(a) Interpretation: The increasing order of basicity of the given compounds is to be stated. Concept Introduction: Pyridine is a heterocyclic compound which contain nitrogen atom as heteroatom. The lone pair of nitrogen atom pyridine is not delocalized over the ring. Pyridine is basic in nature. The basicity of pyridine compounds changes with substitution. Basicity of pyridine compounds depends on the nucleophilicity of their nitrogen lone pair.

Question

Want to see the full answer?

Answer 1

Question

Chapter 26, Problem 26.31AP

Interpretation Introduction

(a)

Interpretation:

The increasing order of basicity of the given compounds is to be stated.

Concept Introduction:

Pyridine is a heterocyclic compound which contain nitrogen atom as heteroatom. The lone pair of nitrogen atom pyridine is not delocalized over the ring. Pyridine is basic in nature. The basicity of pyridine compounds changes with substitution. Basicity of pyridine compounds depends on the nucleophilicity of their nitrogen lone pair.

Interpretation Introduction

(b)

Interpretation:

The increasing order of basicity of the given compounds is to be stated.

Concept Introduction:

Pyridine is a heterocyclic compound which contain nitrogen atom as heteroatom. The lone pair of nitrogen atom pyridine is not delocalized over the ring. Pyridine is basic in nature. The basicity of pyridine compounds changes with substitution. Basicity of pyridine compounds depends on the nucleophilicity of their nitrogen lone pair.

Interpretation Introduction

(c)

Interpretation:

The increasing order of basicity of the given compounds is to be stated.

Concept Introduction:

The basicity of compounds can be compared by comparing the stability of their conjugate acid. If the conjugate acid formed is more stable than the basicity of compound will be greater. Resonance structure containing positive charge on electronegative atom is less stable.

Interpretation Introduction

(d)

Interpretation:

The increasing order of basicity of the given compounds is to be stated.

Concept Introduction:

The basicity of compounds can be compared by comparing the stability of their conjugate acid. If the conjugate acid formed is more stable than the basicity of compound will be greater. Resonance structure containing positive charge on electronegative atom is less stable.

Interpretation Introduction

(e)

Interpretation:

The increasing order of basicity of the given compounds is to be stated.

Concept Introduction:

The basicity of compounds can be compared by comparing the stability of their conjugate acid. If the conjugate acid formed is more stable than the basicity of compound will be greater. Resonance structure containing positive charge on electronegative atom is less stable.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Students have asked these similar questions

Which is the stronger acid in each of the following pairs? Explain your reasoning. (a) Phenol or p-hydroxybenzaldehyde (b) m-Cyanophenol or p-cyanophenol (c) o-Fluorophenol or p-fluorophenol

- Rank the following substances in order of increasing acidity: (a) Phenol, p-methylphenol, p-(trifluoromethyl)phenol (b) Benzyl alcohol, phenol, p-hydroxybenzoic acid

(a) Explain why an alkylamine is more basic than ammonia?(b) How would you convert(i) Aniline to nitrobenzene (ii) Aniline to iodobenzene

Answer 2

Question

Chapter 26, Problem 26.31AP

Interpretation Introduction

(a)

Interpretation:

The increasing order of basicity of the given compounds is to be stated.

Concept Introduction:

Pyridine is a heterocyclic compound which contain nitrogen atom as heteroatom. The lone pair of nitrogen atom pyridine is not delocalized over the ring. Pyridine is basic in nature. The basicity of pyridine compounds changes with substitution. Basicity of pyridine compounds depends on the nucleophilicity of their nitrogen lone pair.

Interpretation Introduction

(b)

Interpretation:

The increasing order of basicity of the given compounds is to be stated.

Concept Introduction:

Pyridine is a heterocyclic compound which contain nitrogen atom as heteroatom. The lone pair of nitrogen atom pyridine is not delocalized over the ring. Pyridine is basic in nature. The basicity of pyridine compounds changes with substitution. Basicity of pyridine compounds depends on the nucleophilicity of their nitrogen lone pair.

