(a) Interpretation: The compounds p -nitroaniline, aniline, and cyclohexylamine are to be arranged in order of increasing C − N bond length. Concept introduction: Amines are the organic compounds that are formed by replacement of hydrogen from ammonia. Amines are basic in nature because the nitrogen can donate its lone pairs and also the ability of the nitrogen to accept the proton in water.

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Answer 1

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Chapter 23, Problem 23.3P

Interpretation Introduction

(a)

Interpretation:

The compounds p-nitroaniline, aniline, and cyclohexylamine are to be arranged in order of increasing C−N bond length.

Concept introduction:

Amines are the organic compounds that are formed by replacement of hydrogen from ammonia. Amines are basic in nature because the nitrogen can donate its lone pairs and also the ability of the nitrogen to accept the proton in water.

Interpretation Introduction

(b)

Interpretation:

The compounds HN=CH2, H3C−NH2, and CH2=CH−NH2 are to be arranged in order of increasing C−N bond length.

Concept introduction:

Amines are the organic compounds that are formed by replacement of hydrogen from ammonia. Amines are basic in nature because the nitrogen can donate its lone pairs and also the ability of the nitrogen to accept the proton in water.

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Draw the structure for the following compounds:(i) Ethanoic acid(ii) Bromopentane(iii) Butane(iv) Hexanal

a) If the pH value of an aqueous solution of trimethylamine [(CH3)3N] is 10.75, what should be the molarity of this solution? (CH3)3N + H2O ↔ (CH3)3NH+ + OH-, Kb = 6,3 × 10-5 b) What will be the pH of the solution prepared by dissolving 8.35 g of aniline hydrochloride (C6H5NH3+Cl-) in 750 mL of 0.215 M aniline (C6H5NH2)? Is this solution an effective buffer? Explain (Kb = 7,4 × 10-10 for aniline, C: 12.0 g / mol, H: 1.0 g / mol, N: 14.0 g / mol, Cl: 35.4 g / mol) .

a) If the pH value of an aqueous solution of trimethylamine [(CH3) 3N] is 10.75, what should be the molarity of this solution? (CH3) 3N + H2O ↔ (CH3) 3NH + + OH-, Kb = 6.3 × 10-5 b) What will be the pH of the solution prepared by dissolving 8.35 g of aniline hydrochloride (C6H5NH3 + Cl-) in 750 mL of 0.215 M aniline (C6H5NH2)? Is this solution an effective buffer? Explain (Kb = 7.4 × 10-10 for aniline, C: 12.0 g / mol, H: 1.0 g / mol, N: 14.0 g / mol, Cl: 35.4 g / mol) .

Answer 2

Question

Chapter 23, Problem 23.3P

Interpretation Introduction

(a)

Interpretation:

The compounds p-nitroaniline, aniline, and cyclohexylamine are to be arranged in order of increasing C−N bond length.

Concept introduction:

Amines are the organic compounds that are formed by replacement of hydrogen from ammonia. Amines are basic in nature because the nitrogen can donate its lone pairs and also the ability of the nitrogen to accept the proton in water.

Interpretation Introduction

(b)

Interpretation:

The compounds HN=CH2, H3C−NH2, and CH2=CH−NH2 are to be arranged in order of increasing C−N bond length.

Concept introduction:

Amines are the organic compounds that are formed by replacement of hydrogen from ammonia. Amines are basic in nature because the nitrogen can donate its lone pairs and also the ability of the nitrogen to accept the proton in water.

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Answer 3

Question

Chapter 23, Problem 23.3P

Interpretation Introduction

(a)

Interpretation:

The compounds p-nitroaniline, aniline, and cyclohexylamine are to be arranged in order of increasing C−N bond length.

Concept introduction:

Amines are the organic compounds that are formed by replacement of hydrogen from ammonia. Amines are basic in nature because the nitrogen can donate its lone pairs and also the ability of the nitrogen to accept the proton in water.

Interpretation Introduction

(b)

Interpretation:

The compounds HN=CH2, H3C−NH2, and CH2=CH−NH2 are to be arranged in order of increasing C−N bond length.

