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Concept explainers
(a)
Interpretation:
The name of the given compound is to be stated.
Concept introduction:
The systematic naming of organic compound is given by
Rules for writing IUPAC name from the structural formula are given below.
- First, identify the longest carbon chain.
- The next step is to identify the groups attached to the longest chain.
- Identify the position, location, and a number of the substituents bonded to the carbon chain.
- Use prefix di, tri, tetra if the same type of substituents is present.
- Name the substituents in alphabetical order.
- In the heterocyclic compound, azo for nitrogen, oxo for oxygen, thio for sulfur and so on is used.
(b)
Interpretation:
The name of the given compound is to be stated.
Concept introduction:
The systematic naming of organic compound is given by IUPAC nomenclature. The naming of organic compound is done such that the structure of the organic compound is correctly interpreted from the name.
Rules for writing IUPAC name from the structural formula are given below.
- First, identify the longest carbon chain.
- The next step is to identify the groups attached to the longest chain.
- Identify the position, location, and a number of the substituents bonded to the carbon chain.
- Use prefix di, tri, tetra if the same type of substituents is present.
- Name the substituents in alphabetical order.
- In heterocyclic compound, azo for nitrogen, oxo for oxygen, thio for sulphur and so on is used.
(c)
Interpretation:
The name of the given compound is to be stated.
Concept introduction:
The systematic naming of organic compound is given by IUPAC nomenclature. The naming of organic compound is done such that the structure of the organic compound is correctly interpreted from the name.
Rules for writing IUPAC name from the structural formula are given below.
- First, identify the longest carbon chain.
- The next step is to identify the groups attached to the longest chain.
- Identify the position, location, and a number of the substituents bonded to the carbon chain.
- Use prefix di, tri, tetra if the same type of substituents is present.
- Name the substituents in alphabetical order.
- In heterocyclic compound, aza for nitrogen, oxa for oxygen, thia for sulphur and so on is used.
(d)
Interpretation:
The name of the given compound is to be stated.
Concept introduction:
The systematic naming of organic compound is given by IUPAC nomenclature. The naming of organic compound is done such that the structure of the organic compound is correctly interpreted from the name.
Rules for writing IUPAC name from the structural formula are given below.
- First, identify the longest carbon chain.
- The next step is to identify the groups attached to the longest chain.
- Identify the position, location, and a number of the substituents bonded to the carbon chain.
- Use prefix di, tri, tetra if the same type of substituents is present.
- Name the substituents in alphabetical order.
- In heterocyclic compound, aza for nitrogen, oxa for oxygen, thia for sulphur and so on is used.
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Chapter 26 Solutions
EBK ORGANIC CHEMISTRY
- Biphenyl has the following structure.(a) Is biphenyl a (fused) polynuclear aromatic hydrocarbon?(b) How many pi electrons are there in the two aromatic rings of biphenyl? How does this number compare with that for naphthalene?(c) The heat of hydrogenation for biphenyl is about 418 kJ>mol (100 kcal>mol). Calculate theresonance energy of biphenyl.(d) Compare the resonance energy of biphenyl with that of naphthalene and with that of two benzene rings. Explain thedifference in the resonance energies of naphthalene and biphenyl.arrow_forward(a) Give chemical tests to distinguish between the following :(i) Benzoic acid and ethyl benzoate (ii) Benzaldehyde and acetophenonearrow_forward(4) Write the structure of the following compounds from their IUPAC names. (a) ethanamide (b) methylethanoate (c) propanoic acid (d) 2-butanone (5) Write the structure of the following ethers and amines from their common names (a) methyl propyl (b) trimethylamine (6) Decide whether the following alcohols are polar or nonpolar (a) CH3CH2CH2CH2CH2CH2CH2OH (b) CH3CH2OHarrow_forward
- (a) (CH3)2CHCH2Cl give the common name (if possible).arrow_forwardBiphenyl has the following structure.(a) Is biphenyl a (fused) polynuclear aromatic hydrocarbon?(b) How many pi electrons are there in the two aromatic rings of biphenyl? How does this number compare with that for naphthalene?arrow_forward(ii) Name the following using IUPAC system of nomenclature: (a) CH2 (Cl) CH (NH2) CHO (b) CH3 C (Br) CH2 CH (F) COOH Brarrow_forward
- Consider the following structural formulas. OH -осн A в D E (a) Which of the compounds A-E can easily be oxidized? (b) Provide the typical oxidation products for all compounds selected in (a). (c) Explain why the compounds not selected in (a) cannot be easily oxidized.arrow_forward(a) Draw the structure of the following :(i) p-Methylbenzaldehyde (ii) 4-Methylpent-3-en-2-one(b) Give chemical tests to distinguish between the following pairs of compounds :(i) Benzoic acid and Ethyl benzoate, (ii) Benzaldehyde and Acetophenone.(iii) Phenol and Benzoic acid.arrow_forwardDraw the structures of the following compounds. (a)methylene chloridearrow_forward
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