Introductory Chemistry: A Foundation
9th Edition
ISBN: 9781337399425
Author: Steven S. Zumdahl, Donald J. DeCoste
Publisher: Cengage Learning
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Chapter 10, Problem 63QAP
Interpretation Introduction
Interpretation:
The term entropy should be defined and why it increases for spontaneous process should be explained.
Concept Introduction:
Entropy is a thermodynamic property that measures the disorder or randomness in a system or in a surrounding. In a spontaneous process there is always an increase in the entropy of the universe.
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Introductory Chemistry: A Foundation
Ch. 10.1 - at if energy were not conserved? How would this...Ch. 10.4 - u are calculating in a chemistry problem. What if...Ch. 10.5 - ercise 10.1 How many calories of energy correspond...Ch. 10.5 - ercise 10.2 Calculate the joules of energy...Ch. 10.5 - ercise 10.3 A 5.63-g sample of solid gold is...Ch. 10.5 - ercise 10.4 A 2.8-g sample of pure metal requires...Ch. 10.6 - Prob. 10.5SCCh. 10.7 - at if Hess’s law were not true? What are some...Ch. 10.7 - Prob. 10.6SCCh. 10.9 - Prob. 1CT
Ch. 10.10 - at if the first law of thermodynamics was true,...Ch. 10 - Prob. 1ALQCh. 10 - friend of yours reads that the process of water...Ch. 10 - ou place hot metal into a beaker of cold water. ol...Ch. 10 - Prob. 4ALQCh. 10 - Prob. 5ALQCh. 10 - xplain why aluminum cans make good storage...Ch. 10 - n Section 10.7, two characteristics of enthalpy...Ch. 10 - Prob. 8ALQCh. 10 - hat is meant by the term driving forces? Why are...Ch. 10 - Prob. 10ALQCh. 10 - Explain in your own words what is meant by the...Ch. 10 - Prob. 12ALQCh. 10 - What if energy was not conserved? How would this...Ch. 10 - The internal energy of a system is said to be the...Ch. 10 - Hydrogen gas and oxygen gas react violently to...Ch. 10 - Consider four 100.0-g samples of water, each in a...Ch. 10 - For each of the following situations ac. use the...Ch. 10 - Prob. 18ALQCh. 10 - Does the entropy of the system increase or...Ch. 10 - Prob. 20ALQCh. 10 - Prob. 1QAPCh. 10 - Prob. 2QAPCh. 10 - Prob. 3QAPCh. 10 - Prob. 4QAPCh. 10 - Prob. 5QAPCh. 10 - n Fig. 10.1, what kind of energy does ball A...Ch. 10 - Prob. 7QAPCh. 10 - f you spilled a cup of freshly brewed hot tea on...Ch. 10 - Prob. 9QAPCh. 10 - Prob. 10QAPCh. 10 - In studying heat flows for chemical processes,...Ch. 10 - When a chemical system evolves energy, where does...Ch. 10 - The combustion of methane, is an exothermic...Ch. 10 - Are the following processes exothermic or...Ch. 10 - What do we mean by thermodynamics? What is the...Ch. 10 - Prob. 16QAPCh. 10 - Prob. 17QAPCh. 10 - If q for a process is a positive number, then the...Ch. 10 - For an endothermic process, q will have a...Ch. 10 - A system absorbs 215 kJ of heat, and 116 kJ of...Ch. 10 - Prob. 21QAPCh. 10 - Prob. 22QAPCh. 10 - If 8.40 kJ of heat is needed to raise the...Ch. 10 - If it takes 654 J of energy to warm a 5.51-g...Ch. 10 - Prob. 25QAPCh. 10 - Prob. 26QAPCh. 10 - Covert the following numbers of kilojoules into...Ch. 10 - Prob. 28QAPCh. 10 - Prob. 29QAPCh. 10 - Prob. 30QAPCh. 10 - .5 kJ of heat is applied to a 1012-g block of...Ch. 10 - What quantity of heat energy must have en applied...Ch. 10 - If 125 J of heat energy is applied to a block of...Ch. 10 - If 100. J of heat energy is applied to a 25-g...Ch. 10 - What quantity of heat is required to raise the...Ch. 10 - Prob. 36QAPCh. 10 - The “Chemistry in Focus” segment Nature Has Hot...Ch. 10 - In the “Chemistry in Focus” segment Firewalking:...Ch. 10 - Prob. 39QAPCh. 10 - A _________ is a device used to determine the heat...Ch. 10 - The enthalpy change for the reaction of hydrogen...Ch. 10 - For the reaction kJ per mole of formed. Calculate...Ch. 10 - Prob. 43QAPCh. 10 - When ethanol (grain alcohol, is burned in oxygen,...Ch. 10 - Prob. 45QAPCh. 10 - Prob. 46QAPCh. 10 - Prob. 47QAPCh. 10 - Prob. 48QAPCh. 10 - Prob. 49QAPCh. 10 - Prob. 50QAPCh. 10 - Prob. 51QAPCh. 10 - Prob. 52QAPCh. 