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Concept explainers
(a)
Interpretation: The given disaccharide has to be classified as a reducing or non-reducing sugar.
Concept introduction: Monosaccharides and most of the disaccharides give positive test with Benedict’s solution. It is used to detect the presence of
(b)
Interpretation: The given disaccharide has to be classified as a reducing or non-reducing sugar.
Concept introduction: Monosaccharides and most of the disaccharides give positive test with Benedict’s solution. It is used to detect the presence of aldehyde or alpha hydroxy ketones. A positive test with Benedict’s solution is confirmed by the formation of a brick-red precipitate.
(c)
Interpretation: The given disaccharide has to be classified as a reducing or non-reducing sugar.
Concept introduction: Monosaccharides and most of the disaccharides give positive test with Benedict’s solution. It is used to detect the presence of aldehyde or alpha hydroxy ketones. A positive test with Benedict’s solution is confirmed by the formation of a brick-red precipitate.
(d)
Interpretation: The given disaccharide has to be classified as a reducing or non-reducing sugar.
Concept introduction: Monosaccharides and most of the disaccharides give positive test with Benedict’s solution. It is used to detect the presence of aldehyde or alpha hydroxy ketones. A positive test with Benedict’s solution is confirmed by the formation of a brick-red precipitate.
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Chapter 18 Solutions
EBK GENERAL, ORGANIC, AND BIOLOGICAL CH
- Complete the following table by providing the Fischer and Haworth Projections of the given sugars. In the Fischer Projection put an asterisk (*) mark in the chiral centers of the molecule. Sugar Fischer Projection Haworth Projection (Complete) alpha-anomer Haworth Projection (Abbreviated) beta-anomer D-Mannose D-Xylose L-Lyxosearrow_forwardDoes gentiobiose (Problem 20.66) have an acetal grouping? A hemiacetal grouping? Do you expect gentiobiose to be a reducing or nonreducing sugar? How would you classify the linkage (x or β and carbon numbers) between the two monosaccharides?arrow_forwardFollowing are Fischer projection for a group of five carbon sugars,all of which are aldopentoses. Identify the pairs that are enantiomers and the pairs that are epimers.(The sugar shown herebare not all of the possible five carbon sugars.)arrow_forward
- Following are Fischer projections for a group of five-carbon sugars, all of which are aldopentoses. Identify the pairs that are enantiomers and the pairs that are epimers. (The sugars shown here are not all of the possible five-carbon sugars.) 1 СНО 2 СНО СНО Н-С—ОН Н-С—ОН Н—С—ОН Н-С—ОН НО —С—Н Н-С—ОН Н- С—ОН НО—С— Н НО—С—Н CH̟OH CH̟OH ČH̟OH в iоchemistry |61 STATE ATION Republic of the Philippines Romblon State University Romblan, Philippines 4 СНО 5 СНО 6 СНО НО—С—Н Н-С—ОН НО -С—Н Н—С—ОН НО -С—Н НО -С—Н H-C–OH Н-С—ОН НО—С—Н CH,OH ČH,OH CH,OHarrow_forwardComplete the following table by providing the Fischer and Haworth Projections of the given sugars. In the Fischer Projection put an asterisk (*) mark in the chiral centers of the molecule. Sugar Fischer Projection Haworth Projection (Complete) alpha-anomer Haworth Projection (Abbreviated) beta-anomer L-Galactose L-Fructose D-Mannose D-Xylose L-Lyxosearrow_forwardAll naturally occurring polysaccharides have one terminal residue, which contains a free anomeric carbon. Why do these polysaccharides not give a positive chemical test for a reducing sugar?Please explainarrow_forward
- What is the family-name ending for a sugar?arrow_forwardThe disaccharide α,β-trehalose differs from the α, α structure as shown by having an (α1→ β1) linkage. Draw its structure as a Haworth projection.arrow_forwardFollowing are structural formulas for cytosine and thymine. Draw two additional tautomeric forms for cytosine and three additional tautomeric forms for thymine.arrow_forward
- Does trehalose (Problem 20.68) have an acetal grouping? A hemiacetal grouping? Do you expect trehalose to be a reducing or nonreducing sugar? Classify the linkage between the two monosaccharides.arrow_forwardWhen the amino acid sequences of insulin isolated from differentorganisms were determined, some differences were noted.For example, alanine was substituted for threonine, serine wassubstituted for glycine, and valine was substituted for isoleucineat corresponding positions in the protein. List the single-basechanges that could occur in triplets to produce these amino acidchanges.arrow_forwardis this an alpha or beta sugar? How can you tell?arrow_forward
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