(a) Interpretation: The curved arrow mechanism for the given reaction is to be stated. Concept introduction: The benzene molecule is an aromatic compound which is a hydrocarbon. It follows all the rules of aromaticity. There are also some aromatic compounds that contain a hetero atom along with carbon and hydrogen atom. These are known as heterocyclic aromatic compounds. They show similar properties as benzene.

Question

How would you account for the following :(a) Electrophilic susbstitution in case of aromatic amines takes place more readily than benzene.(b) Ethanamide is a weaker base than ethanamine.

Answer 1

Question

Chapter 26, Problem 26.43AP

Interpretation Introduction

(a)

Interpretation:

The curved arrow mechanism for the given reaction is to be stated.

Concept introduction:

The benzene molecule is an aromatic compound which is a hydrocarbon. It follows all the rules of aromaticity. There are also some aromatic compounds that contain a hetero atom along with carbon and hydrogen atom. These are known as heterocyclic aromatic compounds. They show similar properties as benzene.

Interpretation Introduction

(b)

Interpretation:

The curved arrow mechanism for the given reaction is to be stated.

Concept introduction:

The benzene molecule is an aromatic compound which is a hydrocarbon. It follows all the rules of aromaticity. There are also some aromatic compounds that contain a hetero atom along with carbon and hydrogen atom. These are known as heterocyclic aromatic compounds. They show similar properties as benzene.

Interpretation Introduction

(c)

Interpretation:

The curved arrow mechanism for the given reaction is to be stated.

Concept introduction:

The benzene molecule is an aromatic compound which is a hydrocarbon. It follows all the rules of aromaticity. There are also some aromatic compounds that contain a hetero atom along with carbon and hydrogen atom. These are known as heterocyclic aromatic compounds. They show similar properties as benzene.

Interpretation Introduction

(d)

Interpretation:

The curved arrow mechanism for the given reaction and structure of the intermediate A is to be stated.

Concept introduction:

The benzene molecule is an aromatic compound which is a hydrocarbon. It follows all the rules of aromaticity. There are also some aromatic compounds that contain a hetero atom along with carbon and hydrogen atom. These are known as heterocyclic aromatic compounds. They show similar properties as benzene.

Interpretation Introduction

(e)

Interpretation:

The curved arrow mechanism for the given reaction is to be stated.

Concept introduction:

The benzene molecule is an aromatic compound which is a hydrocarbon. It follows all the rules of aromaticity. There are also some aromatic compounds that contain a hetero atom along with carbon and hydrogen atom. These are known as heterocyclic aromatic compounds. They show similar properties as benzene.

Interpretation Introduction

(f)

Interpretation:

The curved arrow mechanism for the given reaction and structure of the intermediate B is to be stated.

Concept introduction:

The benzene molecule is an aromatic compound which is a hydrocarbon. It follows all the rules of aromaticity. There are also some aromatic compounds that contain a hetero atom along with carbon and hydrogen atom. These are known as heterocyclic aromatic compounds. They show similar properties as benzene.

Interpretation Introduction

(g)

Interpretation:

The curved arrow mechanism for the given reaction is to be stated.

Concept introduction:

The benzene molecule is an aromatic compound which is a hydrocarbon. It follows all the rules of aromaticity. There are also some aromatic compounds that contain a hetero atom along with carbon and hydrogen atom. These are known as heterocyclic aromatic compounds. They show similar properties as benzene.

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How would you account for the following :(a) Electrophilic susbstitution in case of aromatic amines takes place more readily than benzene.(b) Ethanamide is a weaker base than ethanamine.

(a) Discuss the aromaticity of a six membered heterocyclic compound which is weak base in nature. (b) Discuss about the stability factors of the reaction intermediates, which involved in a name reaction "Wittig rearrangement".

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Answer 2

Question

Chapter 26, Problem 26.43AP

Interpretation Introduction

(a)

Interpretation:

The curved arrow mechanism for the given reaction is to be stated.

Concept introduction:

The benzene molecule is an aromatic compound which is a hydrocarbon. It follows all the rules of aromaticity. There are also some aromatic compounds that contain a hetero atom along with carbon and hydrogen atom. These are known as heterocyclic aromatic compounds. They show similar properties as benzene.

Interpretation Introduction

(b)

Interpretation:

The curved arrow mechanism for the given reaction is to be stated.

