(a) Interpretation: The mechanism of the reaction between 2-methylpropan-2-amine and epoxide is to be stated. Concept introduction: The cyclic ether containing a ring of atoms, carbon, oxygen and carbon is called an epoxide. The opening of the epoxide ring takes place in the presence of a nucleophile. The reaction of amine and epoxide leads to the opening of the epoxide ring.

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Answer 1

Question

Chapter 23, Problem 23.13P

Interpretation Introduction

(a)

Interpretation:

The mechanism of the reaction between 2-methylpropan-2-amine and epoxide is to be stated.

Concept introduction:

The cyclic ether containing a ring of atoms, carbon, oxygen and carbon is called an epoxide. The opening of the epoxide ring takes place in the presence of a nucleophile. The reaction of amine and epoxide leads to the opening of the epoxide ring.

Interpretation Introduction

(b)

Interpretation:

The mechanism of the reaction between ammonia and acrylonitrile is to be stated.

Concept introduction:

The cyclic ether containing a ring of atoms, carbon, oxygen and carbon is called an epoxide. The opening of the epoxide ring takes place in the presence of a nucleophile. The reaction of amine and epoxide leads to the opening of the epoxide ring.

Interpretation Introduction

(c)

Interpretation:

The reason as to why the reaction between ammonia and acrylonitrile stops after two additions, and a third doesn’t occur in high yield is to be stated. The changes that are required in the reaction condition in order to get the third addition are to be stated.

Concept introduction:

The cyclic ether containing a ring of atoms, carbon, oxygen and carbon is called an epoxide. The opening of the epoxide ring takes place in the presence of a nucleophile. The reaction of amine and epoxide leads to the opening of the epoxide ring.

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Answer 2

Question

Chapter 23, Problem 23.13P

Interpretation Introduction

(a)

Interpretation:

The mechanism of the reaction between 2-methylpropan-2-amine and epoxide is to be stated.

Concept introduction:

The cyclic ether containing a ring of atoms, carbon, oxygen and carbon is called an epoxide. The opening of the epoxide ring takes place in the presence of a nucleophile. The reaction of amine and epoxide leads to the opening of the epoxide ring.

Interpretation Introduction

(b)

Interpretation:

The mechanism of the reaction between ammonia and acrylonitrile is to be stated.

Concept introduction:

The cyclic ether containing a ring of atoms, carbon, oxygen and carbon is called an epoxide. The opening of the epoxide ring takes place in the presence of a nucleophile. The reaction of amine and epoxide leads to the opening of the epoxide ring.

Interpretation Introduction

(c)

Interpretation:

The reason as to why the reaction between ammonia and acrylonitrile stops after two additions, and a third doesn’t occur in high yield is to be stated. The changes that are required in the reaction condition in order to get the third addition are to be stated.

Concept introduction:

The cyclic ether containing a ring of atoms, carbon, oxygen and carbon is called an epoxide. The opening of the epoxide ring takes place in the presence of a nucleophile. The reaction of amine and epoxide leads to the opening of the epoxide ring.

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Answer 3

Question

Chapter 23, Problem 23.13P

Interpretation Introduction

(a)

Interpretation:

The mechanism of the reaction between 2-methylpropan-2-amine and epoxide is to be stated.

Concept introduction:

The cyclic ether containing a ring of atoms, carbon, oxygen and carbon is called an epoxide. The opening of the epoxide ring takes place in the presence of a nucleophile. The reaction of amine and epoxide leads to the opening of the epoxide ring.

Interpretation Introduction

(b)

Interpretation:

The mechanism of the reaction between ammonia and acrylonitrile is to be stated.

Concept introduction:

The cyclic ether containing a ring of atoms, carbon, oxygen and carbon is called an epoxide. The opening of the epoxide ring takes place in the presence of a nucleophile. The reaction of amine and epoxide leads to the opening of the epoxide ring.

Interpretation Introduction

(c)

Interpretation:

The reason as to why the reaction between ammonia and acrylonitrile stops after two additions, and a third doesn’t occur in high yield is to be stated. The changes that are required in the reaction condition in order to get the third addition are to be stated.

Concept introduction:

The cyclic ether containing a ring of atoms, carbon, oxygen and carbon is called an epoxide. The opening of the epoxide ring takes place in the presence of a nucleophile. The reaction of amine and epoxide leads to the opening of the epoxide ring.

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Answer 4

Question

Chapter 23, Problem 23.13P

Interpretation Introduction

(a)

Interpretation:

The mechanism of the reaction between 2-methylpropan-2-amine and epoxide is to be stated.

Concept introduction:

The cyclic ether containing a ring of atoms, carbon, oxygen and carbon is called an epoxide. The opening of the epoxide ring takes place in the presence of a nucleophile. The reaction of amine and epoxide leads to the opening of the epoxide ring.

Interpretation Introduction

(b)

Interpretation:

The mechanism of the reaction between ammonia and acrylonitrile is to be stated.

Concept introduction:

The cyclic ether containing a ring of atoms, carbon, oxygen and carbon is called an epoxide. The opening of the epoxide ring takes place in the presence of a nucleophile. The reaction of amine and epoxide leads to the opening of the epoxide ring.

