EBK ELEMENTARY PRINCIPLES OF CHEMICAL P
4th Edition
ISBN: 9781119192107
Author: BULLARD
Publisher: JOHN WILEY+SONS,INC.-CONSIGNMENT
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Question
Chapter 7, Problem 7.35P
Interpretation Introduction
(a)
Interpretation:
The final water temperature should be calculated.
Concept introduction:
First law of
The right hand side of the equation gives the total energy transferred to the system and the left hand side gives gain in total energy of the system.
Interpretation Introduction
(b)
Interpretation:
The specific internal energy, the final temperature of the mixture and the percentage difference in two answers should be calculated.
Concept introduction:
First law of Thermodynamics for a closed system.
The right hand side of the equation gives the total energy transferred to the system and the left hand side gives gain in total energy of the system.
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1. Consider a situation where two volumes of water, one hot, one cold, are both added to a foam
cup.
(a) Sketch a diagram for the cup and volumes of water, using a dashed line to separate the
two volumes, and label all the components.
(b) To your sketch, add a line and label it to indicate the heat flow in this system. For now,
asssume the foam is a perfect insulator.
(c) Write the mathematical relationship between the heat flows for the hot and cold water,
qhot and qcold based on you diagram from parts (a) and (b).
(d) Once the water is well-mixed, both volumes of water come to the same temperature Ts.
Write the mathematical expressions for the temperature changes for each of the volumes
of water, ATcold and AThot, assuming they started at Tcold and Thot for the cold and hot
water respectively.
(e) Assuming that the foam undergoes the same temperature change as the cold water (it's
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AvapH° (CO20) (assumed to be temperature independent): 25.12 kJ mol1
Using the data, calculate the saturated vapor pressure of CO2 at 0°C. To do this, the
equation P = f(T) will be established using a relationship that will be recalled and integrated in
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IV
73.8
(b)
(미)
Vaporisation
5.1
1
Sublimation
-78.5 -56.4
31.1
Température (°C)
Pression (bars)
Fusion
Chapter 7 Solutions
EBK ELEMENTARY PRINCIPLES OF CHEMICAL P
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