Concept introduction:

The benzene molecule is an aromatic compound which is a hydrocarbon. It follows all the rules of aromaticity. There are also some aromatic compounds that contain a hetero atom along with carbon and hydrogen atom. These are known as heterocyclic aromatic compounds. They show similar properties as benzene.

Interpretation Introduction

(c)

Interpretation:

The curved arrow mechanism for the given reaction is to be stated.

Concept introduction:

The benzene molecule is an aromatic compound which is a hydrocarbon. It follows all the rules of aromaticity. There are also some aromatic compounds that contain a hetero atom along with carbon and hydrogen atom. These are known as heterocyclic aromatic compounds. They show similar properties as benzene.

Interpretation Introduction

(d)

Interpretation:

The curved arrow mechanism for the given reaction and structure of the intermediate A is to be stated.

Concept introduction:

The benzene molecule is an aromatic compound which is a hydrocarbon. It follows all the rules of aromaticity. There are also some aromatic compounds that contain a hetero atom along with carbon and hydrogen atom. These are known as heterocyclic aromatic compounds. They show similar properties as benzene.

Interpretation Introduction

(e)

Interpretation:

The curved arrow mechanism for the given reaction is to be stated.

Concept introduction:

The benzene molecule is an aromatic compound which is a hydrocarbon. It follows all the rules of aromaticity. There are also some aromatic compounds that contain a hetero atom along with carbon and hydrogen atom. These are known as heterocyclic aromatic compounds. They show similar properties as benzene.

Interpretation Introduction

(f)

Interpretation:

The curved arrow mechanism for the given reaction and structure of the intermediate B is to be stated.

Concept introduction:

The benzene molecule is an aromatic compound which is a hydrocarbon. It follows all the rules of aromaticity. There are also some aromatic compounds that contain a hetero atom along with carbon and hydrogen atom. These are known as heterocyclic aromatic compounds. They show similar properties as benzene.

Interpretation Introduction

(g)

Interpretation:

The curved arrow mechanism for the given reaction is to be stated.

Concept introduction:

The benzene molecule is an aromatic compound which is a hydrocarbon. It follows all the rules of aromaticity. There are also some aromatic compounds that contain a hetero atom along with carbon and hydrogen atom. These are known as heterocyclic aromatic compounds. They show similar properties as benzene.

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Answer 3

Question

Chapter 26, Problem 26.43AP

Interpretation Introduction

(a)

Interpretation:

The curved arrow mechanism for the given reaction is to be stated.

Concept introduction:

The benzene molecule is an aromatic compound which is a hydrocarbon. It follows all the rules of aromaticity. There are also some aromatic compounds that contain a hetero atom along with carbon and hydrogen atom. These are known as heterocyclic aromatic compounds. They show similar properties as benzene.

Interpretation Introduction

(b)

Interpretation:

The curved arrow mechanism for the given reaction is to be stated.

Concept introduction:

The benzene molecule is an aromatic compound which is a hydrocarbon. It follows all the rules of aromaticity. There are also some aromatic compounds that contain a hetero atom along with carbon and hydrogen atom. These are known as heterocyclic aromatic compounds. They show similar properties as benzene.

Interpretation Introduction

(c)

Interpretation:

The curved arrow mechanism for the given reaction is to be stated.

Concept introduction:

The benzene molecule is an aromatic compound which is a hydrocarbon. It follows all the rules of aromaticity. There are also some aromatic compounds that contain a hetero atom along with carbon and hydrogen atom. These are known as heterocyclic aromatic compounds. They show similar properties as benzene.

Interpretation Introduction

(d)

Interpretation:

The curved arrow mechanism for the given reaction and structure of the intermediate A is to be stated.

Concept introduction:

The benzene molecule is an aromatic compound which is a hydrocarbon. It follows all the rules of aromaticity. There are also some aromatic compounds that contain a hetero atom along with carbon and hydrogen atom. These are known as heterocyclic aromatic compounds. They show similar properties as benzene.

Interpretation Introduction

(e)

Interpretation:

The curved arrow mechanism for the given reaction is to be stated.

Concept introduction:

The benzene molecule is an aromatic compound which is a hydrocarbon. It follows all the rules of aromaticity. There are also some aromatic compounds that contain a hetero atom along with carbon and hydrogen atom. These are known as heterocyclic aromatic compounds. They show similar properties as benzene.

