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Concept explainers
(a)
Interpretation:
The curved-arrow mechanism for the reduction of
Concept Introduction:
The compound
(b)
Interpretation:
The oxidized, reduced species and the electrons involved in the given redox reaction is to be stated.
Concept Introduction:
The addition of hydrogen atom or removal of oxygen atom is known as reduction. The species undergoing reduction is said to get reduced. The addition of oxygen and removal of hydrogen is known as oxidation. The species undergoing oxidation is said to get oxidized.
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Chapter 26 Solutions
EBK ORGANIC CHEMISTRY
- In each of the following reactions, two possible organic products can be formed. Draw both organic products in each case and then circle the one formed in greatest quantity in each case. HC (a) 1) NaH, 2) acid (b) CH,CH,OH (c) CH,CH,OH NH2 (d) Oarrow_forwardDraw the major organic products for each of the following reactions. If no reaction occurs, state so. (a) Br (b) ? + (CH),CuLi → ? + CuLi (c) (d) Br CI. CuLi ? ? + CuLi 2 +arrow_forwardBent (D) Trigonal pyramidal 5. A student wishes to prepare ethyl acetate from the reaction of ethanol and acetic acid. To be successful, this reaction requires (A) an acidic catalyst. (C) an oxidizing agent. (B) a basic catalyst. (D) a reducing agent. 6. Which alkyl halide reacts most rapidly with aqueous sodium hydroxide solution? (A) CH₂Cl (B) CH₂I (C) (CH3)3CCH₂Cl (D) (CH3)3CCH₂I 57. How many isomers are there with the formula C6H₁4?arrow_forward
- Aircraft de-icing agents, such as propylene glycol [1,2-propanediol; CH₃CH(OH)CH₂OH; d=1.036 g/mL], are used toremove ice and snow prior to winter flights, but their presence inrunoff depletes O₂ in natural waters. (a) Write a balanced equa-tion for the complete oxidation of propylene glycol by O₂.(b) What is the “theoretical oxygen demand,” in grams of O₂ required per gram of propylene glycol oxidized? (c) What is thetheoretical oxygen demand, in grams of O₂ required per liter ofsolution, of 90.0% by volume aqueous propylene glycol?arrow_forwardA major use of Cl2 is in the manufacture of vinyl chloride,the monomer of poly(vinyl chloride). The two-step sequence forformation of vinyl chloride is depicted below.(a) Write a balanced equation for each step. (b) Write the overallequation. (c) What type of organic reaction is shown in step 1?(d) What type of organic reaction is shown in step 2? (e) If eachmolecule depicted in the initial reaction mixture represents0.15 mol of substance, what mass (in g) of vinyl chloride forms?arrow_forwardPlease draw the corresponding structure of the following compounds. CH3CH₂OH + PCC → 1. (a) 2. Br (a) [the answer from #1] + OH + H₂CRO4 → 3. Mg →arrow_forward
- 4. Write the formula and name for the product when cyclopentene reacts with (a) Cl2(b) HBr(c) H2, Pt (d) H2O, H+arrow_forward(a) Which of the following represents the equation for the reaction between ethane and chlorine in the presence of UV radiation? A C₂H + Cl₂ → C₂H₂Cl₂ + H₂ B C₂H₂ + Cl₂ → C₂H₂Cl + HCI C C₂H₂ + Cl₂ → 2CH₂CI D C₂H₂ + 2Cl₂ → 2CH₂Cl + 2HCI (b) The UV radiation initially causes the formation of A CI-ions. B CI+ ions. C Cl free radicals. D C₂H, free radicals. (c) Once it has started, the reaction can proceed for a time without UV light because A a chain reaction is occurring. B initiation is occurring. C a substitution reaction is occurring. D termination steps cannot occur without UV light.arrow_forwardThe name of the parent six-membered sulfur-containing heterocycle is thiane. It is numbered beginning at sulfur. Multiple incorporation of sulfur in the ring is indicated by the prefixes di-, tri-, and so on. (a) How many methyl-substituted thianes are there? Which ones are chiral? (b) Write structural formulas for 1,4-dithiane and 1,3,5-trithiane. (c) Which dithiane isomer (1,2-, 1,3-, or 1,4-) is a disulfide?(d) Draw the two most stable conformations of the sulfoxide derived from thiane.arrow_forward
- (a) Draw the three isomers of benzenedicarboxylic acid.(b) The isomers have melting points of 210 °C, 343 °C, and 427 °C. Nitration of the isomers at all possible positions was once used to determine their structures. The isomer that melts at 210 °C gives two mononitro isomers. The isomer that melts at 343 °C gives three mononitro isomers. The isomer that melts at 427 °C gives only one mononitro isomer. Show which isomer has which melting point.arrow_forwardWhat is the major organic product of the following Condensation reaction? "OH / heat H. (A) (В) (C) (D) (E)arrow_forwardGive the major organic product(s) for each of the following reactions. Write NR if a reaction will not occur. - CI (a) `NH2 (b) CI 2 H2N-CH3 (c)arrow_forward
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