The given model of half chair conformation is to be examined from different points of view, and the different types of strains are to be noted. The site of strain and the types of strain are to be indicated. Why the half-chair conformation is so high in energy is to be justified. Concept introduction: Cyclohexane has no ring strain because it adopts a chair conformation in which all angles are about 111° (close to the ideal tetrahedral angle of 109.5 ° ). In the half chair, the actual bond angle increases to 120° , resulting in angle strain, and torsional strain is due to eclipsed conformation. The half-chair conformation in a chair flip is higher in energy than the chair conformation itself due to added ring strain.

Question

Want to see the full answer?

Answer 1

Question

Chapter 4, Problem 4.16YT

Interpretation Introduction

Interpretation:

The given model of half chair conformation is to be examined from different points of view, and the different types of strains are to be noted. The site of strain and the types of strain are to be indicated. Why the half-chair conformation is so high in energy is to be justified.

Concept introduction:

Cyclohexane has no ring strain because it adopts a chair conformation in which all angles are about 111° (close to the ideal tetrahedral angle of 109.5°). In the half chair, the actual bond angle increases to 120°, resulting in angle strain, and torsional strain is due to eclipsed conformation.

The half-chair conformation in a chair flip is higher in energy than the chair conformation itself due to added ring strain.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Students have asked these similar questions

For every structure below, draw the most stable chair conformation. Where two or more conformations are equally stable, draw both.

Specify the types of strain that destabilize the conformer shown below. Hint: All bonds not explicitly shown are in the staggered conformation.

plzz answer this in detail, draw all possible chair conformation and mark the most stable one , please do with clean handwritting

Answer 2

Question

Chapter 4, Problem 4.16YT

Interpretation Introduction

Interpretation:

The given model of half chair conformation is to be examined from different points of view, and the different types of strains are to be noted. The site of strain and the types of strain are to be indicated. Why the half-chair conformation is so high in energy is to be justified.

Concept introduction:

Cyclohexane has no ring strain because it adopts a chair conformation in which all angles are about 111° (close to the ideal tetrahedral angle of 109.5°). In the half chair, the actual bond angle increases to 120°, resulting in angle strain, and torsional strain is due to eclipsed conformation.

The half-chair conformation in a chair flip is higher in energy than the chair conformation itself due to added ring strain.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 3

Question

Chapter 4, Problem 4.16YT

Interpretation Introduction

Interpretation:

The given model of half chair conformation is to be examined from different points of view, and the different types of strains are to be noted. The site of strain and the types of strain are to be indicated. Why the half-chair conformation is so high in energy is to be justified.

Concept introduction:

Cyclohexane has no ring strain because it adopts a chair conformation in which all angles are about 111° (close to the ideal tetrahedral angle of 109.5°). In the half chair, the actual bond angle increases to 120°, resulting in angle strain, and torsional strain is due to eclipsed conformation.

The half-chair conformation in a chair flip is higher in energy than the chair conformation itself due to added ring strain.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 4

Question

Chapter 4, Problem 4.16YT

Interpretation Introduction

Interpretation:

The given model of half chair conformation is to be examined from different points of view, and the different types of strains are to be noted. The site of strain and the types of strain are to be indicated. Why the half-chair conformation is so high in energy is to be justified.

Concept introduction:

Cyclohexane has no ring strain because it adopts a chair conformation in which all angles are about 111° (close to the ideal tetrahedral angle of 109.5°). In the half chair, the actual bond angle increases to 120°, resulting in angle strain, and torsional strain is due to eclipsed conformation.

The half-chair conformation in a chair flip is higher in energy than the chair conformation itself due to added ring strain.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 5

Chapter 4, Problem 4.16YT

Interpretation Introduction

Interpretation:

The given model of half chair conformation is to be examined from different points of view, and the different types of strains are to be noted. The site of strain and the types of strain are to be indicated. Why the half-chair conformation is so high in energy is to be justified.

Concept introduction:

Cyclohexane has no ring strain because it adopts a chair conformation in which all angles are about 111° (close to the ideal tetrahedral angle of 109.5°). In the half chair, the actual bond angle increases to 120°, resulting in angle strain, and torsional strain is due to eclipsed conformation.

The half-chair conformation in a chair flip is higher in energy than the chair conformation itself due to added ring strain.

Answer 6

Chapter 4, Problem 4.16YT

Interpretation Introduction

Interpretation:

The given model of half chair conformation is to be examined from different points of view, and the different types of strains are to be noted. The site of strain and the types of strain are to be indicated. Why the half-chair conformation is so high in energy is to be justified.

Concept introduction:

Cyclohexane has no ring strain because it adopts a chair conformation in which all angles are about 111° (close to the ideal tetrahedral angle of 109.5°). In the half chair, the actual bond angle increases to 120°, resulting in angle strain, and torsional strain is due to eclipsed conformation.

The half-chair conformation in a chair flip is higher in energy than the chair conformation itself due to added ring strain.

Answer 7

Chapter 4, Problem 4.16YT

Interpretation Introduction

Interpretation:

The given model of half chair conformation is to be examined from different points of view, and the different types of strains are to be noted. The site of strain and the types of strain are to be indicated. Why the half-chair conformation is so high in energy is to be justified.

Concept introduction:

Cyclohexane has no ring strain because it adopts a chair conformation in which all angles are about 111° (close to the ideal tetrahedral angle of 109.5°). In the half chair, the actual bond angle increases to 120°, resulting in angle strain, and torsional strain is due to eclipsed conformation.

The half-chair conformation in a chair flip is higher in energy than the chair conformation itself due to added ring strain.

Answer 8

Expert Solution & Answer

Answer 9

Expert Solution & Answer

Answer 10

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 11

Ch. 4 - Prob. 4.1P Ch. 4 - Prob. 4.2P Ch. 4 - Prob. 4.3P Ch. 4 - Prob. 4.4P Ch. 4 - Prob. 4.5P Ch. 4 - Prob. 4.6P Ch. 4 - Prob. 4.7P Ch. 4 - Prob. 4.8P Ch. 4 - Prob. 4.9P Ch. 4 - Prob. 4.10P

Solution Summary: The author explains how the molecular kit is used to build the half-chair conformation to form a model.

Concept explainers

Videos

Want to see the full answer?

Chapter 4 Solutions