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EBK ORGANIC CHEMISTRY
6th Edition
ISBN: 8220103151757
Author: LOUDON
Publisher: MAC HIGHER
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Question
Chapter 8, Problem 8.27P
Interpretation Introduction
Interpretation:
A structure for the complex between
Concept introduction:
The dipole moment is defined as the charge separation between two atoms in a covalent bond or between two ions in an ionic bond. It is used to determine the polarity of atoms or ions.
When the value of dipole moment is zero, then the molecule is said to be non-polar, and when the value of dipole moment is not zero, then the molecule is said to be polar and possess permanent dipole moment.
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Students have asked these similar questions
Compounds B and C are isomers with molecular formula C5H9BrO2. The 1H NMR spectrum of compounds B and C are shown below. The IR spectrum corresponding to compound B showed strong absorption bands at 1739, 1225, and 1158 cm-1, while the spectrum corresponding to compound C have strong bands at 1735, 1237, and 1182 cm-1.
1.Based on the information provided, determine the structure of compounds B and C.
2.Assign all peaks in 1H NMR spectrum of compounds B and C.
A task is assigned to an undergraduate student to test two samples (known as
compounds K and L) in the laboratory. She placed these two compounds through
various scientific tests. She discovered that these compounds have the same
molecular formula, CSHSO. When treated with 2,4-dinitrophenylhydrazine, all of
these compounds produce brightly coloured precipitate, and both are reduced to an
organic compound with the molecular formula C§H100. However, compound K can
be easily oxidized by chromic acid to formed compound N and vice versa for
compound L. Furthermore, when both compounds react with Fehling's solutions,
they produce negative results. However, only compound K forms a silver mirror
when it reacts with Tollen's reagent, and compound L does not.
Identify the possible structural formulae for compounds K, L, and N by ignoring
their position isomerism.
Indicate the formation of compound N from compound K.
Predict the chemical reaction that occurs when compound L reacts with 2,4-…
draw the strucutre based off the IR spectrum, 1H NMR spectrum, and 13C NMR spectrum for Compound B.
Compound B may be prepared by treating Compound A with borane/THF complex followed by oxidative work-up.
Compound A (C8H16) → Compound B (C8H18O)
Chapter 8 Solutions
EBK ORGANIC CHEMISTRY
Ch. 8 - Prob. 8.1PCh. 8 - Prob. 8.2PCh. 8 - Prob. 8.3PCh. 8 - Prob. 8.4PCh. 8 - Prob. 8.5PCh. 8 - Prob. 8.6PCh. 8 - Prob. 8.7PCh. 8 - Prob. 8.8PCh. 8 - Prob. 8.9PCh. 8 - Prob. 8.10P
Ch. 8 - Prob. 8.11PCh. 8 - Prob. 8.12PCh. 8 - Prob. 8.13PCh. 8 - Prob. 8.14PCh. 8 - Prob. 8.15PCh. 8 - Prob. 8.16PCh. 8 - Prob. 8.17PCh. 8 - Prob. 8.18PCh. 8 - Prob. 8.19PCh. 8 - Prob. 8.20PCh. 8 - Prob. 8.21PCh. 8 - Prob. 8.22PCh. 8 - Prob. 8.23PCh. 8 - Prob. 8.24PCh. 8 - Prob. 8.25PCh. 8 - Prob. 8.26PCh. 8 - Prob. 8.27PCh. 8 - Prob. 8.28APCh. 8 - Prob. 8.29APCh. 8 - Prob. 8.30APCh. 8 - Prob. 8.31APCh. 8 - Prob. 8.32APCh. 8 - Prob. 8.33APCh. 8 - Prob. 8.34APCh. 8 - Prob. 8.35APCh. 8 - Prob. 8.36APCh. 8 - Prob. 8.37APCh. 8 - Prob. 8.38APCh. 8 - Prob. 8.39APCh. 8 - Prob. 8.40APCh. 8 - Prob. 8.41APCh. 8 - Prob. 8.42APCh. 8 - Prob. 8.43APCh. 8 - Prob. 8.44APCh. 8 - Prob. 8.45APCh. 8 - Prob. 8.46APCh. 8 - Prob. 8.47APCh. 8 - Prob. 8.48APCh. 8 - Prob. 8.49APCh. 8 - Prob. 8.50APCh. 8 - Prob. 8.51APCh. 8 - Prob. 8.52APCh. 8 - Prob. 8.53APCh. 8 - Prob. 8.54APCh. 8 - Prob. 8.55APCh. 8 - Prob. 8.56APCh. 8 - Prob. 8.57AP
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