Concept explainers
(a)
Interpretation:
The amount of heat transferred to the tank is to be calculated.
Concept introduction:
A flowchart is the complete representation of a process through boxes or other shapes which represents process units and arrows that represents the input and output of the process. The flowchart must be fully labelled to infer important data about the process involved.
In a system, a conserved quantity (total mass, mass of a particular species, energy or momentum) is balanced and can be written as:
Here, ‘ input’ is the stream which enters the system. ‘ generation’ is the term used for the quantity that is produced within the system. ‘ output’ is the stream which leaves the system. ‘ consumption’ is the term used for the quantity that is consumed within the system. ‘ accumulation’ is used for the quantity which is builds up within the system.
All the equations which are formed are then solved simultaneously to calculate the values of the unknown variables.
The equation for energy balance is:
Here,
Mass
(b)
Interpretation:
The final temperature of the contents of the tank is to be calculated.
Concept introduction:
Saturated steam is the steam vaporized with little heat at its boiling point. Above this saturation temperature, the steam becomes superheated.
(c)
Interpretation:
The amount of steam which is condensed is to be calculated.
Concept introduction:
Saturated steam is the steam vaporized with little heat at its boiling point. Above this saturation temperature, the steam becomes superheated.
At this saturation temperature at a particular pressure, steam is present along with some condensed steam when cooled.
The total mass of the system is conserved for the system before and after the cooling takes place.
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Chapter 7 Solutions
EBK ELEMENTARY PRINCIPLES OF CHEMICAL P
- A student determines the molar mass of a liquid unknown by the method used in thisexperiment. She found that the equilibrium temperature of a mixture of ice and water was1.0°C on her thermometer. When she added 12.3 g of her unknown sample to the mixture, thetemperature, after thorough stirring, fell to -4.0°C. She then poured off the solution through ascreen into a beaker. The mass of the solution was 93.4 g. Kf = 1.86°C/m What was the molality of the unknown solution? ______________ m How much unknown liquid was in the decanted solution? ______________ gHow much water was in the decanted solution? ______________ gWhat did she find to be the molar mass of the unknown liquid, assuming she made thecalculation properly?______________ garrow_forwardA gas in the initial state of p1 = 75 psia and V1 = 5 ft.3 undergoes a process to p2 = 25 psia and V2 = 9.68 ft., during which the enthalpy decreases 62 BTU. The %3D specific heat at constant volume is c, = 0.754 BTU/lb.°R. Determine (a) the change of internal energy, (b) the specific heat at constant pressure, (c) the gas constant R.°arrow_forwardConstruct enthalpy cycles; use Hess's law and the following data to calculate the enthalpy of formation of ethane (from carbon and hydrogen gas). Cis) + Ozig) + CO2(g) AHa = -394kJmol H2g) + %02(a) – H20 m AH°. = -286kJmol1 + 3%O2(g) → 2002(9) + 3H20 m AH = -1560kJmol1arrow_forward
- 3. One mole of liquid water at 100 °C is heated until the liquid is converted entirely to vapor at 100 °C and 1 atm pressure. Calculate q, w, AE and AH for each of the following. (a) The vaporization is carried out in a cylinder where the external pressure on the piston is maintained at 1 atm throughout. (b) The cylinder is first expanded against vacuum (Pext = 0) to the same volume as in part (a), and then sufficient heat is added to vaporize the liquid completely to 1 atm pressure.arrow_forwardc) Calculate the standard enthalpy change for the reaction 3C(s) + 4H2 (g) C;H8 (g) Given that C(s) + O2 (g) CO2 (g) AH° = -394 kJmol·' H2 (g) + ½O2 (g) H2O (I) AH° = -286 kJmol C3H8 (g) + 502 (g) 3CO2 (g) + 4H2O (I) AH° = -2220 kJmol·'arrow_forward(7) Combustion of CH4 and H₂. For 100 g mol of a gas mixture of 75 mol % CH4 and 25 mol % H₂, calculate the total heat of combustion of the mixture at 298 K and 101.32 kPa, assuming that combustion is complete.arrow_forward
