(a) Interpretation: The reaction for the preparation of 2, 4-dinitroaniline from aniline is to be stated. Concept introduction: The replacement of hydrogen atom attached to a carbon atom of electron-rich benzene ring by an electrophile is known as electrophilic aromatic substitution reaction. The rate of electrophilic aromatic substitution reaction depends on the substituted group on the aromatic ring. The ring deactivating group retards the electrophilic aromatic substitution reaction and ring activating group enhances the electrophilic aromatic substitution reaction.

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Answer 1

Question

Chapter 23, Problem 23.28P

Interpretation Introduction

(a)

Interpretation:

The reaction for the preparation of 2, 4-dinitroaniline from aniline is to be stated.

Concept introduction:

The replacement of hydrogen atom attached to a carbon atom of electron-rich benzene ring by an electrophile is known as electrophilic aromatic substitution reaction. The rate of electrophilic aromatic substitution reaction depends on the substituted group on the aromatic ring. The ring deactivating group retards the electrophilic aromatic substitution reaction and ring activating group enhances the electrophilic aromatic substitution reaction.

Interpretation Introduction

(b)

Interpretation:

The reaction for the preparation of sulfathiazole from aniline is to be stated.

Concept introduction:

The replacement of hydrogen atom attached to a carbon atom of electron-rich benzene ring by an electrophile is known as electrophilic aromatic substitution reaction. The rate of electrophilic aromatic substitution reaction depends on the substituted group on the aromatic ring. The ring deactivating group retards the electrophilic aromatic substitution reaction and ring activating group enhances the electrophilic aromatic substitution reaction.

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Show how to synthesize the following amines from the indicated starting materials.(a) N-cyclopentylaniline from aniline (b) N-ethylpyrrolidine from pyrrolidine

Arrange the members of each group in order of decreasing basicity: (a) Ammonia, aniline, methylamine (b) Acetanilide, aniline, N-methylaniline (c) 2,4-Dichloroaniline, 2,4-dimethylaniline, 2,4-dinitroaniline (d) 3,4-Dichloroaniline, 4-chloro-2-nitroaniline, 4-chloro-3-nitroaniline (e) Dimethylamine, diphenylamine, N-methylaniline

Predict the products from the reactions of the following amines with sodium nitrite indilute HCl.(a) cyclohexanamine

Answer 2

Question

Chapter 23, Problem 23.28P

Interpretation Introduction

(a)

Interpretation:

The reaction for the preparation of 2, 4-dinitroaniline from aniline is to be stated.

Concept introduction:

The replacement of hydrogen atom attached to a carbon atom of electron-rich benzene ring by an electrophile is known as electrophilic aromatic substitution reaction. The rate of electrophilic aromatic substitution reaction depends on the substituted group on the aromatic ring. The ring deactivating group retards the electrophilic aromatic substitution reaction and ring activating group enhances the electrophilic aromatic substitution reaction.

Interpretation Introduction

(b)

Interpretation:

The reaction for the preparation of sulfathiazole from aniline is to be stated.

Concept introduction:

The replacement of hydrogen atom attached to a carbon atom of electron-rich benzene ring by an electrophile is known as electrophilic aromatic substitution reaction. The rate of electrophilic aromatic substitution reaction depends on the substituted group on the aromatic ring. The ring deactivating group retards the electrophilic aromatic substitution reaction and ring activating group enhances the electrophilic aromatic substitution reaction.

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Answer 3

Question

Chapter 23, Problem 23.28P

Interpretation Introduction

(a)

Interpretation:

The reaction for the preparation of 2, 4-dinitroaniline from aniline is to be stated.

Concept introduction:

The replacement of hydrogen atom attached to a carbon atom of electron-rich benzene ring by an electrophile is known as electrophilic aromatic substitution reaction. The rate of electrophilic aromatic substitution reaction depends on the substituted group on the aromatic ring. The ring deactivating group retards the electrophilic aromatic substitution reaction and ring activating group enhances the electrophilic aromatic substitution reaction.

Interpretation Introduction

(b)

Interpretation:

The reaction for the preparation of sulfathiazole from aniline is to be stated.

Concept introduction:

The replacement of hydrogen atom attached to a carbon atom of electron-rich benzene ring by an electrophile is known as electrophilic aromatic substitution reaction. The rate of electrophilic aromatic substitution reaction depends on the substituted group on the aromatic ring. The ring deactivating group retards the electrophilic aromatic substitution reaction and ring activating group enhances the electrophilic aromatic substitution reaction.

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Answer 4

Question

Chapter 23, Problem 23.28P

Interpretation Introduction

(a)

Interpretation:

The reaction for the preparation of 2, 4-dinitroaniline from aniline is to be stated.