Interpretation Introduction

(f)

Interpretation:

The curved arrow mechanism for the given reaction and structure of the intermediate B is to be stated.

Concept introduction:

The benzene molecule is an aromatic compound which is a hydrocarbon. It follows all the rules of aromaticity. There are also some aromatic compounds that contain a hetero atom along with carbon and hydrogen atom. These are known as heterocyclic aromatic compounds. They show similar properties as benzene.

Interpretation Introduction

(g)

Interpretation:

The curved arrow mechanism for the given reaction is to be stated.

Concept introduction:

The benzene molecule is an aromatic compound which is a hydrocarbon. It follows all the rules of aromaticity. There are also some aromatic compounds that contain a hetero atom along with carbon and hydrogen atom. These are known as heterocyclic aromatic compounds. They show similar properties as benzene.

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Answer 4

Question

Chapter 26, Problem 26.43AP

Interpretation Introduction

(a)

Interpretation:

The curved arrow mechanism for the given reaction is to be stated.

Concept introduction:

The benzene molecule is an aromatic compound which is a hydrocarbon. It follows all the rules of aromaticity. There are also some aromatic compounds that contain a hetero atom along with carbon and hydrogen atom. These are known as heterocyclic aromatic compounds. They show similar properties as benzene.

Interpretation Introduction

(b)

Interpretation:

The curved arrow mechanism for the given reaction is to be stated.

Concept introduction:

The benzene molecule is an aromatic compound which is a hydrocarbon. It follows all the rules of aromaticity. There are also some aromatic compounds that contain a hetero atom along with carbon and hydrogen atom. These are known as heterocyclic aromatic compounds. They show similar properties as benzene.

Interpretation Introduction

(c)

Interpretation:

The curved arrow mechanism for the given reaction is to be stated.

Concept introduction:

The benzene molecule is an aromatic compound which is a hydrocarbon. It follows all the rules of aromaticity. There are also some aromatic compounds that contain a hetero atom along with carbon and hydrogen atom. These are known as heterocyclic aromatic compounds. They show similar properties as benzene.

Interpretation Introduction

(d)

Interpretation:

The curved arrow mechanism for the given reaction and structure of the intermediate A is to be stated.

Concept introduction:

The benzene molecule is an aromatic compound which is a hydrocarbon. It follows all the rules of aromaticity. There are also some aromatic compounds that contain a hetero atom along with carbon and hydrogen atom. These are known as heterocyclic aromatic compounds. They show similar properties as benzene.

Interpretation Introduction

(e)

Interpretation:

The curved arrow mechanism for the given reaction is to be stated.

Concept introduction:

The benzene molecule is an aromatic compound which is a hydrocarbon. It follows all the rules of aromaticity. There are also some aromatic compounds that contain a hetero atom along with carbon and hydrogen atom. These are known as heterocyclic aromatic compounds. They show similar properties as benzene.

Interpretation Introduction

(f)

Interpretation:

The curved arrow mechanism for the given reaction and structure of the intermediate B is to be stated.

Concept introduction:

The benzene molecule is an aromatic compound which is a hydrocarbon. It follows all the rules of aromaticity. There are also some aromatic compounds that contain a hetero atom along with carbon and hydrogen atom. These are known as heterocyclic aromatic compounds. They show similar properties as benzene.

Interpretation Introduction

(g)

Interpretation:

The curved arrow mechanism for the given reaction is to be stated.

Concept introduction:

The benzene molecule is an aromatic compound which is a hydrocarbon. It follows all the rules of aromaticity. There are also some aromatic compounds that contain a hetero atom along with carbon and hydrogen atom. These are known as heterocyclic aromatic compounds. They show similar properties as benzene.

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Answer 5

Chapter 26, Problem 26.43AP

Interpretation Introduction

(a)

Interpretation:

The curved arrow mechanism for the given reaction is to be stated.

Concept introduction:

The benzene molecule is an aromatic compound which is a hydrocarbon. It follows all the rules of aromaticity. There are also some aromatic compounds that contain a hetero atom along with carbon and hydrogen atom. These are known as heterocyclic aromatic compounds. They show similar properties as benzene.

Interpretation Introduction

(b)

Interpretation:

The curved arrow mechanism for the given reaction is to be stated.

