form In3+. The electronic configuration of In+ and In3+ are:

1s22s22p63s23p63d104s24p64d105s2

1s22s22p63s23p63d104s24p64d10

(c)

Expert Solution
Check Mark
Interpretation Introduction

Interpretation: The ability to lose or gain electrons of the given atom when forming ions is to be calculated. The ion most likely formed in each case is to be stated.

Concept introduction: Any atom or molecule gain or lose electrons to acquire stable state. An ion is a charged atom formed by the loss or gain of electron.

To determine: The Phosphorus (P) atom loses or gain electrons; the ion formed by Phosphorus (P) atom.

Answer to Problem 43E

The Phosphorus (P) atom gain electrons. The Phosphorus (P) atom forms P3  ion.

Explanation of Solution

  • To determine: The Phosphorus (P) atom loses or gain electrons.

Non-metals always gain electrons to form negative ion. They gain electron to acquire more stable state.

The electronic configuration of phosphorus is:

1s22s22p63s23p3

Phosphorus is a non-metal hence, it gain electrons.

  • To determine: The ion formed by Phosphorus (P) atom.

Explanation:

Phosphorus atom contains three electrons in last p-sub shell. Hence it gains three electrons to completely fill the p-orbital to form P3 ion. The electronic configuration of P3 is:

1s22s22p63s23p6

Conclusion

Generally metals lose electrons to acquire stable state whereas non- metals gain electrons.

(d)

Expert Solution
Check Mark
Interpretation Introduction

Interpretation: The ability to lose or gain electrons of the given atom when forming ions is to be calculated. The ion most likely formed in each case is to be stated.

Concept introduction: Any atom or molecule gain or lose electrons to acquire stable state. An ion is a charged atom formed by the loss or gain of electron.

To determine: The Tellurium (Te) atom loses or gain electrons; the ion formed by Tellurium (Te) atom.

Answer to Problem 43E

The Tellurium (Te) atom gain electrons. The Tellurium (Te) atom forms Te2 ion.

Explanation of Solution

  • To determine: The Tellurium (Te) atom loses or gain electrons.

Non-metals always gain electrons to form negative ion. They gain electron to acquire more stable state.

The electronic configuration of Tellurium is:

1s22s22p63s23p63d104s24p64d105s25p4

Tellurium is a non-metal hence, it gains electrons.

  • To determine: The ion formed by Tellurium (Te) atom.

Tellurium atom contains four electrons in last p-sub shell. Hence it gains two electrons to completely fill the p-orbital to form Te2 ion. The electronic configuration of Te2 is:

1s22s22p63s23p63d104s24p64d105s25p6

(e)

Expert Solution
Check Mark
Interpretation Introduction

Interpretation: The ability to lose or gain electrons of the given atom when forming ions is to be calculated. The ion most likely formed in each case is to be stated.

Concept introduction: Any atom or molecule gain or lose electrons to acquire stable state. An ion is a charged atom formed by the loss or gain of electron.

To determine: The bromine (Br) atom loses or gain electrons; the ion formed by bromine (Br) atom.

Answer to Problem 43E

The bromine (Br) atom gain electrons. The bromine (Br) atom forms Br ion.

Explanation of Solution

  • To determine: The Bromine (Br) atom loses or gain electrons.

Non-metals always gain electrons to form negative ion. They gain electron to acquire more stable state.

The electronic configuration of bromine is:

1s22s22p63s23p63d104s24p5

Bromine is a non-metal hence, it gain electrons.

  • To determine: The ion formed by bromine atom

Bromine atom contains five electrons in last p-sub shell. Hence it gains one electron to completely fill the p-orbital to form Br-. The electronic configuration of Br is:

1s22s22p63s23p63d104s24p6

(f)

Expert Solution
Check Mark
Interpretation Introduction

Interpretation: The ability to lose or gain electrons of the given atom when forming ions is to be calculated. The ion most likely formed in each case is to be stated.

Concept introduction: Any atom or molecule gain or lose electrons to acquire stable state. An ion is a charged atom formed by the loss or gain of electron.

To determine: The rubidium (Rb) atom loses or gain electrons; the ion formed by rubidium (Rb) atom.

Answer to Problem 43E

The rubidium (Rb) atom loses an electron. The rubidium (Rb) atom forms Rb+ ion.

