The structure of ( R )-2-chloropentane needs to be drawn. Concept Introduction : When four different groups are attached in a single atom then it is called chiral atom. The priority is given to the groups depending on their atomic mass and configuration is decided in such a way that if the increasing order of priority order is clockwise than the configuration is R and if it is anticlockwise then the configuration is S.

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Answer 1

Question

Chapter 5, Problem 45P

(a)

Interpretation Introduction

Interpretation : The structure of ( R )-2-chloropentane needs to be drawn.

Concept Introduction : When four different groups are attached in a single atom then it is called chiral atom. The priority is given to the groups depending on their atomic mass and configuration is decided in such a way that if the increasing order of priority order is clockwise than the configuration is R and if it is anticlockwise then the configuration is S.

(b)

Interpretation Introduction

Interpretation : The structure of ( S )-2-methyl-3-bromohexane needs to be drawn.

Concept Introduction : When four different groups are attached in a single atom then it is called chiral atom. The priority is given to the groups depending on their atomic mass and configuration is decided in such a way that if the increasing order of priority order is clockwise than the configuration is R and if it is anticlockwise then the configuration is S.

(c)

Interpretation Introduction

Interpretation : The structure of (S)-1,3-dichlorobutane should be drawn.

Concept Introduction : When four different groups are attached in a single atom then it is called chiral atom. The priority is given to the groups depending on their atomic mass and configuration is decided in such a way that if the increasing order of priority order is clockwise than the configuration is R and if it is anticlockwise then the configuration is S.

(d)

Interpretation Introduction

Interpretation:The structure of(R)-2-chloro-1,1,1-trifluoro-3-methylbutane should be drawn.

Concept Introduction : When four different groups are attached in a single atom then it is called chiral atom. The priority is given to the groups depending on their atomic mass and configuration is decided in such a way that if the increasing order of priority order is clockwise than the configuration is R and if it is anticlockwise then the configuration is S.

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A difficult problem in the synthesis of PGF2α is the introduction of the OH group at C15 in the desired conguration.a. Label this stereogenic center as R or S.b. A well known synthesis of PGF2α involves reaction of A with Zn(BH4)2, a metal hydride reagent similar in reactivity to NaBH4, to form two isomeric products, B and C. Draw their structures and indicate their stereochemical relationship.c. Suggest a reagent to convert A to the single stereoisomer X.

A difficult problem in the synthesis of PGF2α is the introduction of the OH group at C15 in the desired configuration. a. Label this stereogenic center as R or S. b. A well-known synthesis of PGF2α involves reaction of A with Zn(BH4)2, a metal hydride reagent similar in reactivity to NaBH4, to form two isomeric products, B and C. Draw their structures and indicate their stereochemical relationship. d. Suggest a reagent to convert A to the single stereoisomer X.

For the molecule given, prioritize each substituent on the stereogenic carbon, and assign absolute stereochemistry.

Answer 2

Question

Chapter 5, Problem 45P

(a)

Interpretation Introduction

Interpretation : The structure of ( R )-2-chloropentane needs to be drawn.

Concept Introduction : When four different groups are attached in a single atom then it is called chiral atom. The priority is given to the groups depending on their atomic mass and configuration is decided in such a way that if the increasing order of priority order is clockwise than the configuration is R and if it is anticlockwise then the configuration is S.

(b)

Interpretation Introduction

Interpretation : The structure of ( S )-2-methyl-3-bromohexane needs to be drawn.

Concept Introduction : When four different groups are attached in a single atom then it is called chiral atom. The priority is given to the groups depending on their atomic mass and configuration is decided in such a way that if the increasing order of priority order is clockwise than the configuration is R and if it is anticlockwise then the configuration is S.

(c)

Interpretation Introduction

Interpretation : The structure of (S)-1,3-dichlorobutane should be drawn.

Concept Introduction : When four different groups are attached in a single atom then it is called chiral atom. The priority is given to the groups depending on their atomic mass and configuration is decided in such a way that if the increasing order of priority order is clockwise than the configuration is R and if it is anticlockwise then the configuration is S.

(d)

Interpretation Introduction

Interpretation:The structure of(R)-2-chloro-1,1,1-trifluoro-3-methylbutane should be drawn.

Concept Introduction : When four different groups are attached in a single atom then it is called chiral atom. The priority is given to the groups depending on their atomic mass and configuration is decided in such a way that if the increasing order of priority order is clockwise than the configuration is R and if it is anticlockwise then the configuration is S.