Concept introduction:

The benzene molecule is an aromatic compound which is a hydrocarbon. It follows all the rules of aromaticity. There are also some aromatic compounds that contain a hetero atom along with carbon and hydrogen atom. These are known as heterocyclic aromatic compounds. They show similar properties as benzene.

Interpretation Introduction

(c)

Interpretation:

The curved arrow mechanism for the given reaction is to be stated.

Concept introduction:

The benzene molecule is an aromatic compound which is a hydrocarbon. It follows all the rules of aromaticity. There are also some aromatic compounds that contain a hetero atom along with carbon and hydrogen atom. These are known as heterocyclic aromatic compounds. They show similar properties as benzene.

Interpretation Introduction

(d)

Interpretation:

The curved arrow mechanism for the given reaction and structure of the intermediate A is to be stated.

Concept introduction:

The benzene molecule is an aromatic compound which is a hydrocarbon. It follows all the rules of aromaticity. There are also some aromatic compounds that contain a hetero atom along with carbon and hydrogen atom. These are known as heterocyclic aromatic compounds. They show similar properties as benzene.

Interpretation Introduction

(e)

Interpretation:

The curved arrow mechanism for the given reaction is to be stated.

Concept introduction:

The benzene molecule is an aromatic compound which is a hydrocarbon. It follows all the rules of aromaticity. There are also some aromatic compounds that contain a hetero atom along with carbon and hydrogen atom. These are known as heterocyclic aromatic compounds. They show similar properties as benzene.

Interpretation Introduction

(f)

Interpretation:

The curved arrow mechanism for the given reaction and structure of the intermediate B is to be stated.

Concept introduction:

The benzene molecule is an aromatic compound which is a hydrocarbon. It follows all the rules of aromaticity. There are also some aromatic compounds that contain a hetero atom along with carbon and hydrogen atom. These are known as heterocyclic aromatic compounds. They show similar properties as benzene.

Interpretation Introduction

(g)

Interpretation:

The curved arrow mechanism for the given reaction is to be stated.

Concept introduction:

The benzene molecule is an aromatic compound which is a hydrocarbon. It follows all the rules of aromaticity. There are also some aromatic compounds that contain a hetero atom along with carbon and hydrogen atom. These are known as heterocyclic aromatic compounds. They show similar properties as benzene.

Answer 6

Chapter 26, Problem 26.43AP

Interpretation Introduction

(a)

Interpretation:

The curved arrow mechanism for the given reaction is to be stated.

Concept introduction:

The benzene molecule is an aromatic compound which is a hydrocarbon. It follows all the rules of aromaticity. There are also some aromatic compounds that contain a hetero atom along with carbon and hydrogen atom. These are known as heterocyclic aromatic compounds. They show similar properties as benzene.

Answer 7

Chapter 26, Problem 26.43AP

Interpretation Introduction

(a)

Interpretation:

The curved arrow mechanism for the given reaction is to be stated.

Concept introduction:

The benzene molecule is an aromatic compound which is a hydrocarbon. It follows all the rules of aromaticity. There are also some aromatic compounds that contain a hetero atom along with carbon and hydrogen atom. These are known as heterocyclic aromatic compounds. They show similar properties as benzene.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The curved arrow mechanism for the given reaction is to be stated.

Concept introduction:

The benzene molecule is an aromatic compound which is a hydrocarbon. It follows all the rules of aromaticity. There are also some aromatic compounds that contain a hetero atom along with carbon and hydrogen atom. These are known as heterocyclic aromatic compounds. They show similar properties as benzene.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The curved arrow mechanism for the given reaction is to be stated.

Concept introduction:

The benzene molecule is an aromatic compound which is a hydrocarbon. It follows all the rules of aromaticity. There are also some aromatic compounds that contain a hetero atom along with carbon and hydrogen atom. These are known as heterocyclic aromatic compounds. They show similar properties as benzene.

Answer 10

Interpretation Introduction

(c)

Interpretation:

The curved arrow mechanism for the given reaction is to be stated.

Concept introduction:

The benzene molecule is an aromatic compound which is a hydrocarbon. It follows all the rules of aromaticity. There are also some aromatic compounds that contain a hetero atom along with carbon and hydrogen atom. These are known as heterocyclic aromatic compounds. They show similar properties as benzene.

Answer 11

Interpretation Introduction

(c)

Interpretation:

The curved arrow mechanism for the given reaction is to be stated.