Explanation of Solution

  • To determine: The rubidium atom loses or gain electrons.

Metals always loose electrons to form positive ion. They lose electron to acquire more stable state.

The electronic configuration of rubidium is:

1s22s22p63s23p63d104s24p65s1

Rubidium is a metal hence, it lose electrons.

  • To determine: The ion formed by Rubidium (Rb) atom

Rubidium atom contains one electron in last s-sub shell. Hence it can loose one electron to form Rb+. The electronic configuration of Rb+ is:

1s22s22p63s23p63d104s24p6

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Chapter 3 Solutions

Chemistry: An Atoms First Approach

Ch. 3 - How would you name HBrO4, KIO3, NaBrO2, and HIO?...Ch. 3 - Explain the electronegativity trends across a row...Ch. 3 - The ionic compound AB is formed. The charges on...Ch. 3 - Prob. 3ALQCh. 3 - The bond energy for a CH bond is about 413 kJ/mol...Ch. 3 - Prob. 5ALQCh. 3 - Which has the greater bond lengths: NO2 or NO3?...Ch. 3 - Prob. 7ALQCh. 3 - The second electron affinity values for both...Ch. 3 - What is meant by a chemical bond? Why do atoms...Ch. 3 - Why are some bonds ionic and some covalent?Ch. 3 - Prob. 11ALQCh. 3 - Prob. 12ALQCh. 3 - Prob. 13ALQCh. 3 - Why do we call Ba(NO3)2 barium nitrate, but we...Ch. 3 - Prob. 15ALQCh. 3 - Prob. 16ALQCh. 3 - Compare and contrast the bonding found in the...Ch. 3 - Describe the type of bonding that exists in the...Ch. 3 - Some of the important properties of ionic...Ch. 3 - Prob. 21QCh. 3 - Distinguish between the following terms. a....Ch. 3 - What is the electronegativity trend? Where does...Ch. 3 - Prob. 24QCh. 3 - In general the higher the charge on the ions in an...Ch. 3 - Combustion reactions of fossil fuels provide most...Ch. 3 - Which of the following statements is/are true?...Ch. 3 - Three resonance structures can be drawn for CO2...Ch. 3 - Prob. 29QCh. 3 - Prob. 30QCh. 3 - Without using Fig. 3-4, predict the order of...Ch. 3 - Without using Fig. 3-4, predict the order of...Ch. 3 - Without using Fig. 3-4, predict which bond in each...Ch. 3 - Without using Fig. 3-4, predict which bond in each...Ch. 3 - Prob. 35ECh. 3 - Prob. 36ECh. 3 - Which of the following incorrectly shows the bond...Ch. 3 - Indicate the bond polarity (show the partial...Ch. 3 - Predict the type of bond (ionic, covalent, or...Ch. 3 - List all the possible bonds that can occur between...Ch. 3 - Hydrogen has an electronegativity value between...Ch. 3 - Rank the following bonds in order of increasing...Ch. 3 - Would you expect each of the following atoms to...Ch. 3 - Prob. 44ECh. 3 - Prob. 45ECh. 3 - Prob. 46ECh. 3 - Predict the empirical formulas of the ionic...Ch. 3 - Prob. 48ECh. 3 - Write electron configurations for a. the cations...Ch. 3 - Write electron configurations for a. the cations...Ch. 3 - Which of the following ions have noble gas...Ch. 3 - What noble gas has the same electron configuration...Ch. 3 - Give the formula of a negative ion that would have...Ch. 3 - Prob. 54ECh. 3 - Give three ions that are isoelectronic with neon....Ch. 3 - Consider the ions Sc3+, Cl, K+, Ca2+, and S2....Ch. 3 - Prob. 57ECh. 3 - Prob. 58ECh. 3 - Which compound in each of the following pairs of...Ch. 3 - Which compound in each of the following pairs of...Ch. 3 - Use the following data for potassium chloride to...Ch. 3 - Prob. 62ECh. 3 - Consider the following energy changes: E(kJ/mol)...Ch. 3 - Prob. 64ECh. 3 - Consider the following:...Ch. 3 - Prob. 66ECh. 3 - Rationalize the following lattice energy values:...Ch. 3 - The lattice energies of