(a) Interpretation: Preparation of N - phenylbenzamide from an amine and an acid chloride is to be predicted. Concept introduction: The method used to synthesise amides from amines and acid chlorides in the presence of a base is known as Schotten Baumann reaction. It is typically used to indicate two-phase solvent system in which one is water and other is an organic solvent. It is a condensation reaction in which two molecules combine to form a larger molecule.

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Answer 1

Question

Chapter 23, Problem 23.22P

Interpretation Introduction

(a)

Interpretation:

Preparation of N- phenylbenzamide from an amine and an acid chloride is to be predicted.

Concept introduction:

The method used to synthesise amides from amines and acid chlorides in the presence of a base is known as Schotten Baumann reaction. It is typically used to indicate two-phase solvent system in which one is water and other is an organic solvent. It is a condensation reaction in which two molecules combine to form a larger molecule.

Interpretation Introduction

(b)

Interpretation:

Preparation of N- benzyl -N- ethylpropionamide from N- ethylaniline and a propionyl chloride is to be predicted.

Concept introduction:

The method used to synthesise amides from amines and acid chlorides in the presence of a base is known as Schotten Baumann. It is typically used to indicate two-phase solvent system in which one is water and other is an organic solvent. It is a condensation reaction in which two molecules combine to form a larger molecule.

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Give reasons :(a) Aniline is a weaker base than cyclohexyl amine.(b) It is difficult to prepare pure amines by ammonolysis of alkyl halides.

Predict the products from the reactions of the following amines with sodium nitrite indilute HCl.(a) cyclohexanamine

Draw the structure of the product that will be formed when each of the following amines reacts with sodium nitrite and hydrochloric acid, followed by cuprous chloride. (a) propylamine (b) dipropylamine (c) N-propylaniline (d) N,N-dipropylaniline (e) p-propylaniline

Answer 2

Question

Chapter 23, Problem 23.22P

Interpretation Introduction

(a)

Interpretation:

Preparation of N- phenylbenzamide from an amine and an acid chloride is to be predicted.

Concept introduction:

The method used to synthesise amides from amines and acid chlorides in the presence of a base is known as Schotten Baumann reaction. It is typically used to indicate two-phase solvent system in which one is water and other is an organic solvent. It is a condensation reaction in which two molecules combine to form a larger molecule.

Interpretation Introduction

(b)

Interpretation:

Preparation of N- benzyl -N- ethylpropionamide from N- ethylaniline and a propionyl chloride is to be predicted.

Concept introduction:

The method used to synthesise amides from amines and acid chlorides in the presence of a base is known as Schotten Baumann. It is typically used to indicate two-phase solvent system in which one is water and other is an organic solvent. It is a condensation reaction in which two molecules combine to form a larger molecule.

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Answer 3

Question

Chapter 23, Problem 23.22P

Interpretation Introduction

(a)

Interpretation:

Preparation of N- phenylbenzamide from an amine and an acid chloride is to be predicted.

Concept introduction:

The method used to synthesise amides from amines and acid chlorides in the presence of a base is known as Schotten Baumann reaction. It is typically used to indicate two-phase solvent system in which one is water and other is an organic solvent. It is a condensation reaction in which two molecules combine to form a larger molecule.

Interpretation Introduction

(b)

Interpretation:

Preparation of N- benzyl -N- ethylpropionamide from N- ethylaniline and a propionyl chloride is to be predicted.

Concept introduction:

The method used to synthesise amides from amines and acid chlorides in the presence of a base is known as Schotten Baumann. It is typically used to indicate two-phase solvent system in which one is water and other is an organic solvent. It is a condensation reaction in which two molecules combine to form a larger molecule.

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Answer 4

Question

Chapter 23, Problem 23.22P

Interpretation Introduction

(a)

Interpretation:

Preparation of N- phenylbenzamide from an amine and an acid chloride is to be predicted.