Interpretation Introduction

(c)

Interpretation:

The increasing order of basicity of the given compounds is to be stated.

Concept Introduction:

The basicity of compounds can be compared by comparing the stability of their conjugate acid. If the conjugate acid formed is more stable than the basicity of compound will be greater. Resonance structure containing positive charge on electronegative atom is less stable.

Interpretation Introduction

(d)

Interpretation:

The increasing order of basicity of the given compounds is to be stated.

Concept Introduction:

The basicity of compounds can be compared by comparing the stability of their conjugate acid. If the conjugate acid formed is more stable than the basicity of compound will be greater. Resonance structure containing positive charge on electronegative atom is less stable.

Interpretation Introduction

(e)

Interpretation:

The increasing order of basicity of the given compounds is to be stated.

Concept Introduction:

The basicity of compounds can be compared by comparing the stability of their conjugate acid. If the conjugate acid formed is more stable than the basicity of compound will be greater. Resonance structure containing positive charge on electronegative atom is less stable.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 3

Question

Chapter 26, Problem 26.31AP

Interpretation Introduction

(a)

Interpretation:

The increasing order of basicity of the given compounds is to be stated.

Concept Introduction:

Pyridine is a heterocyclic compound which contain nitrogen atom as heteroatom. The lone pair of nitrogen atom pyridine is not delocalized over the ring. Pyridine is basic in nature. The basicity of pyridine compounds changes with substitution. Basicity of pyridine compounds depends on the nucleophilicity of their nitrogen lone pair.

Interpretation Introduction

(b)

Interpretation:

The increasing order of basicity of the given compounds is to be stated.

Concept Introduction:

Pyridine is a heterocyclic compound which contain nitrogen atom as heteroatom. The lone pair of nitrogen atom pyridine is not delocalized over the ring. Pyridine is basic in nature. The basicity of pyridine compounds changes with substitution. Basicity of pyridine compounds depends on the nucleophilicity of their nitrogen lone pair.

Interpretation Introduction

(c)

Interpretation:

The increasing order of basicity of the given compounds is to be stated.

Concept Introduction:

The basicity of compounds can be compared by comparing the stability of their conjugate acid. If the conjugate acid formed is more stable than the basicity of compound will be greater. Resonance structure containing positive charge on electronegative atom is less stable.

Interpretation Introduction

(d)

Interpretation:

The increasing order of basicity of the given compounds is to be stated.

Concept Introduction:

The basicity of compounds can be compared by comparing the stability of their conjugate acid. If the conjugate acid formed is more stable than the basicity of compound will be greater. Resonance structure containing positive charge on electronegative atom is less stable.

Interpretation Introduction

(e)

Interpretation:

The increasing order of basicity of the given compounds is to be stated.

Concept Introduction:

The basicity of compounds can be compared by comparing the stability of their conjugate acid. If the conjugate acid formed is more stable than the basicity of compound will be greater. Resonance structure containing positive charge on electronegative atom is less stable.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 4

Question

Chapter 26, Problem 26.31AP

Interpretation Introduction

(a)

Interpretation:

The increasing order of basicity of the given compounds is to be stated.

Concept Introduction:

Pyridine is a heterocyclic compound which contain nitrogen atom as heteroatom. The lone pair of nitrogen atom pyridine is not delocalized over the ring. Pyridine is basic in nature. The basicity of pyridine compounds changes with substitution. Basicity of pyridine compounds depends on the nucleophilicity of their nitrogen lone pair.

Interpretation Introduction

(b)

Interpretation:

The increasing order of basicity of the given compounds is to be stated.

Concept Introduction:

Pyridine is a heterocyclic compound which contain nitrogen atom as heteroatom. The lone pair of nitrogen atom pyridine is not delocalized over the ring. Pyridine is basic in nature. The basicity of pyridine compounds changes with substitution. Basicity of pyridine compounds depends on the nucleophilicity of their nitrogen lone pair.

