(a) Interpretation: The synthesis route for the preparation of 2- bromobenzoic acid from o- toluidine ( o- methylaniline) is to be drawn. Concept introduction: The formation of diazonium salt from aromatic amines takes place using sodium nitrite and hydrochloric acid at low temperatures. This process is known as diazotization. The diazonium salts can be converted to aryl halides using copper halides or aryl cyanides using copper cyanides

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Answer 1

Question

Chapter 23, Problem 23.29P

Interpretation Introduction

(a)

Interpretation:

The synthesis route for the preparation of 2- bromobenzoic acid from o-toluidine (o-methylaniline) is to be drawn.

Concept introduction:

The formation of diazonium salt from aromatic amines takes place using sodium nitrite and hydrochloric acid at low temperatures. This process is known as diazotization. The diazonium salts can be converted to aryl halides using copper halides or aryl cyanides using copper cyanides

Interpretation Introduction

(b)

Interpretation:

The synthesis route for the preparation of 2, 4, 6- tribromobenzoic acid from aniline is to be drawn.

Concept introduction:

The formation of diazonium salt from aromatic amines takes place using sodium nitrite and hydrochloric acid at low temperatures. This process is known as diazotization. The diazonium salts can be converted to aryl halides using copper halides or aryl cyanides using copper cyanides

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Write structural formulas for the cyclohexadienyl cations formed from aniline (C6H5NH2) during(a) Ortho bromination (four resonance structures)(b) Meta bromination (three resonance structures)(c) Para bromination (four resonance structures)

Answer 2

Question

Chapter 23, Problem 23.29P

Interpretation Introduction

(a)

Interpretation:

The synthesis route for the preparation of 2- bromobenzoic acid from o-toluidine (o-methylaniline) is to be drawn.

Concept introduction:

The formation of diazonium salt from aromatic amines takes place using sodium nitrite and hydrochloric acid at low temperatures. This process is known as diazotization. The diazonium salts can be converted to aryl halides using copper halides or aryl cyanides using copper cyanides

Interpretation Introduction

(b)

Interpretation:

The synthesis route for the preparation of 2, 4, 6- tribromobenzoic acid from aniline is to be drawn.

Concept introduction:

The formation of diazonium salt from aromatic amines takes place using sodium nitrite and hydrochloric acid at low temperatures. This process is known as diazotization. The diazonium salts can be converted to aryl halides using copper halides or aryl cyanides using copper cyanides

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Answer 3

Question

Chapter 23, Problem 23.29P

Interpretation Introduction

(a)

Interpretation:

The synthesis route for the preparation of 2- bromobenzoic acid from o-toluidine (o-methylaniline) is to be drawn.

Concept introduction:

The formation of diazonium salt from aromatic amines takes place using sodium nitrite and hydrochloric acid at low temperatures. This process is known as diazotization. The diazonium salts can be converted to aryl halides using copper halides or aryl cyanides using copper cyanides

Interpretation Introduction

(b)

Interpretation:

The synthesis route for the preparation of 2, 4, 6- tribromobenzoic acid from aniline is to be drawn.

Concept introduction:

The formation of diazonium salt from aromatic amines takes place using sodium nitrite and hydrochloric acid at low temperatures. This process is known as diazotization. The diazonium salts can be converted to aryl halides using copper halides or aryl cyanides using copper cyanides

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Answer 4

Question

Chapter 23, Problem 23.29P

Interpretation Introduction

(a)

Interpretation:

The synthesis route for the preparation of 2- bromobenzoic acid from o-toluidine (o-methylaniline) is to be drawn.

Concept introduction:

The formation of diazonium salt from aromatic amines takes place using sodium nitrite and hydrochloric acid at low temperatures. This process is known as diazotization. The diazonium salts can be converted to aryl halides using copper halides or aryl cyanides using copper cyanides

Interpretation Introduction

(b)

Interpretation:

The synthesis route for the preparation of 2, 4, 6- tribromobenzoic acid from aniline is to be drawn.

Concept introduction:

The formation of diazonium salt from aromatic amines takes place using sodium nitrite and hydrochloric acid at low temperatures. This process is known as diazotization. The diazonium salts can be converted to aryl halides using copper halides or aryl cyanides using copper cyanides

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Answer 5

Chapter 23, Problem 23.29P

Interpretation Introduction

(a)

Interpretation:

The synthesis route for the preparation of 2- bromobenzoic acid from o-toluidine (o-methylaniline) is to be drawn.

Concept introduction:

The formation of diazonium salt from aromatic amines takes place using sodium nitrite and hydrochloric acid at low temperatures. This process is known as diazotization. The diazonium salts can be converted to aryl halides using copper halides or aryl cyanides using copper cyanides

Interpretation Introduction

(b)

Interpretation:

The synthesis route for the preparation of 2, 4, 6- tribromobenzoic acid from aniline is to be drawn.

Concept introduction:

The formation of diazonium salt from aromatic amines takes place using sodium nitrite and hydrochloric acid at low temperatures. This process is known as diazotization. The diazonium salts can be converted to aryl halides using copper halides or aryl cyanides using copper cyanides

Answer 6

Chapter 23, Problem 23.29P

Interpretation Introduction

(a)

Interpretation:

The synthesis route for the preparation of 2- bromobenzoic acid from o-toluidine (o-methylaniline) is to be drawn.

Concept introduction:

The formation of diazonium salt from aromatic amines takes place using sodium nitrite and hydrochloric acid at low temperatures. This process is known as diazotization. The diazonium salts can be converted to aryl halides using copper halides or aryl cyanides using copper cyanides

Answer 7

Chapter 23, Problem 23.29P

Interpretation Introduction

(a)

Interpretation:

The synthesis route for the preparation of 2- bromobenzoic acid from o-toluidine (o-methylaniline) is to be drawn.

Concept introduction:

The formation of diazonium salt from aromatic amines takes place using sodium nitrite and hydrochloric acid at low temperatures. This process is known as diazotization. The diazonium salts can be converted to aryl halides using copper halides or aryl cyanides using copper cyanides

Answer 8

Interpretation Introduction

(b)

Interpretation:

The synthesis route for the preparation of 2, 4, 6- tribromobenzoic acid from aniline is to be drawn.

Concept introduction:

The formation of diazonium salt from aromatic amines takes place using sodium nitrite and hydrochloric acid at low temperatures. This process is known as diazotization. The diazonium salts can be converted to aryl halides using copper halides or aryl cyanides using copper cyanides

Answer 9

Interpretation Introduction

(b)

Interpretation:

The synthesis route for the preparation of 2, 4, 6- tribromobenzoic acid from aniline is to be drawn.

Concept introduction:

The formation of diazonium salt from aromatic amines takes place using sodium nitrite and hydrochloric acid at low temperatures. This process is known as diazotization. The diazonium salts can be converted to aryl halides using copper halides or aryl cyanides using copper cyanides

Answer 10

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Answer 11

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Answer 12

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Answer 13

Ch. 23 - Prob. 23.1P Ch. 23 - Prob. 23.2P Ch. 23 - Prob. 23.3P Ch. 23 - Prob. 23.4P Ch. 23 - Prob. 23.5P Ch. 23 - Prob. 23.6P Ch. 23 - Prob. 23.7P Ch. 23 - Prob. 23.8P Ch. 23 - Prob. 23.9P Ch. 23 - Prob. 23.10P

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Chapter 23 Solutions