FeCl3, FeCl2, and Fe2O3...Ch. 3 - Prob. 69ECh. 3 - Prob. 70ECh. 3 - Prob. 71ECh. 3 - Acetic acid is responsible for the sour taste of...Ch. 3 - Prob. 73ECh. 3 - The major industrial source of hydrogen gas is by...Ch. 3 - Prob. 75ECh. 3 - Prob. 76ECh. 3 - Prob. 77ECh. 3 - Prob. 78ECh. 3 - Write Lewis structures that obey the octet rule...Ch. 3 - Write Lewis structures that obey the octet rule...Ch. 3 - Write Lewis structures that obey the octet rule...Ch. 3 - Write Lewis structures that obey the octet rule...Ch. 3 - Prob. 83ECh. 3 - Lewis structures can be used to understand why...Ch. 3 - The most common exceptions to the octet rule are...Ch. 3 - Prob. 86ECh. 3 - Write Lewis structures for the following. Show all...Ch. 3 - Prob. 88ECh. 3 - Benzene (C6H6) consists of a six-membered ring of...Ch. 3 - Borazine (B3N3H6) has often been called inorganic...Ch. 3 - An important observation supporting the concept of...Ch. 3 - Consider the following bond lengths: CO143pmC9O123...Ch. 3 - A toxic cloud covered Bhopal, India, in December...Ch. 3 - Peroxyacetyl nitrate, or PAN, is present in...Ch. 3 - Order the following species with respect to...Ch. 3 - Place the species below in order of the shortest...Ch. 3 - Prob. 97ECh. 3 - Prob. 98ECh. 3 - Write Lewis structures that obey the octet rule...Ch. 3 - Write Lewis structures for the species in Exercise...Ch. 3 - A common trait of simple organic compounds is to...Ch. 3 - Prob. 102ECh. 3 - Oxidation of the cyanide ion produces the stable...Ch. 3 - Prob. 104ECh. 3 - Name the compounds in parts ad and write the...Ch. 3 - Prob. 106ECh. 3 - Prob. 107ECh. 3 - Prob. 108ECh. 3 - Prob. 109ECh. 3 - Prob. 110ECh. 3 - Prob. 111ECh. 3 - Prob. 112ECh. 3 - Prob. 113ECh. 3 - Prob. 114ECh. 3 - Prob. 115ECh. 3 - Prob. 116ECh. 3 - Prob. 117ECh. 3 - Write the formula for each of the following...Ch. 3 - Prob. 119ECh. 3 - Write the formula for each of the following...Ch. 3 - Prob. 121ECh. 3 - Prob. 122ECh. 3 - Arrange the following in order of increasing...Ch. 3 - For each of the following, write an equation that...Ch. 3 - Prob. 125AECh. 3 - Write Lewis structures for CO32, HCO3, and H2CO3....Ch. 3 - Which member of the following pairs would you...Ch. 3 - What do each of the following sets of...Ch. 3 - Although both Br3 and I3 ions are known, the F3...Ch. 3 - Prob. 130AECh. 3 - Prob. 131AECh. 3 - Identify each of the following elements: a. a...Ch. 3 - Prob. 133AECh. 3 - Prob. 134AECh. 3 - When molten sulfur reacts with chlorine gas, a...Ch. 3 - The study of carbon-containing compounds and their...Ch. 3 - Prob. 137CWPCh. 3 - Prob. 138CWPCh. 3 - Complete the following table to predict whether...Ch. 3 - Prob. 140CWPCh. 3 - Prob. 141CWPCh. 3 - List the bonds PCl, PF, OF, and SiF from least...Ch. 3 - Arrange the atoms and/or ions in the following...Ch. 3 - Prob. 144CWPCh. 3 - Prob. 145CWPCh. 3 - Which of the following compounds or ions exhibit...Ch. 3 - Prob. 147CPCh. 3 - Prob. 148CPCh. 3 - Given the following information: Energy of...Ch. 3 - Think of forming an ionic compound as three steps...Ch. 3 - Use data in this chapter (and Chapter 2) to...Ch. 3 - Three processes that have been used for the...Ch. 3 - Prob. 153CPCh. 3 - Prob. 154CPCh. 3 - Draw a Lewis structure for the N,...Ch. 3 - Cholesterol (C27H46O) has the following structure:...Ch. 3 - Consider the following computer-generated model of...Ch. 3 - For each of the following ions, indicate the total...Ch. 3 - Prob. 159IPCh. 3 - A polyatomic ion is composed of C, N, and an...
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