Interpretation Introduction

(c)

Interpretation:

The increasing order of basicity of the given compounds is to be stated.

Concept Introduction:

The basicity of compounds can be compared by comparing the stability of their conjugate acid. If the conjugate acid formed is more stable than the basicity of compound will be greater. Resonance structure containing positive charge on electronegative atom is less stable.

Interpretation Introduction

(d)

Interpretation:

The increasing order of basicity of the given compounds is to be stated.

Concept Introduction:

The basicity of compounds can be compared by comparing the stability of their conjugate acid. If the conjugate acid formed is more stable than the basicity of compound will be greater. Resonance structure containing positive charge on electronegative atom is less stable.

Interpretation Introduction

(e)

Interpretation:

The increasing order of basicity of the given compounds is to be stated.

Concept Introduction:

The basicity of compounds can be compared by comparing the stability of their conjugate acid. If the conjugate acid formed is more stable than the basicity of compound will be greater. Resonance structure containing positive charge on electronegative atom is less stable.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 5

Chapter 26, Problem 26.31AP

Interpretation Introduction

(a)

Interpretation:

The increasing order of basicity of the given compounds is to be stated.

Concept Introduction:

Pyridine is a heterocyclic compound which contain nitrogen atom as heteroatom. The lone pair of nitrogen atom pyridine is not delocalized over the ring. Pyridine is basic in nature. The basicity of pyridine compounds changes with substitution. Basicity of pyridine compounds depends on the nucleophilicity of their nitrogen lone pair.

Interpretation Introduction

(b)

Interpretation:

The increasing order of basicity of the given compounds is to be stated.

Concept Introduction:

Pyridine is a heterocyclic compound which contain nitrogen atom as heteroatom. The lone pair of nitrogen atom pyridine is not delocalized over the ring. Pyridine is basic in nature. The basicity of pyridine compounds changes with substitution. Basicity of pyridine compounds depends on the nucleophilicity of their nitrogen lone pair.

Interpretation Introduction

(c)

Interpretation:

The increasing order of basicity of the given compounds is to be stated.

Concept Introduction:

The basicity of compounds can be compared by comparing the stability of their conjugate acid. If the conjugate acid formed is more stable than the basicity of compound will be greater. Resonance structure containing positive charge on electronegative atom is less stable.

Interpretation Introduction

(d)

Interpretation:

The increasing order of basicity of the given compounds is to be stated.

Concept Introduction:

The basicity of compounds can be compared by comparing the stability of their conjugate acid. If the conjugate acid formed is more stable than the basicity of compound will be greater. Resonance structure containing positive charge on electronegative atom is less stable.

Interpretation Introduction

(e)

Interpretation:

The increasing order of basicity of the given compounds is to be stated.

Concept Introduction:

The basicity of compounds can be compared by comparing the stability of their conjugate acid. If the conjugate acid formed is more stable than the basicity of compound will be greater. Resonance structure containing positive charge on electronegative atom is less stable.

Answer 6

Chapter 26, Problem 26.31AP

Interpretation Introduction

(a)

Interpretation:

The increasing order of basicity of the given compounds is to be stated.

Concept Introduction:

Pyridine is a heterocyclic compound which contain nitrogen atom as heteroatom. The lone pair of nitrogen atom pyridine is not delocalized over the ring. Pyridine is basic in nature. The basicity of pyridine compounds changes with substitution. Basicity of pyridine compounds depends on the nucleophilicity of their nitrogen lone pair.

Answer 7

Chapter 26, Problem 26.31AP

Interpretation Introduction

(a)

Interpretation:

The increasing order of basicity of the given compounds is to be stated.