Concept introduction:

The replacement of hydrogen atom attached to a carbon atom of electron-rich benzene ring by an electrophile is known as electrophilic aromatic substitution reaction. The rate of electrophilic aromatic substitution reaction depends on the substituted group on the aromatic ring. The ring deactivating group retards the electrophilic aromatic substitution reaction and ring activating group enhances the electrophilic aromatic substitution reaction.

Interpretation Introduction

(b)

Interpretation:

The reaction for the preparation of sulfathiazole from aniline is to be stated.

Concept introduction:

The replacement of hydrogen atom attached to a carbon atom of electron-rich benzene ring by an electrophile is known as electrophilic aromatic substitution reaction. The rate of electrophilic aromatic substitution reaction depends on the substituted group on the aromatic ring. The ring deactivating group retards the electrophilic aromatic substitution reaction and ring activating group enhances the electrophilic aromatic substitution reaction.

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Answer 5

Chapter 23, Problem 23.28P

Interpretation Introduction

(a)

Interpretation:

The reaction for the preparation of 2, 4-dinitroaniline from aniline is to be stated.

Concept introduction:

The replacement of hydrogen atom attached to a carbon atom of electron-rich benzene ring by an electrophile is known as electrophilic aromatic substitution reaction. The rate of electrophilic aromatic substitution reaction depends on the substituted group on the aromatic ring. The ring deactivating group retards the electrophilic aromatic substitution reaction and ring activating group enhances the electrophilic aromatic substitution reaction.

Interpretation Introduction

(b)

Interpretation:

The reaction for the preparation of sulfathiazole from aniline is to be stated.

Concept introduction:

The replacement of hydrogen atom attached to a carbon atom of electron-rich benzene ring by an electrophile is known as electrophilic aromatic substitution reaction. The rate of electrophilic aromatic substitution reaction depends on the substituted group on the aromatic ring. The ring deactivating group retards the electrophilic aromatic substitution reaction and ring activating group enhances the electrophilic aromatic substitution reaction.

Answer 6

Chapter 23, Problem 23.28P

Interpretation Introduction

(a)

Interpretation:

The reaction for the preparation of 2, 4-dinitroaniline from aniline is to be stated.

Concept introduction:

The replacement of hydrogen atom attached to a carbon atom of electron-rich benzene ring by an electrophile is known as electrophilic aromatic substitution reaction. The rate of electrophilic aromatic substitution reaction depends on the substituted group on the aromatic ring. The ring deactivating group retards the electrophilic aromatic substitution reaction and ring activating group enhances the electrophilic aromatic substitution reaction.

Answer 7

Chapter 23, Problem 23.28P

Interpretation Introduction

(a)

Interpretation:

The reaction for the preparation of 2, 4-dinitroaniline from aniline is to be stated.

Concept introduction:

The replacement of hydrogen atom attached to a carbon atom of electron-rich benzene ring by an electrophile is known as electrophilic aromatic substitution reaction. The rate of electrophilic aromatic substitution reaction depends on the substituted group on the aromatic ring. The ring deactivating group retards the electrophilic aromatic substitution reaction and ring activating group enhances the electrophilic aromatic substitution reaction.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The reaction for the preparation of sulfathiazole from aniline is to be stated.

Concept introduction:

The replacement of hydrogen atom attached to a carbon atom of electron-rich benzene ring by an electrophile is known as electrophilic aromatic substitution reaction. The rate of electrophilic aromatic substitution reaction depends on the substituted group on the aromatic ring. The ring deactivating group retards the electrophilic aromatic substitution reaction and ring activating group enhances the electrophilic aromatic substitution reaction.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The reaction for the preparation of sulfathiazole from aniline is to be stated.

Concept introduction:

The replacement of hydrogen atom attached to a carbon atom of electron-rich benzene ring by an electrophile is known as electrophilic aromatic substitution reaction. The rate of electrophilic aromatic substitution reaction depends on the substituted group on the aromatic ring. The ring deactivating group retards the electrophilic aromatic substitution reaction and ring activating group enhances the electrophilic aromatic substitution reaction.

Answer 10

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Answer 11

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Answer 12

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Answer 13

Ch. 23 - Prob. 23.1P Ch. 23 - Prob. 23.2P Ch. 23 - Prob. 23.3P Ch. 23 - Prob. 23.4P Ch. 23 - Prob. 23.5P Ch. 23 - Prob. 23.6P Ch. 23 - Prob. 23.7P Ch. 23 - Prob. 23.8P Ch. 23 - Prob. 23.9P Ch. 23 - Prob. 23.10P

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Chapter 23 Solutions