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(a)
Interpretation:
The stabilizing interactions between DMSO solvent molecules and a dissolved sodium ion are to be shown.
Concept introduction:
The dipole moment is defined as the charge separation between two atoms in a covalent bond or between two ions in an ionic bond. It is used to determine the polarity of atoms or ions. If the value of dipole moment is zero, then the molecule is said to be non-polar, and if the value of dipole moment is not zero, then the molecule is said to be polar and possess permanent dipole moment.
The solvent dimethyl sulfoxide (DMSO) is polar aprotic in nature. In the solution when an ionic compound is dissolved, this polar solvent shows charge-dipole interactions and donor interactions with it.
(b)
Interpretation:
The stabilizing interactions between DMSO solvent molecules and dissolved water are to be shown.
Concept introduction:
The dipole moment is defined as the charge separation between two atoms in a covalent bond or between two ions in an ionic bond. It is used to determine the polarity of atoms or ions. If the value of dipole moment is zero, then the molecule is said to be non-polar, and if the value of dipole moment is not zero, then the molecule is said to be polar and possess permanent dipole moment.
The solvent dimethyl sulfoxide (DMSO) is polar aprotic in nature. In the solution when an ionic compound is dissolved, this polar solvent shows charge-dipole interactions and donor interactions with it.
(c)
Interpretation:
The stabilizing interactions between DMSO solvent molecules and a dissolved chloride ion are to be shown.
Concept introduction:
The dipole moment is defined as the charge separation between two atoms in a covalent bond or between two ions in an ionic bond. It is used to determine the polarity of atoms or ions. If the value of dipole moment is zero, then the molecule is said to be non-polar, and if the value of dipole moment is not zero, then the molecule is said to be polar and possess permanent dipole moment.
The solvent dimethyl sulfoxide (DMSO) is polar aprotic in nature. In the solution when an ionic compound is dissolved, this polar solvent shows charge-dipole interactions and donor interactions with it.
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Chapter 8 Solutions
EBK ORGANIC CHEMISTRY
- Write the equilibrium-constant expressions and obtainnumerical values for each constant in. (a) the basic dissociation of aniline, C6H5NH2. (b) the acidic dissociation of hypochlorous acid,HClO. (c) the acidic dissociation of methyl ammoniumhydrochloride, CH3NH3Cl. (d) the basic dissociation of NaNO2. (e) the dissociation of H3AsO3to H3O+and AsO33-. (f) the reaction of C2O42-with H2O to give H2C2O4and OH-. show solutionarrow_forwardAnswer ALL parts of this question. (a) Using resonance structures, discuss the following statement; phenols are much stronger acids than aliphatic alcohols. (b) Give the structure of a stronger organic acid than phenol. (c) Rationalise the acidity of the latter organic acid by drawing two resonance structures of the conjugate base. (d) Eugenol is a natural product derived from the dried flower buds of the evergreen tree, Eugenia aromatica. Briefly describe a procedure with reagents required to extract eugenol as a single component from the mixture of compounds present in these flower buds. OH LOCH 3 eugenolarrow_forward(a) Although phenoxide ion has more number of resonating structures than carboxylate ion, carboxylic acid is a stronger acid than phenol. Give two reasons.(b) How will you bring about the following converstions?(i) Propanone to propane (ii) Benzoyl chloride to benzaldehyde(iii) Ethanal to but-2-enalarrow_forward
- (a) What is the hybridization of the nitrogen in each of the following compounds? (b) How does hybridization affect the availability of the lone pair and the basicity of each compound?arrow_forward(a) Tsomane and Nyiko were given a task of synthesising methylenecyclohexane 2. After a brief discussion with each other, Tsomane proposed Method A to synthesise 2 from cyclohexanone 1 while Nyiko proposed Method B that started from hydroxymethylcyclohexane 3. Each student believed that their proposed method is better than the other. (Scheme below) Ph THF A Ph Ph B H₂SO4 100 °C 3 OH (iii) In analysing both these methods, are there other possible alkene products other than methylenecyclohexane 2? Use mechanistic details to support your answer.arrow_forwardA)Which of these compounds (i and ii) are the weaker base.. B)Why would you suggest soarrow_forward
- (a) Explain how pyrrole is isoelectronic with the cyclopentadienyl anion.(b) Specifically, what is the difference between the cyclopentadienyl anion and pyrrole?(c) Draw resonance forms to show the charge distribution on the pyrrole structure.arrow_forwardFollowing is a structural formula for guanidine, the compound by which migratory birds excrete excess metabolic nitrogen. The hydrochloride salt of this compound is a white crystalline powder, freely soluble in water and ethanol. Q. Does proton transfer to guanidine occur preferentially to one of its -NH2 groups (cation A) or to its =NH group (cation B)? Explain.arrow_forwardWould you help me with these (4) Thank you.arrow_forward
- I) The following reaction runs as written therefore... 1HClO2 +1NH3 ==>1ClO2- +1NH4+ (a)HClO2 is a weaker Bronsted base than NH4+(b)ClO2- is a stronger Bronsted base than NH3(c)HClO2 is a stronger Bronsted Acid than NH4+(d)None of those is correct.arrow_forwardWhich compound in each of the following pairs would have the higher boiling point? .Explain your answers (1) or HO. (a) (Ь) (2) HO HO. or HO. (b) (а) (3)[ OH or (a) (b)arrow_forwardExplain the following behaviours :(i) Alcohols are more soluble in water than the hydrocarbons of comparable molecular masses.(ii) Ortho-nitrophenol is more acidic than ortho-methoxyphenol.arrow_forward
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