Concept Introduction:

Pyridine is a heterocyclic compound which contain nitrogen atom as heteroatom. The lone pair of nitrogen atom pyridine is not delocalized over the ring. Pyridine is basic in nature. The basicity of pyridine compounds changes with substitution. Basicity of pyridine compounds depends on the nucleophilicity of their nitrogen lone pair.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The increasing order of basicity of the given compounds is to be stated.

Concept Introduction:

Pyridine is a heterocyclic compound which contain nitrogen atom as heteroatom. The lone pair of nitrogen atom pyridine is not delocalized over the ring. Pyridine is basic in nature. The basicity of pyridine compounds changes with substitution. Basicity of pyridine compounds depends on the nucleophilicity of their nitrogen lone pair.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The increasing order of basicity of the given compounds is to be stated.

Concept Introduction:

Pyridine is a heterocyclic compound which contain nitrogen atom as heteroatom. The lone pair of nitrogen atom pyridine is not delocalized over the ring. Pyridine is basic in nature. The basicity of pyridine compounds changes with substitution. Basicity of pyridine compounds depends on the nucleophilicity of their nitrogen lone pair.

Answer 10

Interpretation Introduction

(c)

Interpretation:

The increasing order of basicity of the given compounds is to be stated.

Concept Introduction:

The basicity of compounds can be compared by comparing the stability of their conjugate acid. If the conjugate acid formed is more stable than the basicity of compound will be greater. Resonance structure containing positive charge on electronegative atom is less stable.

Answer 11

Interpretation Introduction

(c)

Interpretation:

The increasing order of basicity of the given compounds is to be stated.

Concept Introduction:

The basicity of compounds can be compared by comparing the stability of their conjugate acid. If the conjugate acid formed is more stable than the basicity of compound will be greater. Resonance structure containing positive charge on electronegative atom is less stable.

Answer 12

Interpretation Introduction

(d)

Interpretation:

The increasing order of basicity of the given compounds is to be stated.

Concept Introduction:

The basicity of compounds can be compared by comparing the stability of their conjugate acid. If the conjugate acid formed is more stable than the basicity of compound will be greater. Resonance structure containing positive charge on electronegative atom is less stable.

Answer 13

Interpretation Introduction

(d)

Interpretation:

The increasing order of basicity of the given compounds is to be stated.

Concept Introduction:

The basicity of compounds can be compared by comparing the stability of their conjugate acid. If the conjugate acid formed is more stable than the basicity of compound will be greater. Resonance structure containing positive charge on electronegative atom is less stable.

Answer 14

Interpretation Introduction

(e)

Interpretation:

The increasing order of basicity of the given compounds is to be stated.

Concept Introduction:

The basicity of compounds can be compared by comparing the stability of their conjugate acid. If the conjugate acid formed is more stable than the basicity of compound will be greater. Resonance structure containing positive charge on electronegative atom is less stable.

Answer 15

Interpretation Introduction

(e)

Interpretation:

The increasing order of basicity of the given compounds is to be stated.

Concept Introduction:

The basicity of compounds can be compared by comparing the stability of their conjugate acid. If the conjugate acid formed is more stable than the basicity of compound will be greater. Resonance structure containing positive charge on electronegative atom is less stable.

Answer 16

Expert Solution & Answer

Answer 17

Expert Solution & Answer

Answer 18

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 19

Ch. 26 - Prob. 26.1P Ch. 26 - Prob. 26.2P Ch. 26 - Prob. 26.3P Ch. 26 - Prob. 26.4P Ch. 26 - Prob. 26.5P Ch. 26 - Prob. 26.6P Ch. 26 - Prob. 26.7P Ch. 26 - Prob. 26.8P Ch. 26 - Prob. 26.9P Ch. 26 - Prob. 26.10P

Solution Summary: The author explains that Pyridine is a heterocyclic compound which contains nitrogen atom as heteroatom. Basicity of pyridine compounds changes with substitution.

Concept explainers

Want to see the full answer?

Chapter 26 Solutions