EBK ORGANIC CHEMISTRY
EBK ORGANIC CHEMISTRY
6th Edition
ISBN: 8220103151757
Author: LOUDON
Publisher: MAC HIGHER
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Chapter 8, Problem 8.40AP
Interpretation Introduction

Interpretation:

An explanation regarding the extraction of dibutyl ether from benzene into water if the aqueous solution contains moderately concentrated nitric acid is to be stated.

Concept introduction:

A compound is said to be a polar due to the presence of an electronegative atom that tends to attract the electrons closer to itself as compared to the other atom. The electronegative atom acquires a partial negative charge and creates a partial positive charge on the other atom. Polar compounds are soluble in polar solvents, whereas non-polar compounds are soluble in non-polar solvents.

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Aspirin is the common name for the compound acetylsalicylic acid, widely used as a fever reducer and as a pain killer. Salicylic acid, whose name comes from Salix, the willow family of plants, was derived from willow bark extracts. In folk medicine, willow bark teas were used as headache remedies and other tonics. Nowadays, salicylic acid is administered in the form of aspirin which is less irritating to the stomach than salicylic acid. To prepare aspirin, salicylic acid is reacted with an excess of acetic anhydride. A small amount of a strong acid is used as a catalyst which speeds up the reaction. In this experiment, phosphoric acid will be used as the catalyst. The excess acetic acid will be quenched with the addition of water. The aspirin product is not very soluble in water so the aspirin product will precipitate when water is added. The synthesis reaction of aspirin is shown below: Actic anhydride 5 ml. Acetic acid Salicylic acid 28 Acetylsalicylie acid Procedure 1) Mix salicylic…
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