Concept introduction:

Amines are the organic compounds that are formed by replacement of hydrogen from ammonia. Amines are basic in nature because the nitrogen can donate its lone pairs and also the ability of the nitrogen to accept the proton in water.

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Answer 4

Question

Chapter 23, Problem 23.3P

Interpretation Introduction

(a)

Interpretation:

The compounds p-nitroaniline, aniline, and cyclohexylamine are to be arranged in order of increasing C−N bond length.

Concept introduction:

Amines are the organic compounds that are formed by replacement of hydrogen from ammonia. Amines are basic in nature because the nitrogen can donate its lone pairs and also the ability of the nitrogen to accept the proton in water.

Interpretation Introduction

(b)

Interpretation:

The compounds HN=CH2, H3C−NH2, and CH2=CH−NH2 are to be arranged in order of increasing C−N bond length.

Concept introduction:

Amines are the organic compounds that are formed by replacement of hydrogen from ammonia. Amines are basic in nature because the nitrogen can donate its lone pairs and also the ability of the nitrogen to accept the proton in water.

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Answer 5

Chapter 23, Problem 23.3P

Interpretation Introduction

(a)

Interpretation:

The compounds p-nitroaniline, aniline, and cyclohexylamine are to be arranged in order of increasing C−N bond length.

Concept introduction:

Amines are the organic compounds that are formed by replacement of hydrogen from ammonia. Amines are basic in nature because the nitrogen can donate its lone pairs and also the ability of the nitrogen to accept the proton in water.

Interpretation Introduction

(b)

Interpretation:

The compounds HN=CH2, H3C−NH2, and CH2=CH−NH2 are to be arranged in order of increasing C−N bond length.

Concept introduction:

Amines are the organic compounds that are formed by replacement of hydrogen from ammonia. Amines are basic in nature because the nitrogen can donate its lone pairs and also the ability of the nitrogen to accept the proton in water.

Answer 6

Chapter 23, Problem 23.3P

Interpretation Introduction

(a)

Interpretation:

The compounds p-nitroaniline, aniline, and cyclohexylamine are to be arranged in order of increasing C−N bond length.

Concept introduction:

Amines are the organic compounds that are formed by replacement of hydrogen from ammonia. Amines are basic in nature because the nitrogen can donate its lone pairs and also the ability of the nitrogen to accept the proton in water.

Answer 7

Chapter 23, Problem 23.3P

Interpretation Introduction

(a)

Interpretation:

The compounds p-nitroaniline, aniline, and cyclohexylamine are to be arranged in order of increasing C−N bond length.

Concept introduction:

Amines are the organic compounds that are formed by replacement of hydrogen from ammonia. Amines are basic in nature because the nitrogen can donate its lone pairs and also the ability of the nitrogen to accept the proton in water.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The compounds HN=CH2, H3C−NH2, and CH2=CH−NH2 are to be arranged in order of increasing C−N bond length.

Concept introduction:

Amines are the organic compounds that are formed by replacement of hydrogen from ammonia. Amines are basic in nature because the nitrogen can donate its lone pairs and also the ability of the nitrogen to accept the proton in water.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The compounds HN=CH2, H3C−NH2, and CH2=CH−NH2 are to be arranged in order of increasing C−N bond length.

Concept introduction:

Amines are the organic compounds that are formed by replacement of hydrogen from ammonia. Amines are basic in nature because the nitrogen can donate its lone pairs and also the ability of the nitrogen to accept the proton in water.

Answer 10

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Answer 11

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Answer 12

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Answer 13

Ch. 23 - Prob. 23.1P Ch. 23 - Prob. 23.2P Ch. 23 - Prob. 23.3P Ch. 23 - Prob. 23.4P Ch. 23 - Prob. 23.5P Ch. 23 - Prob. 23.6P Ch. 23 - Prob. 23.7P Ch. 23 - Prob. 23.8P Ch. 23 - Prob. 23.9P Ch. 23 - Prob. 23.10P

Solution Summary: The author explains the structure of the compounds p -nitroaniline, aniline and cyclohexylamine.

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Chapter 23 Solutions