Concept explainers
(a)
Interpretation:
The Dash-wedge structure for the given Newman projection is to be drawn.
Concept introduction:
A dash -wedge structure is a three-dimensional representation of a molecule drawn using different representations for bonds in the plane of paper, and those projecting toward and away from the viewer.
The bond which is in the plane of paper is represented by a straight line. The bond which points away from the viewer is represented by a dash line. The bond which points towards the viewer is represented by a wedge line.
(b)
Interpretation:
The Dash-wedge structure for the following Newman projection is to be drawn.
Concept introduction:
A dash -wedge structure is a three-dimensional representation of a molecule drawn using different representations for bonds in the plane of paper and those projecting toward and away from the viewer. The bond which is in the plane of paper is represented by a straight line. The bond which points away from the viewer is represented by a dash line. The bond which points towards the viewer is represented by a wedge line.
(c)
Interpretation:
The Dash-wedge structure for the following Newman projection is to be drawn.
Concept introduction:
A dash -wedge structure is a three-dimensional representation of a molecule drawn using different representations for bonds in the plane of paper and those projecting toward and away from the viewer. The bond which is in the plane of paper is represented by a straight line. The bond which points away from the viewer is represented by a dash line. The bond which points towards the viewer is represented by a wedge line.
(d)
Interpretation:
The Dash-wedge structure for the following Newman projection is to be drawn.
Concept introduction:
A dash -wedge structure is a three-dimensional representation of a molecule drawn using different representations for bonds in the plane of paper and those projecting toward and away from the viewer. The bond which is in the plane of paper is represented by a straight line. The bond which points away from the viewer is represented by a dash line. The bond which points towards the viewer is represented by a wedge line.
Trending nowThis is a popular solution!
Chapter 4 Solutions
ORGANIC CHEMISTRY E-BOOK W/SMARTWORK5
- Consider the Newman projection below. a. Draw a full Lewis structure of this molecule with R1=Me,R2=Et , and R3=iPr . b. Given the sizes of these R groups (R3R2R1) , does the Newman projection above show thelowest potential energy conformation of this bond? If not, draw a Newman projectionshowing the lowest P.E. conformation (sighting down this same bond). c. To draw a Newman projection in the lowest P.E. conformation, the following rule of thumbusually applies: Place the largest group on the front carbon anti to the largest group on theback carbon. Is your answer to the previous question consistent with this rule of thumb?arrow_forwardPlease look at the picture as it is related on my question. When do we decide that it is CH3 or H3C that we put while we are drawing the Newman projection?arrow_forwardFill in the Newman projection for the following molecule from the angle shownarrow_forward
- Draw the Newman projection of the following compound looking down the bond indicated via the arrow. ( see picture)arrow_forwarddraw newman projection for the indicated bond. put largest groups anti to each other.arrow_forwarda. Draw the Newman projection for each molecule shown here, looking down the c-c bond indicated by the arrow. b. Which configuration do you think is more stable? Explain.arrow_forward
- Draw the most stable Newman projection for the following alkanes looking down the C-C bond pointed to by the arrows.arrow_forwardDraw the Newman projection so that it corresponds to the molecule and conformation shown when viewed down the red bond in the direction of the arrow.arrow_forwardYou move along your journey in the Plane of the Page to encounter. pseudoephedrine (below), the principal ingredient the common cold medication Sudafed. Answer the following question about this molecule. Draw Newman Projections for the two indicated bonds.arrow_forward
- Solve correctly please. Which of the following Newman projections is the least stable?arrow_forwardtranslate the bond-line notation structure to the Newman projection by filling int the missing groups (A, B, C, D or E) on the lines in the Newman projection so they match the conformation given in the original structure. Circle if the conformation is a staggered or eclipsed.arrow_forwardWhich of the following is the correct wedge and dash conformation for the following Newman projection?arrow_forward
- Organic Chemistry: A Guided InquiryChemistryISBN:9780618974122Author:Andrei StraumanisPublisher:Cengage Learning