- Two closed tanks are connected to each other by a valve. The first tank contains oxygen (O₂, m= 2.4 kg, T= 134 °C, p= 5 bar) and the other carbon dioxide (CO₂, m= 2.4 kg, T = 33 °C, p = 1.0 bar). When the valve is opened, the gases are allowed to mix. When the mixture reaches equilibrium, the temperature of the mixture is 73 °C. The gases can be assumed to be ideal gases. Calculate m³ (two decimal accuracy) 1) Total volume of the tanks 2) Final pressure of the mixture 3) Molar fraction of oxygen in the mixture 4) Molar fraction of carbon dioxide in the mixture 5) Partial pressure of oxygen in the mixture 6) Partial pressure of carbon dioxide in the mixture 7) Average specific heat capacity of oxygen at constant volume 8) Average specific heat capacity of carbon dioxide at constant volume 9) Heat transferred from or to the process kPa (zero decimal accuracy) % (zero decimal accuracy) % (zero decimal accuracy) kPa (zero decimal accuracy) kPa (zero decimal accuracy) kJ/kgk (three decimal…arrow_forwardF 6. A rigid vessel of volume 0.4 m^3 containing H2 at 21.25°C and a pressure of 715x10^3 Pa is connected to a second rigid vessel of volume 0.75m^3 containing Argon at 30.15°C at a pressure of 203x10^3. A valve separating the two vessels is opened and the mixed gases allowed to cool to a temperature of 12.2°C. What is the final pressure of the gas mixture in the connected vessel in atm? (1 atm = 101325 Pa) Please show all steps.arrow_forwardThermo- Problem 4.23 At 298 K. AH; 131.28 kJ-mol for the reaction -1 with Cp.-8.53, 33.58, 29.12, and 28.82 J K mol for graphite, H₂O(g). CO(g), and H₂(g), respectively Part A Calculate AH; at 210 *C from this information. Assume that the heat capacities are independent of temperature. Express your answer to five significant figures and include the appropriate units. ΔΗ: (210 °C) - Submit Provide Feedback HÅ Value Request Answer Units C(graphite) + H₂O(g) → CO(g) + H₂(g)arrow_forward
- Determine Z and V for steam (H2O) at 250 °C (523.15 K) and 1800 kPa by the following: (a) Ideal gas equation (b) The truncated virial equation, Z=P/V=1+B/V+C/V^2, with the following experimental values of virial coefficients: B = 152.5cm^3/mol; C = -5800cm^6/mol (c) Truncated virial equation up to the parameter B (C excluded). (d) The steam tables (e) Soave/Redlich/Kwong equation (f) Peng/Robinson equation (g) Generalized Pitzer Correlationarrow_forwardA piston/cylinder arrangement contains one mole of an ideal gas (the system) initially at 10.0 atm pressure and 300 K, as shown in the accompanying illustration. Neglecting the mass of the piston, neglecting friction, and assuming isothermal conditions throughout, the pin restraining the piston is removed. For the resulting process: (g = 9.807 m sR7) (a) What is qsyst if the mass of the weight is zero? (b) What is qsyst if the mass of the weight is 100 kg? (c) What is qsyst if the mass of the weight is 1017.4 kg?arrow_forwardIn a generic chemical reaction involving reactants and B and products C and D, aA + bB cC + dD, the standard enthalpy AHin of the reaction is given by AHixn = CAH; (C) + dAH; (D) —aAH (A) – bAH (B) Notice that the stoichiometric coefficients, a, b, c, d, are an important part of this equation. This formula is often generalized as follows, where the first sum on the right-hand side of the equation is a sum over the products and the second sum is over the reactants: where m and n represent the appropriate stoichiometric coefficients for each substance. Part A What is AHxn for the following chemical reaction? CS2(g) + 2H₂O(1)→CO2(g) + 2H₂S(g) You can use the following table of standard heats of formation (AH) to calculate the enthalpy of the given reaction. ■ μÅ Value AHrxn=products H - Σreactants mΔΗ Element/ Compound H(g) H₂(g) H₂O(1) CS2 (g) C(g) C(s) Units ? Standard Heat of Formation (kJ/mol) Express the standard enthalpy of reaction to three significant figures and include the…arrow_forward
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