(a) Interpretation: The curved-arrow mechanism for the reversible reaction of aryl-sulfonic acid in steam is to be predicted. Concept introduction: Electrophilic substitution reactions are that reaction in which an electrophile replaces the atom or function group of a compound. Sulfonation is an electrophilic substitution reaction in which the hydrogen atom of an aromatic ring is replaced by the sulfonic acid functional group .

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Answer 1

Question

Chapter 26, Problem 26.42AP

Interpretation Introduction

(a)

Interpretation:

The curved-arrow mechanism for the reversible reaction of aryl-sulfonic acid in steam is to be predicted.

Concept introduction:

Electrophilic substitution reactions are that reaction in which an electrophile replaces the atom or function group of a compound. Sulfonation is an electrophilic substitution reaction in which the hydrogen atom of an aromatic ring is replaced by the sulfonic acid functional group.

Interpretation Introduction

(b)

Interpretation:

The identification of compound A, B and C in the given reaction scheme is to be predicted.

Concept introduction:

Electrophilic substitution reactions are that reaction in which an electrophile replaces the atom or function group of a compound. Sulfonation is an electrophilic substitution reaction in which the hydrogen atom of an aromatic ring is replaced by the sulfonic acid functional group.

Interpretation Introduction

(c)

Interpretation:

The explanation as to why compound C cannot be synthesized in one step from thiophene.

Concept introduction:

Electrophilic substitution reactions are that reaction in which an electrophile replaces the atom or function group of a compound. Nitration is an electrophilic substitution reaction in which the hydrogen atom of an aromatic ring is replaced by the nitro group.

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Students have asked these similar questions

(a) Which is more reactive towards Electrophilic aromatic substitution (EAS)? (b) Which of the following is a a meta-substituted compound? (c) Which is the least reactive towards Electrophilic aromatic substitution (EAS)? (d) Which is an ortho-substituted compound?

(a) Why are alkyl halides insoluble in water? (b) Why is Butan-l-ol optically inactive but Butan-2-ol is optically active? (c) Although chlorine is an electron withdrawing group, yet it is ortho-, Para- directing in electrophilic aromatic substitution reaction. Why?

Provide the reagents and solvents (where appropriate) needed to bring about the following transformations. (a) CI (b)

Answer 2

Question

Chapter 26, Problem 26.42AP

Interpretation Introduction

(a)

Interpretation:

The curved-arrow mechanism for the reversible reaction of aryl-sulfonic acid in steam is to be predicted.

Concept introduction:

Electrophilic substitution reactions are that reaction in which an electrophile replaces the atom or function group of a compound. Sulfonation is an electrophilic substitution reaction in which the hydrogen atom of an aromatic ring is replaced by the sulfonic acid functional group.

Interpretation Introduction

(b)

Interpretation:

The identification of compound A, B and C in the given reaction scheme is to be predicted.

Concept introduction:

Electrophilic substitution reactions are that reaction in which an electrophile replaces the atom or function group of a compound. Sulfonation is an electrophilic substitution reaction in which the hydrogen atom of an aromatic ring is replaced by the sulfonic acid functional group.

Interpretation Introduction

(c)

Interpretation:

The explanation as to why compound C cannot be synthesized in one step from thiophene.

Concept introduction:

Electrophilic substitution reactions are that reaction in which an electrophile replaces the atom or function group of a compound. Nitration is an electrophilic substitution reaction in which the hydrogen atom of an aromatic ring is replaced by the nitro group.

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Answer 3

Question

Chapter 26, Problem 26.42AP

Interpretation Introduction

(a)

Interpretation:

The curved-arrow mechanism for the reversible reaction of aryl-sulfonic acid in steam is to be predicted.

Concept introduction:

Electrophilic substitution reactions are that reaction in which an electrophile replaces the atom or function group of a compound. Sulfonation is an electrophilic substitution reaction in which the hydrogen atom of an aromatic ring is replaced by the sulfonic acid functional group.

Interpretation Introduction

(b)

Interpretation:

The identification of compound A, B and C in the given reaction scheme is to be predicted.

Concept introduction:

Electrophilic substitution reactions are that reaction in which an electrophile replaces the atom or function group of a compound. Sulfonation is an electrophilic substitution reaction in which the hydrogen atom of an aromatic ring is replaced by the sulfonic acid functional group.

Interpretation Introduction

(c)

Interpretation:

The explanation as to why compound C cannot be synthesized in one step from thiophene.

Concept introduction:

Electrophilic substitution reactions are that reaction in which an electrophile replaces the atom or function group of a compound. Nitration is an electrophilic substitution reaction in which the hydrogen atom of an aromatic ring is replaced by the nitro group.

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Answer 4

Question

Chapter 26, Problem 26.42AP

Interpretation Introduction

(a)

Interpretation:

The curved-arrow mechanism for the reversible reaction of aryl-sulfonic acid in steam is to be predicted.

Concept introduction:

Electrophilic substitution reactions are that reaction in which an electrophile replaces the atom or function group of a compound. Sulfonation is an electrophilic substitution reaction in which the hydrogen atom of an aromatic ring is replaced by the sulfonic acid functional group.