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Answer 3

Question

Chapter 5, Problem 45P

(a)

Interpretation Introduction

Interpretation : The structure of ( R )-2-chloropentane needs to be drawn.

Concept Introduction : When four different groups are attached in a single atom then it is called chiral atom. The priority is given to the groups depending on their atomic mass and configuration is decided in such a way that if the increasing order of priority order is clockwise than the configuration is R and if it is anticlockwise then the configuration is S.

(b)

Interpretation Introduction

Interpretation : The structure of ( S )-2-methyl-3-bromohexane needs to be drawn.

Concept Introduction : When four different groups are attached in a single atom then it is called chiral atom. The priority is given to the groups depending on their atomic mass and configuration is decided in such a way that if the increasing order of priority order is clockwise than the configuration is R and if it is anticlockwise then the configuration is S.

(c)

Interpretation Introduction

Interpretation : The structure of (S)-1,3-dichlorobutane should be drawn.

Concept Introduction : When four different groups are attached in a single atom then it is called chiral atom. The priority is given to the groups depending on their atomic mass and configuration is decided in such a way that if the increasing order of priority order is clockwise than the configuration is R and if it is anticlockwise then the configuration is S.

(d)

Interpretation Introduction

Interpretation:The structure of(R)-2-chloro-1,1,1-trifluoro-3-methylbutane should be drawn.

Concept Introduction : When four different groups are attached in a single atom then it is called chiral atom. The priority is given to the groups depending on their atomic mass and configuration is decided in such a way that if the increasing order of priority order is clockwise than the configuration is R and if it is anticlockwise then the configuration is S.

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Answer 4

Question

Chapter 5, Problem 45P

(a)

Interpretation Introduction

Interpretation : The structure of ( R )-2-chloropentane needs to be drawn.

Concept Introduction : When four different groups are attached in a single atom then it is called chiral atom. The priority is given to the groups depending on their atomic mass and configuration is decided in such a way that if the increasing order of priority order is clockwise than the configuration is R and if it is anticlockwise then the configuration is S.

(b)

Interpretation Introduction

Interpretation : The structure of ( S )-2-methyl-3-bromohexane needs to be drawn.

Concept Introduction : When four different groups are attached in a single atom then it is called chiral atom. The priority is given to the groups depending on their atomic mass and configuration is decided in such a way that if the increasing order of priority order is clockwise than the configuration is R and if it is anticlockwise then the configuration is S.

(c)

Interpretation Introduction

Interpretation : The structure of (S)-1,3-dichlorobutane should be drawn.

Concept Introduction : When four different groups are attached in a single atom then it is called chiral atom. The priority is given to the groups depending on their atomic mass and configuration is decided in such a way that if the increasing order of priority order is clockwise than the configuration is R and if it is anticlockwise then the configuration is S.

(d)

Interpretation Introduction

Interpretation:The structure of(R)-2-chloro-1,1,1-trifluoro-3-methylbutane should be drawn.

Concept Introduction : When four different groups are attached in a single atom then it is called chiral atom. The priority is given to the groups depending on their atomic mass and configuration is decided in such a way that if the increasing order of priority order is clockwise than the configuration is R and if it is anticlockwise then the configuration is S.

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Answer 5

Chapter 5, Problem 45P

(a)

Interpretation Introduction

Interpretation : The structure of ( R )-2-chloropentane needs to be drawn.

Concept Introduction : When four different groups are attached in a single atom then it is called chiral atom. The priority is given to the groups depending on their atomic mass and configuration is decided in such a way that if the increasing order of priority order is clockwise than the configuration is R and if it is anticlockwise then the configuration is S.

(b)

Interpretation Introduction

Interpretation : The structure of ( S )-2-methyl-3-bromohexane needs to be drawn.

Concept Introduction : When four different groups are attached in a single atom then it is called chiral atom. The priority is given to the groups depending on their atomic mass and configuration is decided in such a way that if the increasing order of priority order is clockwise than the configuration is R and if it is anticlockwise then the configuration is S.

(c)

Interpretation Introduction

Interpretation : The structure of (S)-1,3-dichlorobutane should be drawn.

Concept Introduction : When four different groups are attached in a single atom then it is called chiral atom. The priority is given to the groups depending on their atomic mass and configuration is decided in such a way that if the increasing order of priority order is clockwise than the configuration is R and if it is anticlockwise then the configuration is S.