Concept introduction:

The benzene molecule is an aromatic compound which is a hydrocarbon. It follows all the rules of aromaticity. There are also some aromatic compounds that contain a hetero atom along with carbon and hydrogen atom. These are known as heterocyclic aromatic compounds. They show similar properties as benzene.

Answer 12

Interpretation Introduction

(d)

Interpretation:

The curved arrow mechanism for the given reaction and structure of the intermediate A is to be stated.

Concept introduction:

The benzene molecule is an aromatic compound which is a hydrocarbon. It follows all the rules of aromaticity. There are also some aromatic compounds that contain a hetero atom along with carbon and hydrogen atom. These are known as heterocyclic aromatic compounds. They show similar properties as benzene.

Answer 13

Interpretation Introduction

(d)

Interpretation:

The curved arrow mechanism for the given reaction and structure of the intermediate A is to be stated.

Concept introduction:

The benzene molecule is an aromatic compound which is a hydrocarbon. It follows all the rules of aromaticity. There are also some aromatic compounds that contain a hetero atom along with carbon and hydrogen atom. These are known as heterocyclic aromatic compounds. They show similar properties as benzene.

Answer 14

Interpretation Introduction

(e)

Interpretation:

The curved arrow mechanism for the given reaction is to be stated.

Concept introduction:

The benzene molecule is an aromatic compound which is a hydrocarbon. It follows all the rules of aromaticity. There are also some aromatic compounds that contain a hetero atom along with carbon and hydrogen atom. These are known as heterocyclic aromatic compounds. They show similar properties as benzene.

Answer 15

Interpretation Introduction

(e)

Interpretation:

The curved arrow mechanism for the given reaction is to be stated.

Concept introduction:

The benzene molecule is an aromatic compound which is a hydrocarbon. It follows all the rules of aromaticity. There are also some aromatic compounds that contain a hetero atom along with carbon and hydrogen atom. These are known as heterocyclic aromatic compounds. They show similar properties as benzene.

Answer 16

Interpretation Introduction

(f)

Interpretation:

The curved arrow mechanism for the given reaction and structure of the intermediate B is to be stated.

Concept introduction:

The benzene molecule is an aromatic compound which is a hydrocarbon. It follows all the rules of aromaticity. There are also some aromatic compounds that contain a hetero atom along with carbon and hydrogen atom. These are known as heterocyclic aromatic compounds. They show similar properties as benzene.

Answer 17

Interpretation Introduction

(f)

Interpretation:

The curved arrow mechanism for the given reaction and structure of the intermediate B is to be stated.

Concept introduction:

The benzene molecule is an aromatic compound which is a hydrocarbon. It follows all the rules of aromaticity. There are also some aromatic compounds that contain a hetero atom along with carbon and hydrogen atom. These are known as heterocyclic aromatic compounds. They show similar properties as benzene.

Answer 18

Interpretation Introduction

(g)

Interpretation:

The curved arrow mechanism for the given reaction is to be stated.

Concept introduction:

The benzene molecule is an aromatic compound which is a hydrocarbon. It follows all the rules of aromaticity. There are also some aromatic compounds that contain a hetero atom along with carbon and hydrogen atom. These are known as heterocyclic aromatic compounds. They show similar properties as benzene.

Answer 19

Interpretation Introduction

(g)

Interpretation:

The curved arrow mechanism for the given reaction is to be stated.

Concept introduction:

The benzene molecule is an aromatic compound which is a hydrocarbon. It follows all the rules of aromaticity. There are also some aromatic compounds that contain a hetero atom along with carbon and hydrogen atom. These are known as heterocyclic aromatic compounds. They show similar properties as benzene.

Answer 20

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Answer 25

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Answer 26

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Answer 27

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Answer 31

Ch. 26 - Prob. 26.1P Ch. 26 - Prob. 26.2P Ch. 26 - Prob. 26.3P Ch. 26 - Prob. 26.4P Ch. 26 - Prob. 26.5P Ch. 26 - Prob. 26.6P Ch. 26 - Prob. 26.7P Ch. 26 - Prob. 26.8P Ch. 26 - Prob. 26.9P Ch. 26 - Prob. 26.10P

Solution Summary: The author explains that the curved arrow mechanism for the given reaction is shown in Figure 2, 3 and 4.

Chapter 26 Solutions