Interpretation Introduction

(b)

Interpretation:

The identification of compound A, B and C in the given reaction scheme is to be predicted.

Concept introduction:

Electrophilic substitution reactions are that reaction in which an electrophile replaces the atom or function group of a compound. Sulfonation is an electrophilic substitution reaction in which the hydrogen atom of an aromatic ring is replaced by the sulfonic acid functional group.

Interpretation Introduction

(c)

Interpretation:

The explanation as to why compound C cannot be synthesized in one step from thiophene.

Concept introduction:

Electrophilic substitution reactions are that reaction in which an electrophile replaces the atom or function group of a compound. Nitration is an electrophilic substitution reaction in which the hydrogen atom of an aromatic ring is replaced by the nitro group.

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Answer 5

Chapter 26, Problem 26.42AP

Interpretation Introduction

(a)

Interpretation:

The curved-arrow mechanism for the reversible reaction of aryl-sulfonic acid in steam is to be predicted.

Concept introduction:

Electrophilic substitution reactions are that reaction in which an electrophile replaces the atom or function group of a compound. Sulfonation is an electrophilic substitution reaction in which the hydrogen atom of an aromatic ring is replaced by the sulfonic acid functional group.

Interpretation Introduction

(b)

Interpretation:

The identification of compound A, B and C in the given reaction scheme is to be predicted.

Concept introduction:

Electrophilic substitution reactions are that reaction in which an electrophile replaces the atom or function group of a compound. Sulfonation is an electrophilic substitution reaction in which the hydrogen atom of an aromatic ring is replaced by the sulfonic acid functional group.

Interpretation Introduction

(c)

Interpretation:

The explanation as to why compound C cannot be synthesized in one step from thiophene.

Concept introduction:

Electrophilic substitution reactions are that reaction in which an electrophile replaces the atom or function group of a compound. Nitration is an electrophilic substitution reaction in which the hydrogen atom of an aromatic ring is replaced by the nitro group.

Answer 6

Chapter 26, Problem 26.42AP

Interpretation Introduction

(a)

Interpretation:

The curved-arrow mechanism for the reversible reaction of aryl-sulfonic acid in steam is to be predicted.

Concept introduction:

Electrophilic substitution reactions are that reaction in which an electrophile replaces the atom or function group of a compound. Sulfonation is an electrophilic substitution reaction in which the hydrogen atom of an aromatic ring is replaced by the sulfonic acid functional group.

Answer 7

Chapter 26, Problem 26.42AP

Interpretation Introduction

(a)

Interpretation:

The curved-arrow mechanism for the reversible reaction of aryl-sulfonic acid in steam is to be predicted.

Concept introduction:

Electrophilic substitution reactions are that reaction in which an electrophile replaces the atom or function group of a compound. Sulfonation is an electrophilic substitution reaction in which the hydrogen atom of an aromatic ring is replaced by the sulfonic acid functional group.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The identification of compound A, B and C in the given reaction scheme is to be predicted.

Concept introduction:

Electrophilic substitution reactions are that reaction in which an electrophile replaces the atom or function group of a compound. Sulfonation is an electrophilic substitution reaction in which the hydrogen atom of an aromatic ring is replaced by the sulfonic acid functional group.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The identification of compound A, B and C in the given reaction scheme is to be predicted.

Concept introduction:

Electrophilic substitution reactions are that reaction in which an electrophile replaces the atom or function group of a compound. Sulfonation is an electrophilic substitution reaction in which the hydrogen atom of an aromatic ring is replaced by the sulfonic acid functional group.

Answer 10

Interpretation Introduction

(c)

Interpretation:

The explanation as to why compound C cannot be synthesized in one step from thiophene.

Concept introduction:

Electrophilic substitution reactions are that reaction in which an electrophile replaces the atom or function group of a compound. Nitration is an electrophilic substitution reaction in which the hydrogen atom of an aromatic ring is replaced by the nitro group.

Answer 11

Interpretation Introduction

(c)

Interpretation:

The explanation as to why compound C cannot be synthesized in one step from thiophene.

Concept introduction:

Electrophilic substitution reactions are that reaction in which an electrophile replaces the atom or function group of a compound. Nitration is an electrophilic substitution reaction in which the hydrogen atom of an aromatic ring is replaced by the nitro group.

Answer 12

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Answer 13

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Answer 14

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Answer 15

Ch. 26 - Prob. 26.1P Ch. 26 - Prob. 26.2P Ch. 26 - Prob. 26.3P Ch. 26 - Prob. 26.4P Ch. 26 - Prob. 26.5P Ch. 26 - Prob. 26.6P Ch. 26 - Prob. 26.7P Ch. 26 - Prob. 26.8P Ch. 26 - Prob. 26.9P Ch. 26 - Prob. 26.10P

Solution Summary: The author explains the curved arrow mechanism for reversible reaction of aryl-sulfonic acid in steam.

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Chapter 26 Solutions