(d)

Interpretation Introduction

Interpretation:The structure of(R)-2-chloro-1,1,1-trifluoro-3-methylbutane should be drawn.

Concept Introduction : When four different groups are attached in a single atom then it is called chiral atom. The priority is given to the groups depending on their atomic mass and configuration is decided in such a way that if the increasing order of priority order is clockwise than the configuration is R and if it is anticlockwise then the configuration is S.

Answer 6

Chapter 5, Problem 45P

(a)

Interpretation Introduction

Interpretation : The structure of ( R )-2-chloropentane needs to be drawn.

Concept Introduction : When four different groups are attached in a single atom then it is called chiral atom. The priority is given to the groups depending on their atomic mass and configuration is decided in such a way that if the increasing order of priority order is clockwise than the configuration is R and if it is anticlockwise then the configuration is S.

Answer 7

Chapter 5, Problem 45P

(a)

Interpretation Introduction

Interpretation : The structure of ( R )-2-chloropentane needs to be drawn.

Concept Introduction : When four different groups are attached in a single atom then it is called chiral atom. The priority is given to the groups depending on their atomic mass and configuration is decided in such a way that if the increasing order of priority order is clockwise than the configuration is R and if it is anticlockwise then the configuration is S.

Answer 8

(b)

Interpretation Introduction

Interpretation : The structure of ( S )-2-methyl-3-bromohexane needs to be drawn.

Concept Introduction : When four different groups are attached in a single atom then it is called chiral atom. The priority is given to the groups depending on their atomic mass and configuration is decided in such a way that if the increasing order of priority order is clockwise than the configuration is R and if it is anticlockwise then the configuration is S.

Answer 9

(b)

Interpretation Introduction

Interpretation : The structure of ( S )-2-methyl-3-bromohexane needs to be drawn.

Concept Introduction : When four different groups are attached in a single atom then it is called chiral atom. The priority is given to the groups depending on their atomic mass and configuration is decided in such a way that if the increasing order of priority order is clockwise than the configuration is R and if it is anticlockwise then the configuration is S.

Answer 10

(c)

Interpretation Introduction

Interpretation : The structure of (S)-1,3-dichlorobutane should be drawn.

Concept Introduction : When four different groups are attached in a single atom then it is called chiral atom. The priority is given to the groups depending on their atomic mass and configuration is decided in such a way that if the increasing order of priority order is clockwise than the configuration is R and if it is anticlockwise then the configuration is S.

Answer 11

(c)

Interpretation Introduction

Interpretation : The structure of (S)-1,3-dichlorobutane should be drawn.

Concept Introduction : When four different groups are attached in a single atom then it is called chiral atom. The priority is given to the groups depending on their atomic mass and configuration is decided in such a way that if the increasing order of priority order is clockwise than the configuration is R and if it is anticlockwise then the configuration is S.

Answer 12

(d)

Interpretation Introduction

Interpretation:The structure of(R)-2-chloro-1,1,1-trifluoro-3-methylbutane should be drawn.

Concept Introduction : When four different groups are attached in a single atom then it is called chiral atom. The priority is given to the groups depending on their atomic mass and configuration is decided in such a way that if the increasing order of priority order is clockwise than the configuration is R and if it is anticlockwise then the configuration is S.

Answer 13

(d)

Interpretation Introduction

Interpretation:The structure of(R)-2-chloro-1,1,1-trifluoro-3-methylbutane should be drawn.

Concept Introduction : When four different groups are attached in a single atom then it is called chiral atom. The priority is given to the groups depending on their atomic mass and configuration is decided in such a way that if the increasing order of priority order is clockwise than the configuration is R and if it is anticlockwise then the configuration is S.

Answer 14

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Answer 15

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Answer 16

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Answer 17

Ch. 5.1 - Prob. 5.3E Ch. 5.1 - Prob. 5.4E Ch. 5.1 - Prob. 5.5E Ch. 5.2 - Prob. 5.6E Ch. 5.2 - Prob. 5.8TIY Ch. 5.3 - Prob. 5.9E Ch. 5.3 - Prob. 5.11TIY Ch. 5.3 - Prob. 5.12E Ch. 5.4 - Prob. 5.13E Ch. 5.4 - Prob. 5.14E

Solution Summary: The author explains how the structure of ( R )-2-chloropentane needs to be drawn.

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