Concept introduction:

The method used to synthesise amides from amines and acid chlorides in the presence of a base is known as Schotten Baumann reaction. It is typically used to indicate two-phase solvent system in which one is water and other is an organic solvent. It is a condensation reaction in which two molecules combine to form a larger molecule.

Interpretation Introduction

(b)

Interpretation:

Preparation of N- benzyl -N- ethylpropionamide from N- ethylaniline and a propionyl chloride is to be predicted.

Concept introduction:

The method used to synthesise amides from amines and acid chlorides in the presence of a base is known as Schotten Baumann. It is typically used to indicate two-phase solvent system in which one is water and other is an organic solvent. It is a condensation reaction in which two molecules combine to form a larger molecule.

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Answer 5

Chapter 23, Problem 23.22P

Interpretation Introduction

(a)

Interpretation:

Preparation of N- phenylbenzamide from an amine and an acid chloride is to be predicted.

Concept introduction:

The method used to synthesise amides from amines and acid chlorides in the presence of a base is known as Schotten Baumann reaction. It is typically used to indicate two-phase solvent system in which one is water and other is an organic solvent. It is a condensation reaction in which two molecules combine to form a larger molecule.

Interpretation Introduction

(b)

Interpretation:

Preparation of N- benzyl -N- ethylpropionamide from N- ethylaniline and a propionyl chloride is to be predicted.

Concept introduction:

The method used to synthesise amides from amines and acid chlorides in the presence of a base is known as Schotten Baumann. It is typically used to indicate two-phase solvent system in which one is water and other is an organic solvent. It is a condensation reaction in which two molecules combine to form a larger molecule.

Answer 6

Chapter 23, Problem 23.22P

Interpretation Introduction

(a)

Interpretation:

Preparation of N- phenylbenzamide from an amine and an acid chloride is to be predicted.

Concept introduction:

The method used to synthesise amides from amines and acid chlorides in the presence of a base is known as Schotten Baumann reaction. It is typically used to indicate two-phase solvent system in which one is water and other is an organic solvent. It is a condensation reaction in which two molecules combine to form a larger molecule.

Answer 7

Chapter 23, Problem 23.22P

Interpretation Introduction

(a)

Interpretation:

Preparation of N- phenylbenzamide from an amine and an acid chloride is to be predicted.

Concept introduction:

The method used to synthesise amides from amines and acid chlorides in the presence of a base is known as Schotten Baumann reaction. It is typically used to indicate two-phase solvent system in which one is water and other is an organic solvent. It is a condensation reaction in which two molecules combine to form a larger molecule.

Answer 8

Interpretation Introduction

(b)

Interpretation:

Preparation of N- benzyl -N- ethylpropionamide from N- ethylaniline and a propionyl chloride is to be predicted.

Concept introduction:

The method used to synthesise amides from amines and acid chlorides in the presence of a base is known as Schotten Baumann. It is typically used to indicate two-phase solvent system in which one is water and other is an organic solvent. It is a condensation reaction in which two molecules combine to form a larger molecule.

Answer 9

Interpretation Introduction

(b)

Interpretation:

Preparation of N- benzyl -N- ethylpropionamide from N- ethylaniline and a propionyl chloride is to be predicted.

Concept introduction:

The method used to synthesise amides from amines and acid chlorides in the presence of a base is known as Schotten Baumann. It is typically used to indicate two-phase solvent system in which one is water and other is an organic solvent. It is a condensation reaction in which two molecules combine to form a larger molecule.

Answer 10

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Answer 11

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Answer 12

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Answer 13

Ch. 23 - Prob. 23.1P Ch. 23 - Prob. 23.2P Ch. 23 - Prob. 23.3P Ch. 23 - Prob. 23.4P Ch. 23 - Prob. 23.5P Ch. 23 - Prob. 23.6P Ch. 23 - Prob. 23.7P Ch. 23 - Prob. 23.8P Ch. 23 - Prob. 23.9P Ch. 23 - Prob. 23.10P

Solution Summary: The author explains the Schotten Baumann reaction, which is used to synthesise amides from amines and acid chlorides in the presence of a base.

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Chapter 23 Solutions