EBK ORGANIC CHEMISTRY
EBK ORGANIC CHEMISTRY
6th Edition
ISBN: 8220103151757
Author: LOUDON
Publisher: MAC HIGHER
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Chapter 23, Problem 23.63AP
Interpretation Introduction

Interpretation:

The structure of compound A is to be stated. The explaination corresponding to the reason for predicting the structure of A is to be stated.

Concept introduction:

The quaternary compound is formed by the process of reductive amination. There is conversion of amine into imine takes place in this process. The imine is reduced to new amine. The reduction reaction which consists of the atom that gains electrons between two atoms.

Exhaustive methylation is defined as the formation of quaternary ammonium iodide salt with the help of excess CH3I, then Ag2O and heat.

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Wolff–Kishner reduction (hydrazine, KOH, ethylene glycol, 130°C) of the compound shown gave compound A. Treatment of compound A with m-chloroperoxybenzoic acid (MCPBA) gave compound B, which on reduction with lithium aluminum hydride gave compound C. Oxidation of compound C with chromic acid gave compound D (C9H14O). Identify compounds A through D in this sequence.
(b) Compound AA has a molecular formula of CsH&O and gives a positive result using Tollen's reagent. The reaction of compound AA with hot acidified potassium permanganate, KMNO4 gives compound BB. The catalytic hydrogenation of compound AA with nickel, Ni produced compound Cc. The reaction of compound BB with ethanamine, CH:CH2NH2 produces compound DD. Sebatian AA mempunyai formula molekul C3He0 dan memberikan keputusan yang positif menggunakan reagen Tollen. Tindak balas sebatian AA dengan larutan panas kalium permanganat, KMNO4 berasid menghasilkan sebatian BB. Penghidrogenan bermangkin bagi sebatian AA dengan nikel, Ni menghasilkan sebatian CC. Tindak balas sebatian BB dengan etanamina, CH3;CH2NH2 menghasilkan sebatian DD. (1) Draw the structural formula of compounds AA, BB, CC and DD. Lukiskan formula struktur bagi sebatian AA, BB, CC dan DD. (i) Name the type of chemical reaction for the formation of compound CC. Namakan jenis tindak balas kimia bagi penghasilan sebatian Cc.
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Chapter 23 Solutions

EBK ORGANIC CHEMISTRY

Ch. 23 - Prob. 23.11PCh. 23 - Prob. 23.12PCh. 23 - Prob. 23.13PCh. 23 - Prob. 23.14PCh. 23 - Prob. 23.15PCh. 23 - Prob. 23.16PCh. 23 - Prob. 23.17PCh. 23 - Prob. 23.18PCh. 23 - Prob. 23.19PCh. 23 - Prob. 23.20PCh. 23 - Prob. 23.21PCh. 23 - Prob. 23.22PCh. 23 - Prob. 23.23PCh. 23 - Prob. 23.24PCh. 23 - Prob. 23.25PCh. 23 - Prob. 23.26PCh. 23 - Prob. 23.27PCh. 23 - Prob. 23.28PCh. 23 - Prob. 23.29PCh. 23 - Prob. 23.30PCh. 23 - Prob. 23.31PCh. 23 - Prob. 23.32PCh. 23 - Prob. 23.33PCh. 23 - Prob. 23.34PCh. 23 - Prob. 23.35PCh. 23 - Prob. 23.36PCh. 23 - Prob. 23.37PCh. 23 - Prob. 23.38PCh. 23 - Prob. 23.39PCh. 23 - Prob. 23.40PCh. 23 - Prob. 23.41PCh. 23 - Prob. 23.42PCh. 23 - Prob. 23.43PCh. 23 - Prob. 23.44APCh. 23 - Prob. 23.45APCh. 23 - Prob. 23.46APCh. 23 - Prob. 23.47APCh. 23 - Prob. 23.48APCh. 23 - Prob. 23.49APCh. 23 - Prob. 23.50APCh. 23 - Prob. 23.51APCh. 23 - Prob. 23.52APCh. 23 - Prob. 23.53APCh. 23 - Prob. 23.54APCh. 23 - Prob. 23.55APCh. 23 - Prob. 23.56APCh. 23 - Prob. 23.57APCh. 23 - Prob. 23.58APCh. 23 - Prob. 23.59APCh. 23 - Prob. 23.60APCh. 23 - Prob. 23.61APCh. 23 - Prob. 23.62APCh. 23 - Prob. 23.63APCh. 23 - Prob. 23.64APCh. 23 - Prob. 23.65APCh. 23 - Prob. 23.66APCh. 23 - Prob. 23.67APCh. 23 - Prob. 23.68APCh. 23 - Prob. 23.69APCh. 23 - Prob. 23.70APCh. 23 - Prob. 23.71APCh. 23 - Prob. 23.72APCh. 23 - Prob. 23.73APCh. 23 - Prob. 23.74APCh. 23 - Prob. 23.75APCh. 23 - Prob. 23.76APCh. 23 - Prob. 23.77APCh. 23 - Prob. 23.78APCh. 23 - Prob. 23.79APCh. 23 - Prob. 23.80APCh. 23 - Prob. 23.81AP
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