Interpretation Introduction

(c)

Interpretation:

The reason as to why the reaction between ammonia and acrylonitrile stops after two additions, and a third doesn’t occur in high yield is to be stated. The changes that are required in the reaction condition in order to get the third addition are to be stated.

Concept introduction:

The cyclic ether containing a ring of atoms, carbon, oxygen and carbon is called an epoxide. The opening of the epoxide ring takes place in the presence of a nucleophile. The reaction of amine and epoxide leads to the opening of the epoxide ring.

Expert Solution & Answer

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Answer 5

Chapter 23, Problem 23.13P

Interpretation Introduction

(a)

Interpretation:

The mechanism of the reaction between 2-methylpropan-2-amine and epoxide is to be stated.

Concept introduction:

The cyclic ether containing a ring of atoms, carbon, oxygen and carbon is called an epoxide. The opening of the epoxide ring takes place in the presence of a nucleophile. The reaction of amine and epoxide leads to the opening of the epoxide ring.

Interpretation Introduction

(b)

Interpretation:

The mechanism of the reaction between ammonia and acrylonitrile is to be stated.

Concept introduction:

The cyclic ether containing a ring of atoms, carbon, oxygen and carbon is called an epoxide. The opening of the epoxide ring takes place in the presence of a nucleophile. The reaction of amine and epoxide leads to the opening of the epoxide ring.

Interpretation Introduction

(c)

Interpretation:

The reason as to why the reaction between ammonia and acrylonitrile stops after two additions, and a third doesn’t occur in high yield is to be stated. The changes that are required in the reaction condition in order to get the third addition are to be stated.

Concept introduction:

The cyclic ether containing a ring of atoms, carbon, oxygen and carbon is called an epoxide. The opening of the epoxide ring takes place in the presence of a nucleophile. The reaction of amine and epoxide leads to the opening of the epoxide ring.

Answer 6

Chapter 23, Problem 23.13P

Interpretation Introduction

(a)

Interpretation:

The mechanism of the reaction between 2-methylpropan-2-amine and epoxide is to be stated.

Concept introduction:

The cyclic ether containing a ring of atoms, carbon, oxygen and carbon is called an epoxide. The opening of the epoxide ring takes place in the presence of a nucleophile. The reaction of amine and epoxide leads to the opening of the epoxide ring.

Answer 7

Chapter 23, Problem 23.13P

Interpretation Introduction

(a)

Interpretation:

The mechanism of the reaction between 2-methylpropan-2-amine and epoxide is to be stated.

Concept introduction:

The cyclic ether containing a ring of atoms, carbon, oxygen and carbon is called an epoxide. The opening of the epoxide ring takes place in the presence of a nucleophile. The reaction of amine and epoxide leads to the opening of the epoxide ring.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The mechanism of the reaction between ammonia and acrylonitrile is to be stated.

Concept introduction:

The cyclic ether containing a ring of atoms, carbon, oxygen and carbon is called an epoxide. The opening of the epoxide ring takes place in the presence of a nucleophile. The reaction of amine and epoxide leads to the opening of the epoxide ring.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The mechanism of the reaction between ammonia and acrylonitrile is to be stated.

Concept introduction:

The cyclic ether containing a ring of atoms, carbon, oxygen and carbon is called an epoxide. The opening of the epoxide ring takes place in the presence of a nucleophile. The reaction of amine and epoxide leads to the opening of the epoxide ring.

Answer 10

Interpretation Introduction

(c)

Interpretation:

The reason as to why the reaction between ammonia and acrylonitrile stops after two additions, and a third doesn’t occur in high yield is to be stated. The changes that are required in the reaction condition in order to get the third addition are to be stated.

Concept introduction:

The cyclic ether containing a ring of atoms, carbon, oxygen and carbon is called an epoxide. The opening of the epoxide ring takes place in the presence of a nucleophile. The reaction of amine and epoxide leads to the opening of the epoxide ring.

Answer 11

Interpretation Introduction

(c)

Interpretation:

The reason as to why the reaction between ammonia and acrylonitrile stops after two additions, and a third doesn’t occur in high yield is to be stated. The changes that are required in the reaction condition in order to get the third addition are to be stated.

Concept introduction:

The cyclic ether containing a ring of atoms, carbon, oxygen and carbon is called an epoxide. The opening of the epoxide ring takes place in the presence of a nucleophile. The reaction of amine and epoxide leads to the opening of the epoxide ring.

Answer 12

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Answer 13

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Answer 14

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Answer 15

Ch. 23 - Prob. 23.1P Ch. 23 - Prob. 23.2P Ch. 23 - Prob. 23.3P Ch. 23 - Prob. 23.4P Ch. 23 - Prob. 23.5P Ch. 23 - Prob. 23.6P Ch. 23 - Prob. 23.7P Ch. 23 - Prob. 23.8P Ch. 23 - Prob. 23.9P Ch. 23 - Prob. 23.10P

Solution Summary: The author explains the mechanism of the reaction between 2-methylpropan-2-amine and epoxide.

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Chapter 23 Solutions