10 - Prob. 53QAPCh. 10 - Prob. 54QAPCh. 10 - Prob. 55QAPCh. 10 - Prob. 56QAPCh. 10 - Prob. 57QAPCh. 10 - Prob. 58QAPCh. 10 - Prob. 59QAPCh. 10 - Prob. 60QAPCh. 10 - If a reaction occurs readily but has an...Ch. 10 - Prob. 62QAPCh. 10 - Prob. 63QAPCh. 10 - Prob. 64QAPCh. 10 - Which of the following is an endothermic process?...Ch. 10 - Prob. 66APCh. 10 - Prob. 67APCh. 10 - Calculate the amount of energy required (in...Ch. 10 - If takes 1.25 kJ of energy to heat a certain...Ch. 10 - What quantity of heat energy would have to be...Ch. 10 - The specific heat capacity of gold is 0.13 J/g °C....Ch. 10 - Calculate the amount of energy required (in...Ch. 10 - If 10. J of heat is applied to 5.0-g samples of...Ch. 10 - A 50.1)-g sample of water at 100. °C is poured...Ch. 10 - A 25.0-g sample of pure iron at 85 °C is dropped...Ch. 10 - If 7.24 kJ of heat is applied to a 952-g block of...Ch. 10 - For each of the substances listed in Table 10.1,...Ch. 10 - A system releases 213 kJ of heat and has a...Ch. 10 - Prob. 79APCh. 10 - Calculate the enthalpy change when 5.00 g of...Ch. 10 - Prob. 81APCh. 10 - Prob. 82APCh. 10 - It has been determined that the body can generate...Ch. 10 - Prob. 84APCh. 10 - Prob. 85CPCh. 10 - The specific heat capacity of graphite is 0.71 J/g...Ch. 10 - A swimming pool, 10.0 in by 4.0 m, is filled with...Ch. 10 - Prob. 88CPCh. 10 - Prob. 89CP
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- Define the term entropy, and give an example of a sample of matter that has zero entropy. What are the units of entropy? How do they differ from the units of enthalpy?arrow_forwardWhat is entropy? Why is entropy important?arrow_forwardExplain in your own words what is meant by the term entropy. Explain how both matter spread and energy spread are related to the concept of entropy.arrow_forward
- For each process, tell whether the entropy change of the system is positive or negative. Water vapor (the system) deposits as ice crystals on a cold windowpane. A can of carbonated beverage loses its fizz. (Consider the beverage but not the can as the system. What happens to the entropy of the dissolved gas?) A glassblower heats glass (the system) to its softening temperature.arrow_forward9.17 If a machine does 4.8103kJ of work after an input of 7.31104kJ of heat, what is the change in internal energy for the machine?arrow_forwardA 5.33-g piece of Cu metal is heated to 99.7C in boiling water, then dropped into a calorimeter containing 99.53g of H2O at 22.6C. The calorimeter is sealed to the outside environment, and temperature equalizes. Cp[Cu(s)]=0.385J/gK, Cp[H2O]=4.18J/gK. a Discuss the process that occurs inside the calorimeter in terms of the zeroth and first laws of thermodynamics. b What is the final temperature inside the system? c What is the entropy change of the Cu(s)? dWhat is the entropy change of the H2O(l)? e What is the total entropy change in the system? f Discuss the process that occurs inside the calorimeter in terms of the second law thermodynamics. Do you expect it to be spontaneous?arrow_forward
- One statement of the second law of thermodynamics is that heat cannot be turned completely into work. Another is that the entropy of the universe always increases. How are these two statements related?arrow_forwardFor each situation described in Question 13, predict whether the entropy of the system increases or decreases.arrow_forwardWhat happens to the entropy of the universe during a spontaneous process?arrow_forward
- Explain how the equation dU+pdVTdS0 is consistent with the idea that spontaneous changes occur with a decrease in energy and an increase in entropy.arrow_forward9.23 Which system does not work: (a) E=436J , q=400J ; or E=317J , q=347J ?arrow_forwardThe statement Energycan beneithercreatednor destroyedis sometimes used as an equivalent statement of the first law of thermodynamics. There areinaccuracies to the statement, however. Restate it tomake it less inaccurate.arrow_forward
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